Project/Area Number |
08554022
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 展開研究 |
Research Field |
Organic chemistry
|
Research Institution | Ehime University |
Principal Investigator |
TANAKA Koichi Ehime University, Dept.of Applied Chemistry, Associate Prof., 工学部, 助教授 (10116949)
|
Project Period (FY) |
1996 – 1997
|
Project Status |
Completed (Fiscal Year 1997)
|
Budget Amount *help |
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1997: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1996: ¥2,000,000 (Direct Cost: ¥2,000,000)
|
Keywords | Optical Resolution / Chiral Recognition / Enantiomer / Separation / Inclusion Crystal / Host Compound / Distilllation / キラル分離 / 不斉認識 / 包接化合物 / 光学活性体 / 光学異性体 / 包接 / ホストーゲスト銹体 |
Research Abstract |
A new optical resolution method for enantiomers by simple distilllation in the presence of optically active host compounds has been developed. Optically active host compounds having high chiral recognition ability have also been designated and prepared. For expmple, 2-hexanol was found to be resolved very efficiently by simple distilllation in the presence of a new tartaric acid dimer host compound.
|