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TO REALIZE FERROELECTRIC NON-VOLATILE MEMORIES (MFS) BY USING YMNO_3 AND SURFACE MODIFICATION

Research Project

Project/Area Number 08555078
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Electronic materials/Electric materials
Research InstitutionOSAKA PREFECTURE UNIVERSITY

Principal Investigator

ITO Taichiro  OSAKA PREFECTURE UNIVERSITY,COLLEGE OF ENGINEERING,PROFESSOR, 工学部, 教授 (10081366)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Takashi  ROHM CO., R&D DIVISION,ADVANCED TECHNOLOGY,RESEARCHER, VLSI研究開発部, 研究員
KAMISAWA Akira  ROHM CO., R&D DIVISION,ADVANCED TECHNOLOGY,MANAGER, VLSI研究開発部, 課長
FUJIMURA Norifumi  OSAKA PREFECTURE UNIVERSITY,COLLEGE OF ENGINEERING,ASSOCIATE PROFESSOR, 工学部, 助教授 (50199361)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥15,900,000 (Direct Cost: ¥15,900,000)
Fiscal Year 1997: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1996: ¥13,800,000 (Direct Cost: ¥13,800,000)
KeywordsFERROELECTRIC MEMORY / MFSFET / YMnO_3 / SURFACEMODIFICATION / Y_2O_3 / YbMnO_3 / 強誘電体 / 不揮発性メモリー / VLSI / エピタキシャル成長 / 界面修飾法 / MFS / 誘電特性
Research Abstract

We have studied to realize new MFS-FET type ferroelectric non-volatile memories. There were two problems, large leak currents and small remanent polarizations to realize MFS-FET using the new material, YMnO_3.
To make clear and overcome these problems, we have examined as follows.
(1) YMnO_3 films grown on MgO and Pt substrates have remanent polarization of 0.2muC/cm^2, which is sufficient to operate devices, but those directly on Si substrates do not have remanent polarization because of weak crystallinity. We have tried some surface modification, and found that Y-Mn-O and Y_2O_3 buffer layr improve the crystallinity of YMnO_3. We have confirmed that existence of buffer layr is effective to control the carrier on the Si surface. After examining electric properties, such as C-V and pulse characteristics, we have confirmed fundamental movements as MFS-FET.However, there is still large leak current.
(2) To make clear the origin of leak current, we have examined on bulk samples. We have found that valence fluctuation of Mn leads to the leak current, and substitution of A-site atom by Yb and doping of Zr decrease the leak current. Substitution by Yb decreases the prosess temperature. We do believe that our study is much contributing to realize MFS-FET using RMnO_3.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] N.Aoki: "Formation of YMnO_3 Films Directly on Si Substrate" Journal of Crystal Growth. 174. 796-800 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Yoshimura: "Fabrication of YMnO_3 Thin Films on Si Substrates by a Pulsed Laser Deposition Method" Japanese Journal of Applied Physics. 36. 5921-5924 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Fujimura: "YMnO_3 Thin Films Prepared from Solutions for Non-Volatile Memory Deveices" Japanese Journal of Applied Physics. 36. L1601-L1603 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Yoshimura: "Growth and Properties of YmO_3 Thin Films for Nonvolatile Memories" Journal of Korean Physical society. 32. S1632-S1635 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Aoki, N.Fujimura, T.Yoshimura and T.Ito: "Formation of YMnO_3 Films Directly on Si Substrate" Journal of Crystal Growth.174. 796-800 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, N.Aoki, K.Hokayama, S.Tsukui, K.Kawabata and T.Ito: "Fabrication of YMnO_3 Thin Films on Si Substrates by a Pulsed Laser Deposition Method" Japanese Journal of Applied Physics. 36. 5921-5924 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Fujimura, H.Tanaka, H.Kitahata, K.Tadanaga, T.Yoshimura, T.Ito and T.Minami: "YMnO_3 Thin Films Prepared from Solutions for Non-Volatile Memory Devices" Japanese Journal of Applied Physics. 36. L1601-L1603 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, N.Aoki, K.Hokayama, S.Tsukui, K.Kawabata and T.Ito: "Growth and Properties of YMnO_3 Thin Films for Non-Volatile Memories" Journal of Korean Physical Society. 32. S1632-S1635 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] N.Aoki: "Formation of YMnO_3 Films Directly on Si Substrate" Journal of Crystal Growth. 174. 796-800 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Yoshimura: "Fabrication of YMnO_3 Thin Films on Si Substrates by a Pulsed Laser Deposition Method" Japanese Journal of Applied Physics. 9B1. 5921-5924 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Fujimura: "YMnO_3 Thin Films Prepared from Solutions for Non-Volatile Memory Devices" Japanese Journal of Applied Physics. 36 12A. L1602-L1603 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Yoshimura: "Growth and Electrical Property of YMnO_3 Thin Films on Si Substrate" Symposia proc.of Materials Research Society. (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Yoshimura: "Electrical properties of Y_2O_3 Thin Films as a buffer layer for MFIS type PET" Japanese Journal of Applied Physics. (to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Shimura: "Delectric property Improvement of YMnO_3 by substituting A site ion" Japanese Journal of Applied Physics. (to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] Norifumi Fujimura: "Fabrication of YMnO_3 Films : New Candidate for Non-Volatile Memory Devices" Mat. Res. Soc. Symp. Proc.433. 119-124 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Norifumi Fujimura: "Epitaxially Grown YMnO_3 Film : New Candidate for Nonvolatile Memory Devies" Appl. Phys. Letters. 69・7. 1011-1013 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Norifumi Fujimura: "Growth Mechanism of YMnO_3 Film as a New Candidate for Nonvolatile Memory Devices" J. Appl. Phys.80・12. 7084-7088 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Nobuaki Aoki: "Formation of YMnO_3 Films Directly on Si Substrate" J. Crystal Growth. (in press). (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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