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Growth and excitonic properties of InGaN ternary alloy semiconductors

Research Project

Project/Area Number 08455148
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionYamaguchi University

Principal Investigator

TAGUCHI Tsunemasa  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (90101279)

Co-Investigator(Kenkyū-buntansha) YAMADA Yoichi  Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (00251033)
SHINOZUKA Yuzo  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (30144918)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥7,700,000 (Direct Cost: ¥7,700,000)
Fiscal Year 1997: ¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 1996: ¥4,400,000 (Direct Cost: ¥4,400,000)
Keywordsnitride semiconductor / alloy semiconductor / moleclar beam epitaxy / exciton / localization / isoelectronic impurity / self trapping / stimulated emission / 誘導放出 / RF放電 / ドナー束縛励起子 / マイクロ波プラズマ / ラジカル源
Research Abstract

We have studied the growth and the excitonic optical properties of nitride semiconductors, especially In _xGa_<1-x>N ternary alloys, in order to clarify the radiative recombination process responsible for high luminescence efficiency.
Photoluminescence measurement was performed for GaN epitaxial layrs grown under various conditions by RF-MBE.It was foudn that the sample grown under a Ga-rich condition showed an extremely strong excitonic luminescence line. Temperature dependence of the excitonic luminescence line revealed an abnormal behavior below 150 K.The abnormal linewidth broadening with temperature can not be explained by a typical model of exciton localization in an inhomogeneously-broadened system. We should consider another type of recombination process, such as exciton self-trapping or -capturing due to lattice distortion induced around defect sites.
In the case of an In_<0.08>Ga_<0.92>N ternary alloy epitaxial layr, the photoluminescence spectrum was dominated by an intense si … More ngle broad emission band with a peak energy and a linewidth of 384 nm and 38 meV,respectively, at low temperature. It was found from temperature-dependent and time-resolved photoluminescence measurements that the single broad emission band consisted of two components. Surface-mode stimulated emission was observed under high-density excitation at the energy position of the lower-energy component from low temperature up to room temperature. The origin of the lower-energy component was explained by considering an extrinsic exciton self-trapping due to In clusters in ternary alloys.
We have also observed that the intensity of near-UV luminescence from a Si-doped In_<0.08>Ga_<0.93>N layr with an electron concentration of 2 * 10^<18> cm^<-3> was approximately one order of magnitude stronger than that from an undoped one. It is reasonable to understand that the photogenerated carrier trapping by Si donors takes place effectively before the annihilation of carriers by nonradiative recombination processes. This fact unambiguously indicates that the doping of Si donors into active layrs has a large possibility to enhance the performance of light-emitting devices. Less

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (25 results)

All Other

All Publications (25 results)

  • [Publications] 田口 常正: "Effect of high current injection on the blue radiative recombination in InGaN single quantum well light-emitting diodes" Japanese Journal of Applied Physics. 37(3B)(in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 山田 陽一: "Effects of Si-doping on luminescence properties of In_XGa_<1-X>N epitaxial layers" Journal of Crystal Growth. (in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 田口 常正: "Blue radiative recombination due to hot electrons in InGaN single-quantum-well LEDs" Journal of Crystal Growth. (in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 福田 大祐: "RF-MBE法によるGaN薄膜の成長と光学的評価" 山口大学工学部研究報告. 48(1). 89-93 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 工藤 広光: "InGaN SQW青色LEDの再結合発光におけるホットエレクトロン効果" 山口大学工学部研究報告. 48(1). 95-99 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 内田 章: "MOCVD成長In_XGa_<1-X>N混晶薄膜のフォトルミネッセンス特性" 山口大学工学部研究報告. 48(2)(印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Okada et al.: "Biexciton luminescence from GaN epitaxial layrs" Japanese Journal of Applied Physics. Vol.35, No.6B. L787-L789 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Taguchi et al.: "Time-resolved luminescence spectroscopy of GaN and InGaN epitaxial layrs under high-density excitat" Proceedings of the 23rd International Conference on the Physics of Semiconductors, edited by M.Scheffler and R.Zimmermann (World Scientific, Singapore, 1996). 541-544 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Taguchi et al.: "Effect of high current injection on the blue radiative recombination in InGaN single quantum well light-emitting diodes" Japanese Journal of Applied Physics. Vol.37, No.3B (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yamada et al.: "Effects of Si-doping on luminescence properties of In_xGa_<1-x>N epitaxial layrs" Journal of Crystal Growth. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] S.Kato et al.: "Structural properties and intense ultraviolet emission of polycrystalline GaN films on AIN ceramics grown by N plasma-excited CVD" Journal of Crystal Growth. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Taguchi et al.: "Blue radiative recombination due to hot electrons in InGaN single-quantum-well LEDs" Journal of Crystal Growth. (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Fujimoto et al.: "Luminescence properties of InGaN blue-LEDs under cw and pulsed current inejction" Technology Reports of the Yamaguchi University. Vol.47, No.1 (in Japanese). 87-91 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] D.Fukuda et al.: "Optical properties of GaN epitaxial films grown by RF-MBE" Technology Reports of the Yamaguchi University. Vol.48, No.1 (in Japanese). 89-93 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kudo et al.: "Effect of hot electrons on recombination radiation in InGaN SQW blue LEDs" Technology Reports of the Yamaguchi University. Vol.48, No.1 (in Japanese). 95-99 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Uchida et al.: "Photoluminescence properties of In_xGa_<1-x>N alloy films grown by metalorganic chemical vapor deposition" Technology Reports of the Yamaguchi University. Vol.48, No.2 (in press) (in Japanese). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 田口常正: "Effect of high current injection on the blue radiative recombination in InGaN single quantum well light-emitting diodes" Japanese Journal of Applied Physics. 37(3B)(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山田陽一: "Effects of Si-doping on luminescence properties of In_xGa_<1-x>N epitaxial layers" Journal of Crystal Growth. (in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 田口常正: "Blueradiative recombination due to hot electrons in InGaN single-quantum-well LEDs" Journal of Crystal Growth. (in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 福田大祐: "RF-MBE法によるGaN薄膜の成長と光学的評価" 山口大学工学部研究報告. 48(1). 89-93 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 工藤広光: "InGaN SQW青色LEDの再結合発光におけるホットエレクトロン効果" 山口大学工学部研究報告. 48(1). 95-99 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 内田章: "MOCVD成長In_xGa_<1-x>N混晶薄膜のフォトルミネッセンス特性" 山口大学工学部研究報告. 48(2)(印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 岡田清彦: "Biexciton luminescence from GaN epitaxial layers" Japanese Journal of Applied Physics. 35(6B). L787-L789 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 田口常正: "Time-resolved luminescence spectroscopy of GaN and InGaN epitaxial layers under high-density excitation" Proceedings of the 23rd International Conference on the Physics of Semiconductors. 1. 541-544 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 藤本正克: "InGaN青色LEDの連続発光およびパルス発光特性" 山口大学工学部研究報告. 47(1). 87-91 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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