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Research and development of pervaporation and vapor permeation for organic liquid mixtures through zeolite membranes

Research Project

Project/Area Number 08555193
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 反応・分離工学
Research InstitutionYamaguchi University

Principal Investigator

OKAMOTO Kenichi  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (20029218)

Co-Investigator(Kenkyū-buntansha) ABE Jun  Mitsui Engineering and Shipbuilding Co, Engineering Department, Environmental Sy, 環境エネルギー統括部, 主幹研究員
KONDO Masakazu  Mitsui Engineering and Shipbuilding Co, Chiba Laboratory, Manager, 千葉研究所, 主幹研究員
TANAKA Kazuhiro  Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (30188289)
KITA Hidetoshi  Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (10177826)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥10,600,000 (Direct Cost: ¥10,600,000)
Fiscal Year 1998: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1997: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1996: ¥6,500,000 (Direct Cost: ¥6,500,000)
KeywordsMembrane Separation / Zeolite Membrane / Pervaporation / Vapor Permeation / Organic Liquid Separation / Inorganic Membrane / パ-ベ-パレーション
Research Abstract

Zeolite membranes were prepared on the surface of porous tubular support using the hydrothermal synthesis. The surface morphologies of the membranes were characterized by X- ray diffraction and SEM.Based on pervaporation and vapor permeation measurements for organic liquid mixtures, NaA.zeolite membrane showed very high water-selective permeation for water/organic liquid mixture, NaY zeolite membrane showed very high alcohol-selective for alcohol/ether or alcohol/benzene mixtures, and ZSM-5 zeolite membrane showed alcohol-selective for alcohol/water mixtures. The tubular-type modules have been fabricated with NaA zeolite membrane, which has high pervaporation performance, excellent mechanical strength, thermal resistance and extremely high durability to solvents.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] 岡本, 健一: "水蒸気透過膜を利用した分離による反応促進" 触媒. 39・5. 347-352 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 近藤, 正和: "Tubular-type Pervaporation Module with Zeolite NaA Membrane" J.Membr.Sci.133. 133-141 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 岡本, 健一: "ゼオライト膜" J.Ion Exchange. 9・4. 175-182 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 近藤,正和: "有機溶媒脱水用NaA型ゼオライト膜モジュール" 膜. 23・2. 95-99 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多, 英敏: "Preparation of X and Y-type Zeolite Membranes and Pervaporation Properties" Am.Chem.Soe.Symp.Ser.(印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 高木, 俊介: "耐酸性ゼオライト膜の創製" 化学工学シンポジウムシリーズ. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Okamoto: "Promotion of reaction by membrane separation through water-permselective membranes" Syokubai (Catalysis). 39. 347-352 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Kondo, M.Komori, H.Kita, K.Okamoto: "Tubular-type pervaporation module with zeolite NaA membrane" J.Membr.Sci.133. 133-141 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Okamoto: "Zeolite membranes" J.Ion Exchange. 9. 175-182 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Kondo, Y.Matuo, Y.Morigami, J.Abe: "Tubular-type pervaporation module with NaA zeolite membrane" Maku (Membrane). 23. 95-99 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita, H.Asamura, K.Tanaka, K.Okamoto: "Preparation of X and Y-type zeolite membranes and pervaporation properties" Am.Chem.Soc.Symp.Ser.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Takaki, H.Kita, K.Okamoto, M.Kondo: "Preparation of new zeolite membranes with acid resistance" Symp.Ser.Chem.Eng.Jpn.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 岡本,健一: "ゼオライト膜" J.Ion Exchange. 9巻・4号. 175-182 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 高木,俊介: "耐酸性ゼオライト膜の創製" 化学工学シンポジウムシリーズ. (印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 近藤,正和: "有機溶媒脱水用NaA型ゼオライト膜モジュール" 膜. 23巻2号. 95-99 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 喜多,英敏: "Penaporation and Vapor Permeation Using Zeolite Membranes" Proc.China-Japan Symp.Membr.Membrane Processes. 13-14 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 近藤,正和: "Tubular-type parvaporation module with 2eolite NaA membrane" J.Membr.Sci.133巻. 133-141 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 喜多,英敏: "Pervaporation and Vapor Permeation Using Zeolite Membrares" Proc.Int.Cong.Membranes and Membrane Processes(ICOM'96). 1102-1103 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 近藤,正和: "Tubular type Pervaporation Module with Zeolite NaA Membrane" Proc.Int.Cong.Membranes and Membrane Processes(ICOM'96). 390-391 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 喜多,英敏: "NaY zeolite membrane for the pervaporation separation of methanol-methyl-tert-butyl ether mixtures" J.Chem.Soc.,Chem.Commun.45-46 (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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