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QUANTITATIVE DETERMINATION OF MOLECULAR ORIENTATION OF FUNCTIONAL ORGANIC THIN FILMS BY ANGLE-RESOLVED ULTRAVIOLET PHOTOELECTRON SPECTROSCOPY

Research Project

Project/Area Number 08455004
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionOKAZAKI NATIONAL RESEARCH INSTITUTE (1997-1998)
Chiba University (1996)

Principal Investigator

UENO Nobuo  OKAZAKI NATIONAL RESEARCH INSTITUTE INSTITUTE FOR MOLECULAR SCIENCE, PROFESSOR, 分子科学研究所, 教授 (40111413)

Co-Investigator(Kenkyū-buntansha) OKUDAIRA Koji  CHIBA UNIV., FAC.OF ENG., ASSOCIATE PROFESSOR, 工学部, 助教授 (50202023)
HARADA Yoshiya  CHIBA UNIV., FAC.OF ENG., PROFESSOR, 工学部, 教授 (20013477)
HASEGAWA Shinji  OKAZAKI NATIONAL RESEARCH INSTITUTE, INSTITUTE FOR MOLECULAR SCIENCE, RESEARCH A, 分子科学研究所, 助手 (10228447)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1998: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1997: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsORGANIC THIN FILM / SYNCHROTRON RADIATION / UPS / ELECTRONIC STATE / PHOTOELECTRON SPECTROSCOPY / MOLECULAR DEVICE / MOLECULAR ORIENTATION / SURFACE AND INTERFACE / UPS / 有機分子 / 分子デバイス / 紫外光電子分光 / 低速電子透過 / ペニングイオン化電子分光 / 低速電子回析 / 電子エネルギー損失
Research Abstract

(1) A theoretical method for the calculation of photoelectron angular distributions from organic thin films was successfully performed in the single scattering approximation.
(2) The photoelectron angular distributions from various thin films prepared by organic molecular beam epitaxy were successfully analyzed to give quantitative molecular orientation angles.
(3) The above analysis method was applied to investigate polymer surfaces.The orientation of pendant groups at the surfaces of pendant group polymers was determined by the quantitative analysis of the photoelectron angular distributions.
(4) It was shown that the results obtained by angle-resolved ultraviolet photoelectron spectroscopy combined with theoretical intensity analysis were consistent with those obtained by other surface sensitive spectroscopies.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (34 results)

All Other

All Publications (34 results)

