• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Syntheses of high-sensitive polyfunctional complexes and their basic and applied properties

Research Project

Project/Area Number 08554026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Inorganic chemistry
Research InstitutionOchanomizu University

Principal Investigator

FUKUDA Yutaka  INSTITUTION (Ochanomizu University), DEPARTMENT (Chemistry), TITLE OF POSITION (Professor), 理学部, 教授 (30021950)

Co-Investigator(Kenkyū-buntansha) UCHIDA Fumio  INSTITUTION (Fuji-Kagaku), DEPARTMENT (Chemical Institute), TITLE OF POSITION (M, 部長
SATO Noriko  INSTITUTION (Toshiba), DEPARTMENT (Research Institute), TITLE OF POSITION (head, 研究主務
西出 利一  日産(株), 主任研究員
MIZUKAMI Fujio  INSTITUTION (Busshitukagaku-Kogyougijyutukenkyusho), DEPARTMENT (Chemistry), TIT, 物質工学工業技術研究所, 総合企画調査官
YAMADA Shinji  INSTITUTION (Ochanomizu University), DEPARTMENT (Chemistry), TITLE OF POSITION (, 理学部, 助教授 (30183122)
NISHIDE Ri-ichi  INSTITUTION (Nissan), DEPARTMENT (Meterial institute), TITLE OF POSITION (hard o
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥10,900,000 (Direct Cost: ¥10,900,000)
Fiscal Year 1998: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1997: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1996: ¥7,800,000 (Direct Cost: ¥7,800,000)
KeywordsChromotropism / Dinuclear complexes / tetraketone / mixed ligand complexes / spin-crossover complexes / rare-earth metal complexes / スピンクロスオーバ錯体 / 機能性錯体 / ソルバトクロミズム / サーモクロミズム / テトラゲン / 磁気性特性 / 酸化還元反応 / 多核化配位子 / 表示素子材料 / 電気化学
Research Abstract

The aim of this research project is syntheses of new chelate complexes which have ckiromotropic properties. Chromotropism means the reversible color change due to the changes of chemical or physical environmental conditions such as solvents, temperaure, pressure. electron(redax reaction), light, which is called as Solvatochromism, Thermochromism, Piezochromism, Electrochromism. Photochromism. In this research. We could obtain solvato- and thermo-chromism with Ni(ll) and Cu(ll) mixed ligand (mono- or di-nuclear) complexes in various organic solvents. The key factors for observing such kinds of chromorropisms are (1)the complexes which have an intermediate ligand field strength and (2>he donor and acceptor properties of the solvents used. We used some cyclic diamines, linear ones and the terreamine as the partner ligand and various kinds of beta-diketonates. triketonates and tetraketonate as the another partner, We have Obtained some Fe(Il) and Fe(m) spin-crossover complexes which contain polydentate Schiff-base ligands or tridentate his (imidazole)pyridine, For the electrochromic system, we could try to synthesize Mn(Il and Ill) complexes with a stable polyamino-polycarboxylate ligand, In this case, Mn(II) system is color-less and the Mn(III) analogue is deep red, which is very stable and reversible system. We have to try mixed valence system which show interesting electrochromism in future. We have also obtained many kinds of mixed ligand lanthanide complexes which have the quarternary system, i.e., terpyridine(terpy), acerylacetonate(acac). and nitrate (NO3) : Ln(terpy)(acac)(No3)2.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (33 results)

All Other

All Publications (33 results)

  • [Publications] 林かつら他: "Formation and structure of mixed quarternary chelates with late-lanchanide metal cons" Chem.Lett.1998. 1173-1174 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 森幸恵他: "Magnetic field effects on the proto induced electron transfer of 10-methylphenothiazine with 4-(4-cyano benzoyloxy)TEMPO in fluid solutions" Chem.Phys.Lett.286. 446-451 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 鴉浦啓他: "Substituent effects of cis-dioxobio(dithiocarbamato)molybdenum(VI) on redox properties : redox potentials for one electron reduction and second order rate constants for oxygen atom transfer." Inorg.Chim.Acta. 269. 260-268 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 益田晶子 他: "First evaluation of ultra fast(ground state)intramolecular electron transfer rate in solution by NMR spin luetice relaxation, An application" J.Phys.Chem.A. 101. 2245-2253 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] F.Jalilehvand 他: "Syntheses of new coppen(II)mixed ligand complexes and their chromotropic properties in solution and in the solid state" J.Chem.Soc.Dalton Frans.1996. 3251-3256 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 小林由美子 他: "Syneheses and structure of new dinuclear Pd(II)complexes with 1,1,2,2-tetraacetyl ehanate and β-dilectonates" Chem.Lett.1996. 663-664 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 福田豊他 編・著: "詳説 無機化学" 講談社サイエンティフィック, 292 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 大野公一他 編・著: "化学入門" 化学入門 共立出版, 168

