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Photochemical synthesis of new ionophores and their application

Research Project

Project/Area Number 08555226
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Synthetic chemistry
Research InstitutionGUNMA UNIVERSITY

Principal Investigator

NISHIMURA Jun  Department of Chem., Gunma Univ., prof., 工学部, 教授 (10107352)

Co-Investigator(Kenkyū-buntansha) NAKAMURA Yosuke  Department of Chem., Gunma Univ., Instructor, 有機化学基礎研究センター, 助手 (60261864)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥10,700,000 (Direct Cost: ¥10,700,000)
Fiscal Year 1998: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1997: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1996: ¥5,300,000 (Direct Cost: ¥5,300,000)
Keywords[2+2]photocycloaddition / styrene derivertives / oligo(oxyethylene)linkage / crown compounds / crownophanes / lithiophilic ionophores / extraction / silver metal ion / クラウン化合物 / クラウノファン / クラウノパドラン / リチウムイオン選択性 / ナトリウムイオン選択性 / アザクリプトファン / ホストーゲスト化学 / トリビニルベンゼン
Research Abstract

We have developed intramolecular [2+2] photocycloaddition of styrene derivatives, such as substituted styrene, vinylnaphthalene, vinyiphenanthrene, and so on. The photocyclization showed tether-length dependency ; i.e., the longer the tether becomes, the lower yield is obtained. If oligo(oxyethylene) linkage is used as the tether, however, the yield does not depend on the length and generally becomes quantitative. This tendency has been determined to be due to the flexible property of oligo(oxyethylene) chain.
We were prompted to use this efficient reaction to make a new type of crown compounds (so- called crownophanes) and succeeded in the cultivation of a new ionophore synthetic method.
The prototypical crownophanes showed relatively high Li^+ ion selectivity on the solid-liquid extraction, so we tried to improve the selectivity and found, after several trials, that simply and appropriately modified crownophanes having two cyclobutane linkages (crownopaddlanes) extracted the Li ion exclusively and quantitatively on the extraction experiment.
Next we tried to make crownophanes working efficiently for the extraction of heavy metal cations. We first made some precursors having two hydroxyl groups on the oligo(oxyethylene) linkage or the aromatic nuclei and then treated these functional groups with pyridylmethyl chloride. The modified crownophanes with two pyridine side arms showed high affinity toward Ag^+ ion on the liquid-liquid extraction. Especially, the compound having the side arms on the aromatic nuclei exhibited the excellent selectivity.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (79 results)

All Other

All Publications (79 results)

