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Analysis and Control of Ferroelectric/Semiconductor(Metal)Interface for Their Device-Application

Research Project

Project/Area Number 08455150
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionHimeji Institute of Technology

Principal Investigator

NIU Hirohiko  Himeji Institute of Technology, Faculty of Engineering, Professor, 工学部, 教授 (40047618)

Co-Investigator(Kenkyū-buntansha) FUJISAWA Hironori  Himeji Institute of Technology, Faculty of Engineering, Research Assistant, 工学部, 助手 (30285340)
SHIMIZU Masaru  Himeji Institute of Technology, Faculty of Engineering, Associate Professor, 工学部, 助教授 (30154305)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥6,300,000 (Direct Cost: ¥6,300,000)
Fiscal Year 1997: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1996: ¥3,500,000 (Direct Cost: ¥3,500,000)
KeywordsMFS-Device / Ferroelectric thin films / Semiconductor interface / MOCVD / PZT thin films / Ir electrode / MFS型デバイス / 強誘電体 / Ir
Research Abstract

This study has been performed on the interfacial phenomena that heve become of considerable importance in the development of new memory devices by technologically combining ferroelectirc films with silicon devices. The Pb (Zr, Ti) O_3 (PZT) films by MOCVD were used as the experimental ferroelectric species. The importan knowledge derived from this study can be briefly summarized as follows.
1.Good step coverage (76-93%) was obtained for thin PZT films depostied on Ir/SiO_2, whereas deformation of Pt/SiO_2 steps was observed when PZT films were deposited at 600゚C ; this deformation was mainly caused by the diffusion of Pb into the steps.
2.This conductive films of Ir and/or Iro_2 on SiO_2/Si playd the role of an effective barrier in suppressing diffusion of the PZT elements into SiO_2 and, with bottom electrodes composed of them good polarization-fatigue properties were confirmed for the PZT capacitors on SiO_2/Si.
3.For Metal/Ferroelectric/Semiconductor type field effect transister (MFS-FET) to succeed as a non-voltaic memory, two serious difficulties must be overcome : (1) the amount of carrier traps existing at the F/S intreface must be small enough for the field effect to operata well at the S side.
(2)The gate F Of MFS-FET must be designed so that ferroelectric remnant Polarization can operate effectively on the FET channel. The difficulty (1) can be surmounted by high dielectric constant of the F film, while initially, regarding (2), a further investigation will be needed to give more detailed descriptions of the electrical properties of F film or F Capacitor.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (19 results)

All Other

All Publications (19 results)

  • [Publications] Masaru Shimizu et al.: "Step Coverage of Pb(Zr,Ti)O_3 Thin Films Grown by MOCVD" Material Research Society Symposium Proceedings. 433. 201-206 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Hironori Fujisawa et al.: "Simultaneous Observation of the Surface Topography and Current Flow of PZT Thin Films Using an Atomic Force Microscope" Integrated Ferroelectrics. 18. 71-78 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu et al.: "Step Coverage Characterisrics of Pb(Zr,Ti)O_3 thin films on Various Electrode Materials by Metalorganic Chemical Vapor Deposition" Japanese Journal of Applied Physics. 36. 5808-5811 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu et al.: "Properties of Sputtered Ir and IrO_2 Electrodes for PZT Capacitors" The 8th US-Japan Seminar on Dielectric and Piezoelectric Ceramics Extended Abstracts. 124-127 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu et al.: "Effects of Sputtered Ir and IrO_2 Electrodes on the Properties of PZT Thin Films Deposited by MOCVD" Material Research Society Symposium Proceedings. 493(印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu et al.: "Pb(Zr,Ti)O_3 thin film deposition on Ir and IrO_2 electrodes by MOCVD" Proceedings of 9th International Meeting of Ferroelectricty. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu, Hironori Fujisawa, Hirohiko Niu et al.: "Step Coverage of Pb(Zr, Ti)O_3 Thin Films Grown by MOCVD." Material Research Society Symposium Proceedings. 433. 201-206 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Hironori, Fujisawa, Masaru Shimizu, Hirohiko Niu et al.: "Simultaneous Observation of the Surface Topography and Current Flow of PZT Thin Films Using an Atomic Force Microscope." Integrated Ferroelectrics. 18. 71-78 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu, Hironori Fujisawa, Hirohiko Niu et al.: "Step Coverage Characteristics of Pb(Zr, Ti)O_3 thin films on Various Electrode Materials by Metalorganic Chemical Vapor Deposition." Japanese Journal of Applied Physics. 36. 5808-5811 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu, Hironori Fujisawa, Hirohiko Niu et al.: "Properties of Sputtered Ir and IrO_2 Electrodes for PZT Capacotirs." The 8th US-Japan Seminar on Dielectric and Piezoelectric Ceramics Extended Abstracts. 124-127 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu, Hironori Fujisawa, Hirohiko Niu et al.: "Effects of Sputtered Ir and IrO_2 Electrodes on the Properties of PZT Thin Films Deposited by MOCVD." Material Research Society Symposium Proceedings. 493(in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Masaru Shimizu, Hironori Fujisawa, Hirohiko Niu et al.: "Pb(Zr, Ti)O_3 thin film deposition on Ir and IrO_2 electrodes by MOCVD." Proceedings of 9th International Meeting of Ferroelectricty. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] M.Shimizu, H.Fujisawa, H.Niu, et al.: "Step Coverge Characteristics of Pb(Zr,Ti)O_3 thin films on Various Electrode Materials by Metalorganic Chemical Vapor Deposition" Jpn.J.Appl.Phys.36・9B. 5808-5811 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Shimizu, H.Fujisawa, H.Niu, et al.: "Properties of Sputtered Ir and Ir O_2 Electrodes for PZT Capacitors" Extended Abstracts, The 8th US-Japan Seminar on Dielectric and Piezoelectric Ceramics. 124-127 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Shimizu, H.Fujisawa, H.Niu, et al.: "Effects of Sputtered Ir and Ir O_2 Electrodes on the Properties of PZT Thin Films Deposited by MOCVD" Proc., Mater.Res.Soc.Symp.493 (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Shimizu, H.Fujisawa, H.Niu, et al.: "Pb(Zr,Ti)O_3 thin film deposition on Ir and Ir O_2 electrodes by MOCVD" Proc.9th International Meeting of Ferroelectricty. (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] M. Shinmizu et al.: "Step Coverage of Pb (Zr, Ti) O_3 Films Grown by MOCVD" Mat. Rec. Soc. Symp. Proc.,. 433. 201-206 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M. Shinmizu et al.: "MOCVD of Pb-Based Ferroelectric Oxide Thin Films" J. Cryst. Growth. 173. in Press (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] H. Fujisawa et al.: "Simultaneous Observation of Surface Topography and Current Flow of PZT Thin Films Using an Atomic Force Microscope" Integrated Ferroelectrics 9th Int. Symp.(1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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