  • [Publications] N.Ueno et al.: "Low-energy electron transmission spectroscopy of thin films of chloroaluminum phthalocyanine on MoS_2" Jpn.J.Appl.Phys.36. 5731-5736 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Ueno et al.: "Thickness dependent orientation of pendant phenyl group at the surface of polystyrene thin films" Jpn.J.Appl.Phys.37. 4979-4982 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Hasegawa et al.and N.Ueno: "Origin of photoemission intensity oscillation of C_<60>" Phys.Rev.B. 58. 4927-4933 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Azuma et al.and N.Ueno: "Angle-resolved UV photoelectron spectra (UPS) of thin films of perylene-3,4,9,10 tetracarboxylic dianhydride on MoS_2" J.Synchrotron Radiation. 5. 1044-1046 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Azuma et al.and N.Ueno: "Temperature dependence of photoelectron angular distribution from thin films of chloroalminum phthalocyanine on MoS_2" J.Synchrotron Radiation. 5. 1047-1049 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Kera,N.Ueno et al.: "Characterization of ultrathin films of titanyl phthalocyanine on graphite: PIES and UPS study" Thin Solid Films. 327-329. 278-282 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Masuda,N.Ueno and J.J.Pireaux(編集): "Proceeding of the Seventh International Conference on Electron Spectroscopy" Elsevier Science, 1-1064 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Ueno: "Angle-resolved UPS of ultrathin films of functional organic molecules with synchrotron radiation : Determination of molecular orientation by quantitative analysis of photoelectron angular distribution" J.Electron Spectr.Relat.Phenom. 78. 345-350 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Ueno, A.Kitamura, K.K.Okudaira, T.Miyamae, Y.Harada, S.Hasegawa, H.Ishii, H.Inokuchi, T.Fujikawa, T.Miyazaki and K.Seki: "Angle-resolved UPS of thin films of bis(1,2,5-thiadiazolo)-p-quinobis (1,3-dithiole) on the MoS_2 surface" J.Chem.Phys.107. 2079-2088 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Ueno, Y.Azuma, T.Yokota, M.Aoki, K.K.Okudaira and Y.Harada: "Low-energy electron transmission spectroscopy of thin films of chloroaluminum phthalocyanine on MoS_2" Jpn.J.Appl.Phys.36(9A) Part 1. 5731-5736 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Azuma, T.Hasebe, T.Miyamae, K.K.Okudaira, Y.Harada, K.Seki, E.Morikawa, V.Saile, and N.Ueno: "Angle-resoived UV photoelectron spectra (UPS ) of thin films of perylene-3,4,9,10-tetracarboxylic dianhydride on MoS_2" J.Synchrotron Radiation. 5. 1044-1046 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Azuma, M.Tsutsui, S.Kera.M.Aoki, T.Miyamae, K.Okudaira, Y.Harada and N.Ueno: "Temperature dependence of photoelectron angular distribution from thin films of chloroaluminum phthalocyanine on MoS_2" J.Synchrotron Radiation. 5. 1047-1049 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Kera, A.Abduaini, M.Aoki, K.K.Okudaira, N.Ueno, Y.Harada, Y.Shirota, and T.Tsuzuki: "Characterization of ultrathin films of titanyl phthalocyanine on graphite : PIES and UPS study" Thin Solid Films.327-329. 278-282 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Azuma, T.Yokota, S.Kera, M.Aoki.K.K.Okudaira, Y.Harada, and N.Ueno: "Characterization of thin films of chloroaluminum phthalocyanine on MoS_2 : HREELS, LEET and PIES study" Thin Solid Films. 327-329. 303-307 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Azuma, T.Yokota, S.Kera, M.Aoki, K.Okudaira, Y.Harada, and N.Ueno: "High-resolution electron energy loss spectroscopy of chloroaluminum phthalocyanine ultrathin films" J.Electron Spectr. & Related Phenom. 88-91. 881-884 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.K.Okudaira, S.Hasegawa, P.T.Sprunger, E.Morikawa, V.Saile, K.Seki, Y.Harada and N.Ueno: "Photoemission study of pristine and photodegraded poly(methyl methacrylate)" J.Appl.Phys.83(8). 4292-4298 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Hasegawa, T.Miyamae, K.Yakushi, H.Inokuchi, K.Seki and N.Ueno: "Origin of photoemission intensity oscillation of C_<60>" Phys.Rev. B58(8). 4927-4933 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Ueno, Y.Azuma, M.Tsutsui, K.K.Okudaira, and Y.Harada.: "Thickness dependent orientation of pendant phenyl group at the surface of polystyrene thin films" Jpn.J.Appl.Phys. 37(9A). 4979-4982 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Ueno et al.: "Low-energy electron transmission spectroscopy of thin films of chloroaluminum phthalocyanine on MoS_2" Jpn.J.Appl.Phys.36. 5731-5736 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Ueno et al.: "Thickness dependent orientation of pendant phenyl group at the surface of polystyrene" Jpn.J.Appl.Phys.37. 4979-4982 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Hasegawa et al.and N.Ueno: "Origin of photoemission intensity oscillation of C_<60>" Phys.Rev.B. 58. 4927-4933 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Azuma et al.and N.Ueno: "Angle-resolved UV photoelectron spectra(UPS)of thin films of perylene-3,4,9,10 tetracarboxylic dianhydride on MoS_2" J.Synchrotron Radiation. 5. 1044-1046 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Azuma et al.and N.Ueno: "Temperature dependence of photoelectron angular distribution from thin films of chloroalminum phthalocyanine on MoS_2" J.Synchrotron Radiation. 5. 1047-1049 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kera,N.Ueno et al.: "Characterization of ultrathin films of titanyl phthalocyanine on graphite:PIES and UPS study" Thin Solid Films. 327-329. 278-282 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Masuda,N.Ueno and J.J.Pireaux.(編集): "Proceeding of the Seventh International Conference on Electron Spectroscopy" Elsevier Science, 1-1064 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Ueno: "Angle-resolved UPS of thin films of bis (1,2,5-thiadiazolo)-p-quinobis (1,3-dithiole) on the MoS_2 surface" J.Chem.Phys.107. 2079-2088 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Ueno: "Low-energy electron transmission spectroscopy of thin films of chloroaluminum phthalocyznine on MoS_2" Jpn.J.Appl.Phys.36(9A). 5731-5736 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Nobuo Ueno: "Site-specific chemical-bond scission in PMMA by inner shell excitation" Jpn.J.Appl.Phys.36(12B). 7605-7610 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Azuma: "Angle-Resolved UPS of Thin Films of Perylene-3,4,9,10-Tetracarboxylic-Dianhydride on MoS_2" J.Synchrotron Radiation. (in press.).

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Azuma: "Angle-Resolved Ultraviolet Photoelectron Spectroscopy of Thin Films of Chloroalminum Phthalocyanine on MoS_2" J.Synchrotron Radiation. (in press.).

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Azuma: "Characterization of Thin Films of Chloroalminum Phthalocyanine on MoS2:HREELS,LEET and PIES Study" Thin Solid Films. (in press.).

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Ueno: "Angle-resolved UPS of ulirathin films of functional organic molecules with synchrotron radiation:Determination of molecular orientation by quantitalive analysis of photoelectron angular distribution." J.Electron Spectr.Relat.Phenom.78. 345-350 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Hasegawa: "Angle-resolved photoemission from oriented thin films of naphthacen Comparison with theoretical spectra." J.Electron Spectr.Relat.Phenom.78. 391-394 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Ishii: "Angle-resolved ultravioled photoelectron spectroscopy of oriented film of model compound of poly(p-phenylene):Wave number(k)-conservation and k blurring in a system with small number of repeating units." J.Electron Spectr.Relat.Phenom.78. 395-398 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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