| Project/Area Number |
08455367
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
反応・分離工学
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| Research Institution | Yamaguchi University |
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Principal Investigator |
OKAMOTO Ken-ichi Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (20029218)
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| Co-Investigator(Kenkyū-buntansha) |
TANAKA Kazuhiro Yamaguchi University, Faculty of Engineering, Research Associate, 工学部, 助手 (30188289)
KITA Hidetoshi Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (10177826)
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| Project Period (FY) |
1996 – 1997
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| Project Status |
Completed (Fiscal Year 1997)
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| Budget Amount *help |
¥7,800,000 (Direct Cost: ¥7,800,000)
Fiscal Year 1997: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1996: ¥6,400,000 (Direct Cost: ¥6,400,000)
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| Keywords | Pervaporation / Polyimides / Membrane Separation / Organic Liquid Mixtures Separation / 炭化膜 / オレフィン / パラフィン分離 / 化学修飾 |
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| Research Abstract |
The crosslinked membranes of the phosphorylated polymides displayd higher pervaporation (PV) performance with excellent durability toward aromatic/non-aromatic hydrocarbon mixtures, compared with the base polymide and its homolog membranes, because of the higher solubility selectivity due to affinity of the phosphonate groups to the aromatic hydrocarbons.
Polymides from thianthrene-2,3,7,8-tetracarboxylic dianhydride-5,5-10,10-tetraoxide and diamines were synthesized and the investigation of their PV properties are in progress. Copolyimides from 2,2'-diethynylbenzidine were synthesized. The crosslinking based on the ethynyl groups enhanced the PV performance due to the increased diffusivity selectivity. The addition of tetracyanoethylene was also effective for the improvement of the PV performance.
Carbon molecular sieve membranes wer prepared by pyrolyzing polyimide and polypyrrolone membranes at 500-700 ﾟC in N2. They displayd high performance for gas separation such as propylene/propane.
Poly (glycidyl methacrylate) grafted membranes were prepared using porous high density polyethylene films as substrate. The membranes prepared by the homogeneous both-side plasma treatment and under the mild polymerization conditions displayd the highest PV performance.
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