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Study on Repassivation Mechanism of Alloys in Molten Salts by Straining Electrode

Research Project

Project/Area Number 08455331
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionTokyo Institute of Technology

Principal Investigator

NISHIKATA Atsushi  Tokyo Institute of Tech., Faculty of Eng.Associate Prof., 工学部, 助教授 (90180588)

Co-Investigator(Kenkyū-buntansha) NODA Kazuhiko  Tokyo Institute of Tech., Faculty of Eng.Research Assist., 工学部, 助手 (60241361)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥8,200,000 (Direct Cost: ¥8,200,000)
Fiscal Year 1997: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1996: ¥7,400,000 (Direct Cost: ¥7,400,000)
KeywordsStraining electrode / Molten salt / high temperature Corrosion / Oxide film / Passivation / stress / Polarization curve / 腐食 / ステンレス鋼 / 不働態皮膜
Research Abstract

1. The straining electrode system used in high temperature molten salts was first established in this study in order to investigate the breakdown and repassivation behavior of SUS304 in NaNO_3-KNO_3 melts containing chloride ions (-50 mol%) at 573K.
2. In the elastic deformation region on the stress-strain curve, the anodic current increased by deformation probably due to decrease in thickness of oxide layr or breakdown of oxide layr.
3. In the plastic deformation region, the anodic current increased due to breakdown of oxide film which was caused by formation of slip step on the surface.
4. The anodic current increased by increasing the strain rate because the formation rate of slip step on the surface becomes higher than the repassivation rate of oxide layr.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] 張弓, 西方 篤, 水流 徹: "ごみ焼却炉模擬環境における合金の耐食性評価への交流インピーダンス法の適用" 日本金属学会誌. 60. 970-979 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.NISHIKATA, G.Zhang, T.Tsuru: "Rapid Evaluation of Corrosion Resistance of Ni-base Alloys in Molten Salts Using AC Impedane Method" Mater.Trans.JIM. 38. 312-318 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 張弓, 西方 篤, 水流 徹: "浸漬試験,塗布試験,埋没試験によるNi基合金の高温耐食性評価" 日本金属学会誌. 61. 587-595 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 西方 篤, 柴橋 威光, 張弓, 水流 徹, 小林 重夫, 占部 武生: "ごみ焼却炉環境での腐食のモニタリング" 材料と環境'97講演集. 137-140 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 西方 篤: "浸漬,埋没,塗布試験の比較と電気化学計測の適用" 第117回腐食防食シンポジウム資料. 27-36 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Zhang, A.Nishikata, T.Tsuru: "Application of AC Impedance Method to Evaluation of Corrosion Resistance of Alloys in Simulated Waste Incinerator Environment" J.Japan Inst.Metals. 60. 970-979 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Nishikata, G.Zhang, T.Tsuru: "Rapid Evaluation of Corrosion Resistance of Ni-base Alloys in Molten Salts Using AC Impedance Method" Mater.Trans.JIM. 38. 312-318 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] G.Zhang, A.Nishikata, T.Tsuru: "Evaluation of High Temperature Corrosion Resistance of Ni-based Alloys Using Immersion, Coating and Embedding tests" J.Japan Inst.Metals. 61. 587-595 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] A.Nishikata, et al.: "Corrosion Monitoring of Alloys in Waste Incinerator Environments" Proc.of ZAIRYO-TO-KANKYO '97. 137-140 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 張弓 西方篤 水流徹: "ごみ焼却炉模擬環境における合金の耐食性評価への交流インピーダンス法の適用" 日本金属学会誌. 60. 970-979 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] A.Nishikata, G.Zhang, T.Tsuru: "Rapid Evaluation of Corrosin Resistance of Ni-base Alloys in Molten Salts Using AC Impedance Method″" Mater.Trans.JIM.38. 312-318 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 張弓 西方篤 水流徹: "浸漬試験、塗布試験、埋没試験によるNi基合金の高温耐食性評価" 日本金属学会誌. 61. 587-595 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 西方篤 柴橋威光 張弓 水流徹 小林重夫 占部武生: "ごみ焼却炉環境での腐食のモニタリング" 材料と環境'97講演集. 137-140 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 西方篤: "浸漬、埋没、塗布試験の比較と電気化学計測の適用" 第117回腐食防食シンポジウム試料. 27-36 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 張弓,西方篤,水流徹: "ごみ焼却炉模擬環境における合金の耐食性評価への交流インピーダンスの適用" 日本金属学会誌. 60. 970-979 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 張弓,西方篤,水流徹: "溶融塩腐食系における電気化学インピーダンスと耐食性評価への応用" 腐食防食'96講演集. 29-32 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 西方篤,柴橋威光,張弓,水流徹: "ごみ焼却炉環境における腐食のセンタリング" 材料と環境'97講演集. (発表予定). (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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