  • [Publications] Y.Nakamura 他7名: "Photophysical Properties of Various Regioisomers of [60]Fullerene-ο-Quinodimethane Bisadducts" J.Chem.Soc., Perkin Trans.2. 127-131 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada 他3名: "New Ionophores Derived from a Rigid Calixarene Regioisomer" Tetrahedron Lett.in press. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他3名: "Effects of Oligooxyethylene Linkage on Intramolecular[2+2]Photocycloaddition of Styrene Derivatives" J.Phys.Org.Chem.11. 79-8〓 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada 他3名: "A New Intermolecular Photochemical Approach of Calix[4]arene Synthesis" Synlett. 269-270 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Inokuma, K.Kimura, and J.Nishimura: "Photochemical Synthesis of Diazacryptophane" Chem.Lett.287-288 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Inokuma 他4名: "Efficient and Selective Synthesis of Crownopaddlanes Possessing Two Cyclobutane Rings : Exclusive Li+Ion Complexation" J.Org.Chem.63・17. 5791-5796 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Taki 他4名: "[60]Fullerene(A1, D1)-Bisadducts : CD Spectra and Diastereospecific Synthesis" Enantiomer. 3. 231-239 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, M.Mizutani, and J.Nishimura: "Highly selective Li+ion transport by calix[4]arenes" Tetrahedron Lett.39. 8467-8470 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada 他4名: "Characterization of New Rigid Calixarenes Capping Crown Ethers" Tetrahedron Lett.39. 8461-8464 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Taki 他6名: "Selective Functionalization on[60]Fullerene Governed by Tether Length" J.Am.Chem.Soc.109. 926-932 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他3名: "Synthesis of Paddlanes Possessing Cyclophane Shaft and Cyclobutane Blades" Tetrahedron. 53・13. 4593-4600 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他3名: "Synthesis of 1, 8-Naphthylene-Bridged syn-Cyclophanes by Efficient Intramolecular[2+2]Photocycloaddition" Tetrahedron Lett.38・11. 1983-1986 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Yamaji 他3名: "Laser Flash Photolysis Studies on Dynamic Behaviors of Triplet Naphthalenophanes Sensitized by Triplet Benzophenone" J.Chem.Soc., Faraday Trans.93・6. 1065-1070 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他4名: "Interaction between Benzene and Naphthalenophane : In Gas Phase and Crystalline Lattice" Ann./Recueil. 1769-1776 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Taki 他4名: "Synthesis of Polyesters Containing[60]Fullerene Moiety in the Main Chain by Mild Surface Condensation Method" Polym.J.29. 1020-1022 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada 他3名: "A New Class of Chiral Calix[4]arenes as Receptors Having a Plane of Chirality" Tetrahedron Lett.38・52. 9013-9016 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Inokuma 他4名: "Ag^+-Selective Bisaminimides Possessing Oligo(oxyethylene)Linkages" Chem.Lett.123-124 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他6名: "Synthesis, Structure, and Electronic Properties of syn-[2.2]Phenan-threnophanes : First Observation of Their Excimer Fluorescence at High Temperature" J.Am.Chem.Soc.118. 1006-1012 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他5名: "Relaxation Processes in the Exited State of C60-ο-quinodimethane Adducts" J.Chem.Soc., Faraday Trans.92. 377-382 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura 他6名: "Inclusion Crystals from Naphtharenophanes in Aromatic Solvents," Mol.Cryst.Liq.Cryst.276. 105-112 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, K.Endoh, and J.Nishimura: "A New Molecular Cleft for Organic Diols by Using a Rigid Calixarene Analog" J.Soc.Photogr.Sci.Technol.Jpn.59. 471-474 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, T.Mita, and J.Nishimura: "Synthesis and Properties of [2.2](3,3')Biphenylo(3,6)-phenanthrenophane" Tetrahedron Lett.37・22. 3877-3880 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.-R.Gao, S.Inokuma, and J.Nishimura: "Selective Ion Clefts Based on a Three-Bridged[43]Cyclophane" J.Inclusion Phenomena. 23・4. 329-341 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 中村洋介, 西村 淳(分担): "季刊化学総説「炭素第三の同素体フラーレンの化学」" 日本化学会編, 学会出版センター, 東京, 印刷中 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, M.Taki, S.Tobita, H.Shizuka, H.Yokoi, K.Ishiguro, Y.Sawaki, and J.Nishimura: "Photophysical Properties of Various Regioisomers of[60]Fullerene-o-Quinodimethane Bisadducts" J.Chem.Soc., Perkin Trans. 2. 127-131 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, M.Mizutani, F.Ishii, and J.Nishimura: "New Ionophores Derived from a Rigid Calixarene Regioisomer" Tetrahedron Lett.in press. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, T.Fujii, S.Inokuma, and J.Nishimura: "Effects of Oligooxyethylene Linkage on Intramolecular [2+2] Photocycloaddition of Styrene Derivatives" J.Phys.Org.Chem.11. 