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "Ni (II)-Ln (III) complexes of the dinucleating ligand, N,N^1-bis (3-hydroxysalicylidene) ethylenediamine" J.Coord.Chem.38. 347-354 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Kobayashi et al.: "Syntheses and structure of new dinuclear palladium (II) complexes with 1,1,2,2-tetraacetylethanate and beta-diketonates" Chem.Lett.1996. 663-664 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] F.Jalilehvand et al.: "Syntheses and new copper (II) mixed ligand complexes and their chromotropic properties in solution and in the solid state" J.Chem.Soc., Dalton Trans.1996. 3251-3256 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] A.Masuda et al.: "First evaluation of ultrafast (grand state) intramolecular electron transfer rate in solution by NMR spin lattice relaxation. An application to mixed valence biferrocene monocation (Fe (II), Fe (III))" J.Phys.Chem.A.101. 2245-2253 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Sakamoto et al.: "Synthesis and properties of Cu (II)-Ln (III) complexes of N,N^1-bis (3-formyl-5-methylsalicylidene)-1,3-propanediamine" Polyhedron. 16. 3345-3351 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Tanaka et al.: "Synthesis of new cationinc Schiff-base complexes of copper (II) and their selective binding with DNA" Bull.Chem.Soc.Jpn.70. 615-629 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Yamada et al.: "Electronic transitions of ternary copper (II) naphthalenediolate complexes" Bull.Chem.Soc.Jpn.71. 305-313 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Unoura et al.: "Substituent effects of cis-dioxobis (dithiocarbamato) molybdenum (VI) on redox properties ; redox potentials for one electron reduction and second order rate constants for oxygen atom transfer" Inorg.Chim.Acta.269. 260-268 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hayashi et al.: "Formation and structure of mixed quarternary chelates with late-lanthanide metal ions" Chem.Lett.1998. 1173-1174 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Mori et al.: "Nagnetic field effects on the photoinduced electron transfer of 10-methylphenothiazine with 4-, (4-cyanobenzoyloxy) TEMPO in fluid solutions" Chem.Phys.Lett.286. 446-451 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Yamada et al.: "13C-15N Coupling constants in a series of twisted amides : relationship with C (O)-N twist angles" J.Chem.Soc.Chem.Commun.1997. 885-886 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 坂本政臣他: "Ni(II)-Ln(III) complexes of the dinucleating ligand,N,N'-bis(3-hydroxy-salicylidene) ethylonediamine" J.Coord.Chem.38. 347-354 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] 小林由美子他: "Syntheses and structure of new dinuclear palladiums (II) complexes with 1,1,2,2,-tetra acetylethane and β-diketores" Chem.Lett.1996. 663-664 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] Farideh Talileh vand: "Syntheses of new copper (II) mixed ligand complexes and their chromofropic propertces in salution and in the solid state" T.Chem.Soc.,Dalton Trans.1996. 3251-3256 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山田泰教 他: "Electronic transitions of terrary copper (II) naphthalenedilate complexes" Bull.Chem.Soc.Jpn.71. 305-313 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 林かつら 他: "Formation and structure of mixed quarternary chelates with late-lanthanide metal ions" Chem.Lett.1998. 1173-1174 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 森幸恵他: "Magnetic field effects on the photo in duced electron transfer of 10-methylphens thiazine with 4-(4-cyanobenzoyloxy) TEMPO in fluid Solutions" Chem.Phys.Lett.286. 446-451 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 福田 豊 他編著: "評説 無機化学" 講談社 サイエンティファック, 292 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] 大野公一 他: "化学入門" 共立出版, 168 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Yamada et al.: "Electronic Structure of (2,2′-bipyridine)(catecholato)copper(II)" Mol.Cryst.Lig.Ctyst.286. 23-28 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yamada et al.: "Electronic Structure of (catecholato)(1,10-phenan ehroline)copper(II)Intramoleocular Interligand Electronic Interaction" J.Coord .Chem.38. 1-13 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] F.Falilehuand et al.: "Syneheses of new copper(II)mixed ligand complexes and their chromofropic propersties in solution and in the solid state" J.Chem.Soc.Dalton.Frans.1996. 3251-3256 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Kobayashi et al.: "Syneheses and Structure of new dinuclear Pd(II)complexes with 1,1,2,2-tetra a cetylethanate and B-diketonate" Chem.Lett.1996. 663-664 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 福岡 豊 他編著: "詳説 無機化学" 講談社サイエンティフィック, 292 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 大野 公一 他著: "化学入門" 共立出版, 168 (1997)

    • Related Report
      1997 Annual Research Report

URL: 

Published: 1996-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi