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Development of new-type negative ion sources using powdery samples

Research Project

Project/Area Number 08555077
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Electronic materials/Electric materials
Research InstitutionEhime University

Principal Investigator

KAWANO Hiroyuki  Ehime University, Facully of Science, Prof., 理学部, 教授 (50006144)

Co-Investigator(Kenkyū-buntansha) MIYAKE Kiyoshi  日立製作所, 電力電機開発本部, 主任研究員
SASAO Mamiko  文部省核融合科学研究所, 助教授 (00144171)
WADA Motoi  同志社大学, 工学部, 教授 (30201263)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 1998: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1997: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1996: ¥3,400,000 (Direct Cost: ¥3,400,000)
KeywordsNegative ion Sourece / Thermal ion desorption / Electron-stimulated desorption / Desorption energy / Work function / Powdery alkali salts / Powdery alkali earth salts / Temperature-programmed desorption / 粉末状塩型水素化物 / 水素負イオン脱離エネルギー / 熱電子放射 / 水素負イオン / 塩型水素化物 / 離脱エネルギー / エネルギーサイクル
Research Abstract

To develop new-type negative ion sources using powdery samples instead of gases or liquids, compact ion sources designed and manufactured by us were examined with many samples under various conditions. Namely, a small amount (-5 mg) of powder deposited directly on a fine mesh or a metal plate was bombarded by electrons (-100-300 eV, -1-3 mA/0.05 cm^2) emitled from a hot tungsten wire. By this method, such ions as D^-, Li^-, F^-, Na^-, Cl^-, Ag^- and O^- were successfully produced from those powdery samples of LiD, LiI, LiF, NaF, NaCl^-, AgCl and BaO, respectively. Especially, saline hydride (e.g., SrH_2) on a boat-type ribbon heated to -700-900 K was useful for producing H^- by both thermal and election-stimulated desorptions. In this case, electrons were supplied from the heated sample itself without using a special election gun. In other wards, the sample served as a triple source supplying H^-, e^- and SrH_2 (sublimated onto a surrounding slit plate). Both thermal desorption energy of H^- and work function of those active spots created by hydrogen release from the sample were determined by a stepwise or temperature-programmed heating method. The active spots consisting of alkali or alkali-earth metal were destroyed by admission of H_2 or O_2, but recreated by stopping the admission. Theoretical analysis of these results yielded a simple model explaining the mechanism of the thermal desarption. The currents of thee above ions after mass analysis were -10^<-12> - 10^<-9> A/0.05 cm^2 (apparent area of the emitting sample surface) and was constant in time to within *5% for more than -10h.
In condusion, our compact ion sources (-2 cm^3) are usable for producing various negative ions with little release of gases during operation. Much further work, however, is needed to find the best powdery sample and experimental condition for producing a more stronger and stable beam for every ion species of interest.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (40 results)

All Other

All Publications (40 results)

