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A study on the rubber effect and the stabilization phenomenon in shape memory alloys

Research Project

Project/Area Number 08455285
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

MARUKAWA Kenzaburo  Hokkaido Univ., Grad.School of Eng., Pro., 大学院・工学研究科, 教授 (20001191)

Co-Investigator(Kenkyū-buntansha) TSUCHIYA Koichi  Toyohasi Univ.of Tech., Fac.of Eng., Lec., 生産システム工学系, 講師 (50236907)
TAKEZAWA Kazuyoshi  Hokkaido Univ., Grad.School of Eng., Ins., 大学院・工学研究科, 助手 (80001311)
TAKAMA Toshihiko  Hokkaido Univ., Grad.School of Eng., Ass.Pro., 大学院・工学研究科, 助教授 (40001309)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥6,600,000 (Direct Cost: ¥6,600,000)
Fiscal Year 1997: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1996: ¥5,600,000 (Direct Cost: ¥5,600,000)
Keywordsshape memory effect / martensitic transformation / rubber effect / stabilization phenomenon / degree of order / short range order / aging effect / 形状記憶合金 / ゴム状弾性
Research Abstract

In order to improve characteristics of shape memory alloys for a variety of applications, it is necessary to study the nature of martensitic transformation more precisely, because the shape memory effect is brought about by martensitic transformation. Concerning this transformation in copper based shape memory alloys, two important problems remains unsolved so far, which are the rubber effect and the stabilization phenomenon of martensites. The present authors have recently presented a new view that the change in short range order (SRO) due to aging is the cause of these phenomena. The purpose of the present study is to examine this view more closely by experiments and theoretical calculations. The results are summarized in the following.
(1) In copper alloys, the time evolution of the rubber effect and the stabilization due to aging was measured. It was found that these effects become prominent as the aging proceed, and that they have almost the same time constant with each other.
(2) The change in short range order was traced by electrical resistivity measurements and by x-ray diffraction measurements. It was affirmed that the time constant of the SRO change is approximately the same as those of the rubber effect and the stabilization. This results supports the view mentioned above.
(3) The SRO was calculated theoretically as a function of aging temperature in order to clarify the condition of appearance of the rubber effect and the stabilization. It was found that the rubber effect should be most prominent at temperatures around the transition temperature of order-disorder. The dependence of the stabilization on the aging temperature was also clarified.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] K, Tsuchiya: "Study of aging kinetics in copper based alloy martensites," Mater.Trans.JIM. 37(3). 304-308 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 田淵 正幸: "Cu-Zn-Al合金のベイナイト変態に及ぼす外部応力の効果" 日本金属学会誌. 60(11). 1058-1063 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 田淵 正幸: "Cu-Zn-Al合金におけるベイナイト析出とそれに続く変態の過程" 日本金属学会誌. 61(1). 1-7 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K, Takezawa: "Critrcal temperature for ordering and B2 domain structure in Ag-Zn β phase alloys," Mater.Trans.JIM. 39(1). 80-86 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K, Tsuchiya: "Rubber-like behavior and stabilization of martensite in Cu-based shape memory alloys," Displacive Phase Transformations and Their Applications. 148-157 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K, Tsuchiya: "Fcc-fct martensitic transformation and spinodal decomposition in Mu-Cu alloy," Proc.Int.Symp.on Advanced Engineering Materials. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tsuchiya: "Study of aging kinetics in copper based alloy martensites" Mater.Trans.JIM. 37(3). 304-308 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tabuchi: "Effect of applied stress on bainitic transformation in Cu-Zn-Al alloy (inJapanese)" Nihon Kinzoku Gakkaishi. 60(11). 1058-1063 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tabuchi: "Bainitic precipitation and subsequent transformation in Cu-Zn-Al alloy (in Japanese)" Nihon Kinzoku Gakkaishi. 61(1). 1-7 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Takezawa: "Critical temperature for ordering and B2 domain structure in Ag-Zn beta phase alloys" Mater.Trans.JIM. 39(1). 80-86 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tsuchiya: "Rubber-like behavior and stabilization of martensite in Cu-based shape memory alloys" "Displacive Phase Transformations and Their Applications".148-157 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tsuchiya: "Fcc-fct martensitic transformation and spinodal decomposition in Mn-Cu alloy" "Proc.Int.Symp.on Advanced Engineering Materials". (in press). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Tsuchiya: "Study of aging kinetics in copper based alloy martensites," Mater.Trans.JIM. 37(3). 304-308 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 田淵正幸: "Cu-Zn-Al合金のベイナイト変態に及ぼす外部応力の効果" 日本金属学会誌. 60(11). 1058-1063 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 田淵正幸: "Cu-Zn-Al合金におけるベイナイト析出とそれに続く変態の過程" 日本金属学会誌. 61(1). 1-7 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Takezawa: "Critical temperature for ordering and B2 domain structure in Ag-Zn beta phase alloys," Mater.Trans.JIM. 39(1). 80-86 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Tsuchiya: "Rubber-like behavior and stabilization of martensite in Cu-based shape memory alloys," Displacive Phase Transformations and Their Applications. 148-157 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Tsuhiya: "Fcc-fct martensitic transformation and spinodal decomposition in Mn-Cu alloy," Proc.Int.Symp.on Advanced Engineering Materials. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Tsuchiya: "Study of Aging Kinetics in Copper Based Alloy Martensites" Mater.Trans.of Japan Inst.Metals. 37・3. 304-308 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 田淵,正幸: "Cu-Zn-Al合金のベイナイト変態に及ぼす外部応力の効果" 日本金属学会誌. 60・11. 1058-1063 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 土谷浩一: "Cu-Zn-Al合金マルテンサイト相の時効による構造変化と安定化" 高エネルギー超強力X線回折室年報. 13. 17-19 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 田淵正幸: "Cu-Zn-Al合金におけるベイナイト析出とそれに続く変態の過程" 日本金属学会誌. 61・1. 1-7 (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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