79-83 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, M.Hagiwara, M.Mineo, and J.Nishimura: "A New Intermolecular Photochemical Approach of Calix[4]arene Synthesis" Synlett. 269-270 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Inokuma, K.Kimura, and J.Nishimura: "Photochemical Synthesis of Diazacryptophane" Chem.Lett.287-288 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Inokuma, M.Takezawa, H.Katoh, Y.Nakamura, and J.Nishimura: "Efficient and Selective Synthesis of Crownopaddlanes Possessing Two Cyclobutane Rings : Exclusive Li^+ Ion Complexation" J.Org.Chem.63(17). 5791-5796 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Taki, Y.Nakamura, H.Uehara, M.Sato, and J.Nishimura: "[60]Fullerene(A_1D_1)-Bisadducts : CD Spectra and Diastereospecific Synthesis" Enantiomer. 3. 231-239 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, M.Mizutani, and J.Nishimura: "Highly selective Li^+ ion transport by calix[4]arenes" Tetrahedron Lett.39. 8467-8470 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, M.Mizutani, F.Ishii, and J.Nishimura: "A Synthesis and Characterization of New Rigid Calixarenes Capping Crown Ethers" Tetrahedron Lett.39. 8461-8464 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Taki, S.Sugita, Y.Nakamura, E.Kasashima, E.Yashima, Y.Okamoto, and J.Nishimura: "Selective Functionalization on [60]Fullerene Governed by Tether Length" J.Am.Chem.Soc.109. 926-932 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, Y.Hayashida, Y.Wada, and J.Nishimura: "Synthesis of Paddlanes Possessing Cyclophane SHaft and Cyclobutane Blades" Tetrahedron. 53(13). 4593-4600 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, M.Matsumoto, Y.Hayashida, and J.Nishimura: "Synthesis of 1,8-Naphthylene-Bridged syn-Cyclophanes by Efficient Intramolecular[2+2] Photocycloaddition" Tetrahedron Lett.38(11). 1983-1986 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Yamaji, K.Shima, J.Nishimura and H.Shizuka: "Laser Flash Photolysis Studies on Dynamic Behaviors of Triplet Naphthalenophanes Sensitized by Triplet Benzophenone" J.Chem.Soc.Faraday Trans. 93(6). 1065-1070 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, H.Suzuki, Y.Hayashida, T.Kudo, and J.Nishimura: "Interaction between Benzene and Naphthalenophane : In Gas Phase and Crystalline Lattice" Ann./Recueil. 1769-1776 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Taki, S.Takigami, Y.Watanabe, Y.Nakamura, and J.Nishimura: "Synthesis of Polyesters Containing [60]Fullerene Moiety in the Main Chain by Mild Surface Condensation Method" Polym.J.29. 1020-1022 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, M.Mizutani, F.Ishii, and J.Nishimura: "A New Class of Chiral Calix[4]arenes as Receptors Having a Plane of Chirality" Tetrahedron Lett.38(52). 9013-9016 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Inokuma, H.Satoh, T.Yasuda, S.Nishioka, and J.Nishimura: "Ag^+-Selective Bisaminimides Possessing Oligo(oxyethylene)Linkages" Chem Lett.123-124 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, T.Tsuihiji, T.Mita, T.Minowa, S.Tobita, H.Shizuka, and J.Nishimura: "Synthesis, Structure, and Electronic Properties of syn-[2.2]Phenanthrenophanes : First Observation of Their Excimer Fluorescence at High Temperature" J.Am.Chem.Soc.118. 1006-1012 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, T.Minowa, Y.Hayashida, S.Tobita, H.Shizuka, and J.Nishimura: "Relaxation Processes in the Exited State of C60-o-quinodimethane Adducts" J.Chem.Soc.Faraday Trans.92. 377-382 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, T.Kitada, T.Kushima, T.Kudo, J.Nishimura, N.Tatsuta, and O.Yamashita: "Inclusion Crystals from Naphtharenophanes in Aromatic Solvents" Mol.Cryst.Liq.Cryst.276. 105-112 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Okada, K.Endoh, and J.Nishimura: "A New Molecular Cleft for Organic Diols by Using a Rigid Calixarene Analog" J.Soc.Photogr.Sci.Technol.Jpn.59. 471-474 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura, T.Mita, and J.Nishimura: "Synthesis and Properties of [2,2](3,3')Biphenylo(3,6)phenanthrenophane" Tetrahedron Lett.37(22). 3877-3880 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.-R.Gao, S.Inokuma, and J.Nishimura: "Selective Ion Clefts Based on a Three-Bridged[4_3]Cyclophane" J.Inclusion Phenomena. 23(4). 329-341 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Nakamura他7名: "Photophysical Properties of Various Regioisomers of[60]Fullerene-o-Quinodimethane Bisadducts" J.Chem.Soc.,Perkin Trans.2. 127-131 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Okada他3名: "New Ionophores Derived from a Rigid Calixarene Regioisomer" Tetrahedron Lett.(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Nakamura他3名: "Effects of Oligooxyethylene Linkage on Intramolecular[2+2]Photocycloaddition of Styrene Derivatives" J.Phys.Org.Chem.11. 79-83 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Okada他3名: "A New Intermolecular Photochemical Approach of Calix[4]arene Synthesis" Synlett. 