  • [Publications] H.Kawano: "Negative hydrogen ion emission from heated metal hydride powder" Rev.Sci.Instrum.67・3. 1190-1192 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Desorption energy of H^- from heated saline hydrides and their work function effective for thermal electron emission" Thermochim.Acta. 299・1. 81-85 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Ion desorption from Solid surfaces" The Physics of Ionized Gases. 169-183 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 河野 博之: "熱脱離法による負イオンの生成" アイオニクス. 23・7. 55-62 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 河野 博之: "NaH粉末の真空加熱によるH_2, H^-及び熱電子の放出反応" 日本化学会九州支部・中国四国支部合同大会講演要旨集(宮崎). 185 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 河野 博之: "熱脱離法による負イオンの生成" 第44回応用物理学関係連合講演会要旨集(東京). 1371 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Development of compact negative ion source for solid samples" Proc.of the Workshop on Negative Ion Sources and Their Applications. 129-134 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Simultaneous production of H^- by both thermal and electron-stimulated desorptions from saline hydrides" Rev.Sci.Instrum.69・2. 1182-1184 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Thermal electron emission from saline hydrides deposited on a metal surface" Appl.Surf.Sci.(印刷中). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Thermal desorption of H_2, H^- and electron by temperature-programmed heating of saline hydrides in vacuum" Thermchim.Acta. (印刷中). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: "Thermal desorption of H^- from heated saline hydrides" Proc.of the Symp.on Negative Ion Sources and Their Applications(NIFS). (印刷中). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Wada: "Gas release from a compact powdery sample ion source" IEEE Proc.of 12th Ion Implantation Technology. (印刷中). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 和田 元: "小型粉体負イオン源" 負イオン源および負イオンビームとその応用議事録. (印刷中). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, H.Nagayasu, N.Serizawa, H.Ohta and M.Takeda: ""Negative hydrogen ion emission from heated metal hydride powder"" Rev.Sci.Instrum.67. 1190-1192 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, N.Serizawa, M.Takeda, T.Maeda, A.Tanaka and Y.Zhu: ""Desorption energy of H' from heated saline hydrides and their work function effective for thermal electron emission"" Thermochim.Acta. 299. 81-85 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano: ""Ion desorption from solid surfaces-Fundamental research and its applications"" The Physics of Ionized Gases (Proc.of the 18th Int.Symp.on the Phys.of Ionized Gases, Yugoslavia, 1996). 169-183 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, N.Serizawa and A.Tanaka: ""Negative ion production by a thermal desorption method"" Ionics. 23. 55-62 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, N.Serizawa, M.Takeda, T.Maeda, A.Tanaka and Y.Zhu: ""Development of compact negative ion sources for solid Samples"" Pioc.of Workshop on Negative Ion Sources and Their Applications, NIFS, Toki. 129-134 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, N.Serizawa, A.Tanaka, M.Wada, M.Sasao and K.Miyake: ""Simultaneous production of H^- by both thermal and electron-stimulated desorptions from saline hydrides"" Rev.Sci.Instrum.69. 953-955 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, N.Serizawa, A.Tanaka and Y.Zhu: ""Thermal electron emission from saline hydrides deposited on a metal surface"" Appl.Surf.Sci.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, Y.Zhu and A.Tanaka: ""Thermal desorption of H_2, H^- and electron by temperature-programmed heating of saline hydrides in vacuum"" Thermochim. Acta. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Wada, T.Kasuya, M.Sasao and H.Kawano: ""Gas release from a compact powdery sample ion source"" IEEE Proc.of 12th Ion Implantation Technology. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kawano, A.Tanaka, Y.Zhu, M.Wada and M.Sasao: ""Thermal desorption of H^- from healed saline hydrides"" Proc.of Workshop on Negative Ion Sources and Their Applications, NIFS, Toki. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H. Kawano: "Simultaneous production of H^- by both thermal and electron-stimulated desorptions from saline hydrides" Review of Scientific Instruments. 69・2. 1182-1184 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H. Kawano: "Thermal electron emission from saline hydrides deposited on a metal surface" Applied Surface Science,. 印刷中. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H. Kawano: "Thermal desorption of H_2, H^- and electron by temperature-programmed heating of saline hydrides in vacume" Thermochimica Acta. 印刷中. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H. Kawano: "Thermal desorption of H^- from heated saline hydrides" Proceedings of Symposium on Negative Ion Sources and Their Applications, NIFS, Toki, 1999. 印刷中. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] M. Wada: "Gas release from a compact powdery sample ion source" IEEE Proceedings of 12th Ion Implantation Technology. 印刷中. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 和田 元: "小型粉体負イオン源の開発" 負イオン源および負イオンビームとその応用議事録(核融研). 印刷中. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kawano: "Desorption energy of H^- from heated saline hydrides and their work function effective for thermal electron emission" Thermochimica Acta. 299・1. 81-85 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kawano: "Ion desorption from solid surfaces" The Physics of Ionized Gases. 169-183 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 河野博之: "熱脱離法による負イオンの生成" アイオニクス. 23・7. 55-62 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 河野博之: "NaH粉末の真空加熱によるH_2,H^-及び熱電子の放出反応" 日本化学会九州支部・中国四国支部合同大会講演要旨集(宮崎). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kawano: "Development of compact negative ion soarce for sdid samples" Proc. of the Symp. on Negative Ion Sources and Their Applications. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kawano: "Simultaneous production of H^- by both thermal and electron-stimulated desorptions from saline hydrides" Review of Scientific Instruments. 69・2(印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kawano: "Negative hydrogen ion emission from heated metal hydride powder" Rev.Sci.Instrum.67・3. 1190-1192 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kawano: "Desorption energy of H^- from heated Saline hydrides and their work function effective for thermal electron emission" Thermochim.Acta. (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kawano: "Ion desorption from solid surfaces" Proc.18th Symp.Physics of Ionized Gasses,Kotor,Yugoslavia,1996. (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kawano: "Development of compact negative ion source for solid samples" Proc.2nd Symp.Negative Ion Sources and Their Applications,NIFS,Toki,1996. (印刷中).

    • Related Report
      1996 Annual Research Report
  • [Publications] 河野博之: "熱脱離法による負イオンの生成" 第44回応用物理学関係連合講演会要旨集(1997年3月、東京). (印刷中).

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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