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Verification of Stability of CaF2/diamond MIS Interface and Application to HT-MISFET

Research Project

Project/Area Number 08455020
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 表面界面物性
Research InstitutionOsaka University

Principal Investigator

KOBAYASHI Takeshi  Osaka Univ., DEPT.of CHEM.SCI., ENG., Professor, 大学院・基礎工学研究科, 教授 (80153617)

Co-Investigator(Kenkyū-buntansha) MAKI Tetsurou  Osaka Univ., DEPT.of CHEM.SCI., ENG., Assistant, 大学院・基礎工学研究科, 助手 (80273605)
FUJII Tatsuhiko  Osaka Univ., DEPT.of CHEM.SCI., ENG., Lecturer, 大学院・基礎工学研究科, 講師 (40238530)
作田 健  大阪大学, 基礎工学部, 講師 (70221273)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥7,400,000 (Direct Cost: ¥7,400,000)
Fiscal Year 1997: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1996: ¥6,500,000 (Direct Cost: ¥6,500,000)
KeywordsDiamond thin film / Surface, interface / CaF2 / FET / Epitaxy / 弗化カルシウム / ダイヤモンド / 界面準位 / MISFET / フッ素化
Research Abstract

Dimond thin film technology is growing up today, and p-type semiconductive diamond film has been obtainable reproducively by boron doping technique. It is the time to extend diamond to the actual electronic applications.
So far, our group conducted research on evaluation and control of diamond surface and interface. In this project, we have focused role of fluorination and oxygen reduction very effective for diamond surface stabilization.
Major results are as follows :
(1) Oxygen adsorption unfavorably introduces the surface states which pin the surface band.
(2) Ca atom serves as oxygen-getter during CaF2 deposition on diamond surface.
(3) Fluorine atom directly bonds with surface carbon atom and stabilizes the surface electrical property.
(4) We have got pretty nice interface by CaF2/diamond MIS structure, and MISFET made thus worked quite well. We obtained for the first time diamond MISFET with normally off property.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (19 results)

All Other

All Publications (19 results)

  • [Publications] 小林 猛: "Thin film CaF2 stabilizing effect on single-crystal diamond surface" Appl.Surface Science. 117/118. 570-573 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 小林 猛: "Cathodoluminescence measurement of CVD diamond surface" Appll.Surface Science. 117/118. 578-581 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 牧 哲朗: "Hall Effect Measurement and Band Bending Calculation of Hydrogenated Diamond Thin Films Drown by Chemical Vapor Deposition" Jpn.J.Appl.Phys.38. 3414-3417 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 牧 哲朗: "Prospect of Semiconducting Diamond Electronics" Diamond Films and Technology. 6-4. 199-216 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yun, T.Maki, H.Tanaka and T.Kobayashi: "Electrical properties of metal-insulator-semiconductor (MIS) interface and MISFETs employing hydrogenated diamond film surface" Int.Conf.on Solid St.Devices and Materials. (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Kurokawa, H.kawamura, T.Maki and T.Kobayashi: "Cathodoluminescence Measurement of CVD Diamond Films Specially-grown for Hard-Electronics" Int.Conf.on Solid St.Devices and Materials. (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Maki, and T.Kobayashi: "Diamond Thin Films-New Way to Hard Electronics by Diamond Semiconductor" Materials Society of Japan (Invited Paper). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Maki, H.Kawamura and T.Kobayashi: "Cathodoluminescence associated with Atomic Species terminating the Diamond Surface" New Diamond Forum, (Invited Paper, Tokyo). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Young YUN,T.Maki and T.Kobayashi: "Surface state density distribution of semiconducting diamond films measured from the Al/CaF2/i-diamond metal-insulator-semiconductor (MIS) diodes and transistors" J.Appl.Phys.3422-3429 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Kobayashi: "Key technologies for breakthrough toward next-stage electionic devices" IEICE (in Japanese). (in press).(1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Maki, T.Hosomi and T.Kobayashi: "Diamond Thin-Film Growth by Using Xe Assisted Microwave Plasma Chemical Vapor Deposition" IEE Japan Trans.(MC-97-1). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 小林 猛: "Thin film CaF2 stabilizing effect on single-crystal diamond surface" Appl.Surface Science. 117/118. 570-573 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 小林 猛: "Cathodoluminescence measurement of CVD diamond surface" Appl.Surface Science. 117/118. 578-581 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 牧 哲朗: "Hall Effect Measurement and Band Bending Calculation of Hydrogenated Diamond Thin Films Grown by Chemical Vapor Deposition" Jpn.J.Appl.Phys.38. 3414-3417 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 牧 哲朗: "Prospect of Semiconducting Diamond Electronics" Diamond Films and Technology. 6-4. 199-216 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Kobayashi: "Observation of Capaitance Hunching at Flat Band Voltage in Diamond Metal-insulator-semicanductor structures" Jpn.J.Appl.Phys.35(8). L1081-L1084 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Kobayashi: "Prospect of Semiconducting Diamond Electronics" Diamond Films and Technologies. 6(4). 199-216 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 牧哲朗: "SrTiO_3/CaF_2複合ゲート絶縁膜を用いたダイヤモンドMISFET" ダイヤモンド・シンポジウム. 12月. (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Kobayashi: "Effect of Oxygen additive on Microwave Plasma for Diamond Film Synthesis Studied by Plasma・Impedance-Measurement" Jpn.J.Appl.Phys.35(7B). L936-L939 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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