269-270 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Inokuma,K.Kimura,and J.Nishimura: "Photochemical Synthesis of Diazacryptophane" Chem.Lett.287-288 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Inokuma他4名: "Efficient and Selective Synthesis of Crownopaddlanes Possessing Two Cyclobutane Rings:Exclusive Li+Ion Complexation" J.Org.Chem.63・17. 5791-5796 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Taki他4名: "[60]Fullerene(A1,D1)-Bisadducts:CD Spectra and Diastereospecific Synthesis" Enantiomer. 3. 231-239 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Okada,M.Mizutani,and I.Nishimura: "Highly selective Li+ion transport by calix[4]arenes" Tetrahedron Lett.39. 8467-8470 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Okada他4名: "Characterization of New Rigid Calixarenes Capping Crown Ethers" Tetrahedron Lett.39. 8461-8464 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 中村洋介,西村 淳(分担): "季刊化学総説「炭素第三の同素体フラーレンの化学」" 日本化学会編,学会出版センター,東京(印刷中), (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Taki: "Selective Functionalization on [60]Fullerene Governed by Tether Length" J.Am.Chem.Soc.109. 926-932 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura: "Synthesis of Paddlanes Possessing Cyclophane Shaft and Cyclおbutane Blades" Tetrahedron. 53(13). 4593-4600 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura: "Synthesis of 1,8-Naphthylene-Bridged syn-Cyclophanes by Efficient Intramolecular[2+2]Photocycloaddition" Tetrahedron Lett.38(52). 1983-1986 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Yamaji: "Laser Flash Photolysis Studies on Dynamic Behaviors of Triplet Naphthalenophanes Sensitized by Triplet Benzophenone" J.Chem.Soc.,Faraday Trans.93(6). 1065-1070 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura: "Interaction between Benzene and Naphthalenophane:In Gas Phase and Crystalline Lattice" Ann./Recueil. 1769-1776 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Taki: "Synthesis of Polyesters Containing[60]Fullerene Moiety in the Main Chain by Mild Surface Condensation Method" Polym.J.29. 1020-1022 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Okada: "A New Class of Chiral Calix[4]arenes as Receptors Having a Plane of Chirality" Tetrahedron Lett.38(52). 9013-9016 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura: "Effects of Oligooxyethylene Linkage on Intramolecular[2+2] Photocycloaddition of Styrene Derivatives" J.Phys.Org.Chem.11. 1-5 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Okada: "A New Intermolecular Photochemical Approach of Calix[4]arene Synthesis" Synlett. in press. (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Inokuma: "Photochemical Synthesis of Diazacryptophane" Chem.Lett.in press. (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakamura: "Fullerene-Vol.4:Recent Advances in the chemistry and physics of fullerenes and related materials" Ed.by K.M.Kadish and R.S.Ruoff,Electrochemical Society,Inc., 1248(37-44) (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Inokuma: "Ag^+-selective Bisaminimides Possessing Oligo (oxyethylene) Linkages" Chem.Lett.123-124 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Nakamura: "Synthesis,Structure,and Electronic Properties of syn-[2,2]Phenanthrenophanes : First Observation of Their Excimer Fluorescence at High Temperature" J.Am.Chem.Soc.118. 1006-1012 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Nakamura: "Relaxation Processes in the Exited State of C60-o-quinodimethane Adducts" J.Chem.Soc.,Faraday Trans.92. 377-382 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Nakamura: "Inclusion Crystals from Naphtharenophanes in Aromatic Solvents" Mol.Cryst.Liq.Cryst.276. 105-112 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Okada: "A New Molecular Cleft for Organic Diols by Using a Rigid Calixarene Analog" J.Soc.Photogr.Sci.Technol.Japan. 59. 471-474 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Nakamura: "Synthesis and Properties of [2,2] (3,3') Biphenylo (3,6) phenanthrenophane" Tetrahedron Lett.37(22). 3877-3880 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] S.-R.Gao: "Selective Ion Clefts Based on a Three-Bridged [43] Cyclophane" J.Inclusion Phenomena. 23(4). 329-341 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 中村洋介: "フラーレンの化学の最近の進歩 その1-[60]フラーレンへのオルトキノジメタンおよびその類縁体の付加反応・生成物の物性." 有機合成化学協会誌. 54. 574-579 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 中村洋介: "グラフ理論と辺ラベル法" 有機合成化学協会誌. 54. 623-623 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Taki: "Selective Functionalization on [60] Fullerence Gorverned by Tether Length." J.Am.Chem.Soc.(in press). (1997)

    • Related Report
      1996 Annual Research Report
  • [Publications] M.Yamaji: "Laser Flash Photolysis Studies on Dynamic Behaviors of Triplet Naphthalenophanes Sensitized by Triplet Benzophenone" J.Phys.Chem.(in press). (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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