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Investigation of the decomposition reaction and measurement of the rate coefficient between N_2 (A^3SIGMA^+_) and contamination gas.

Research Project

Project/Area Number 08458167
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 環境保全
Research InstitutionChiba Institute of Technology

Principal Investigator

ITOH Huruo  Chiba Institute of Technology, Department of Electrical Engineering, Professor, 工学部, 教授 (90083849)

Co-Investigator(Kenkyū-buntansha) SUZUKI Susumu  Chiba Institute of Technology, Department of Physics, Assistant, 工学部, 助手 (00265472)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1998: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1997: ¥500,000 (Direct Cost: ¥500,000)
Keywordsmetastable molecule / N_2 (A^3SIGMA^+_) / contamination gas / quenching rate coefficient / CO_2 / CH_2FCF_3 / CF_4 / C_2F_6 / C_3F_8 / 窒素 / 衝突脱励起 / 一酸化窒素 / CCl_2F_2
Research Abstract

It is interested in the destruction of ozone layer by the fluorocarbons and in the atmospheric green-house effect by C0_2, SF_6, CF_4, and so on. In order to remove these contamination gases, the discharge plasma is widely used. In this case1 if the plasma reactor is operated in the atmospheric pressure, it is important to understand the reaction processes between the contamination gas in atmospheric pressure and the nitrogen radicals generated in the plasma reactor. Particularly, the metastable nitrogen molecule N_2(A^3SIGMA^+_) of one of the nitrogen radicals has various effects in the reaction processes in plasmas.
In this research, the loss processes of N_2(A^3SIGMA^+_) by CO_x, NO_x, CCl_2F_2, CH_2FCF_3 CF_4 and C_2F_6 are investigated in Townsend discharge. We systematically determine the collisional quenching rate coefficients of N_2(A^3SIGMA^+_) by them.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] S.Suzuki,H.Okutsuno,H.Itoh,N.Ikuta and H.Sekizawa: "Loss Processes of N_2(A^3Σ^+_u)by CCl_2F_2 and CH_2FCF_3" Proc.of Korea-Japan Symposium on Electrical Discharge and High Voltage Engineering. 175-178 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki,H.Itoh,H.Sekizawa and N.Ikuta: "Quenching rate coefficient of N_2(A^3Σ^+_u)by CF_4" Proc.of the 13th International Symposium on Plasma Chemistry(ISPC-13)(Beijing,China). Vol.I. 59-64 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 鈴木,伊藤,生田: "N_2準安定励起分子のC_nF_<2n+2>(n=1,2,3)による脱励起過程" 電気学会放電研究会資料. ED-97-211. 11-15 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki,H.Itoh,H.Sekizawa and N.Ikuta: "Loss Processes of N_2(A^3Σ^+_u)by Harmful Gases" Jpn.J.Appl.Phys.Vol.36,Part 1,No.7B. 4744-4746 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki,H.Itoh,H.Sekizawa and N.Ikuta: "Determination of Collisional Quenching Rate Coefficient of N_2(A^3Σ^+_u)by Perfluoroalkanes C_nF_<2n+2>(n=1〜3)" 第15回プラズマプロセシング研究会プロシーディングス. 458-461 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 鈴木、伊藤、関澤、生田: "N_2(A^3Σ^+_u)の大気汚染ガスによる衝突脱励起反応速度係数の測定" 電気学会放電研究会資料. ED-98-117. 63-67 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki, H.Okutsuno, H.Itoh, N.Ikuta and H.Sekizawa.: "Loss Processes of N_2 (A^3SIGMA^+_) by CCl_2F_2 and CH_2FCF_3" Proc.of Korea-Japan Symposium on Electrical Discharge and High Voltage Engineering. 175-178 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki, H.Itoh, H.Sekizawa and N.Ikuta: "Quenching rate coefficient of N_2 (A^3SIGMA^+_) by CF_4" Proc.of the 13th International Symposium on Plasma Chemistry (ISPC-13) (Beijing, China). Vol.I. 59-64 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki, H.Itoh and N.Ikuta: "De-excitation Processes of N_2 Metastable Molecules by C_nF_<2n+2> (n=1,2,3)" Papers of Technical Meeting on Electrical Discharges. ED-97-211. 11-15 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki, H.Itoh, H.Sekizawa and N.Ikuta: "Loss Processes of N_2 (A^3SIGMA^+_) by Harmful Gases" Jpn.J.Appl.Phys.Vol.36, Part 1, No.7B. 4744-4746 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki, H.Itoh, H.Sekizawa and N.Ikuta: "Determination of Collisional Quenching Rate Coefficient of N_2 (A^3SIGMA^+_) by Perfluoroalkanes C_nF_<2n+2> (n=1-3)" Proc.of The 15th Symposium on Plasma Processing. 458-461 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki, H.Itoh, H.Sekizawa and N.Ikuta: "Measurements of Collisional Quenching Rate Coefficient of N_2 (A^3SIGMA^+_) by Air Pollution Gases" Papers of Technical Meeting on Electrical Discharges. ED-98-117. 63-67 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Suzuki,H.Itoh,H.Sekizawa and N.Ikuta: "Loss Processes of N_2(A^3Σ^+_u) by Harmful Gases" Japanese Journal of Applied Physics. Vol.36,Part 1,No.7B. 4744-4746 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Suzuki,H.Itoh,H.Sekizawa and N.Ikuta: "Determination of Collisional Quenching Rate Coefficient of N_2(A^3Σ^+_u) by Perfluoroalkanes C_nF_<2n+2>(n=1〜3)" 第15回プラズマプロセシング研究会プロシーディングス. 458-461 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 鈴木、伊藤、関澤、生田: "N_2(A^3Σ^+_u)の大気汚染ガスによる衝突脱励起反応速度係数の測定" 電気学会放電研究会資料. ED-98-117. 63-67 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Suzuki, H.Itoh, H.Sekizawa and N.Ikuta: "Loss Processes of N_2(A^3Σ^+_u) by Harmful Gases" Japanese Journal of Applied Physics Part 1. No.7. 4744〜4746 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Suzuki, H.Itoh, H.Sekizawa and N.Ikuta: "Determination of Collisional Quenching Rate Coefficient of N_2(A^3Σ^+_u) by Perfluoroalkanes C_nF_<2n+2>(n=1〜3)" 第15回プラズマプロセシング研究会プロシ-ディングス. 458-461 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Suzuki,H.Itoh,H.Sekizawa and N.Ikuta: "Loss Processes of N_2(A^3Σ^+_u) by Harmful Gases" Japanese Journal of Applied Physics Part 1. No.7(掲載決定). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Suzuki,H.Okutsuno,H.Itoh,N.Ikuta and H.Sekizawa: "Deexcitation Processes of N_2(A^3Σ^+_u) by Contamination Gases" Contributed paper of 13th European Sectional Conference on the Atomic and Molecular Physics of Ionised Gases (Poprad). B. 453-454 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.Suzuki,H.Okutsuno,H.Itoh,N.Ikuta and H.Sekizawa: "Loss Processes of N_2(A^3Σ^+_u) by CCl_2F_2 and CH_2FCF_3" Proceeding of Korea-Japan Symposium on Electrical Discharge and High Voltage Engineering. 175-178 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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