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Electrical Conductivity and Magnetism in Metallic carbides Encapsulated in Fullerenes

Research Project

Project/Area Number 08640466
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionIwaki Meisei University

Principal Investigator

YOSIDA Yositaka  Iwaki Meisei University・College of Science and Engineering, Professor, 理工学部, 教授 (20107444)

Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1997: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1996: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsFullerenes / Carbon nanotubes / Carbon nanocages / Electrical conductivity / Magnetism / Rare earth metallic carbides / 内包フラレン
Research Abstract

I.Rare earth dicarbides crystals (RC_2 ; R=La, Ce, Pr, Nd, Gd, Tb, Dy, Ho, Er, Tm, and Lu) encapsulated in carbon nanocages or nanotubes are synthesized. A role of an eutectic reaction for the RC_2-C systems giving rise the encapsulation compounds is pointed out. The results are published in Physica B and Carbon.
II.Electrical resistance in pressed samples composed of multiwalled carbon nanotubes is described in terms of Mott's law for three-dimensional (3D) variable range hopping (VRH) conduction. While that in pressed samples of three porous systems composed of carbon nanocages in which LaC_2, CeC_2, or GdC_Z crystals are encapsulated is described in terms of Mott's law for 2D VRH conduction. The low field magnetotransport features support a predicted quantum interference effect on 3D or 2D VRH conduction. The results are published in Applied Physics Letters and Journal of Applied Physics.
III.A systematic study of magnatization curves for CeC_2 crystals encapsulated in carbon nanocages in magnetic fields up to 42 T in the low-temperature antiferromagnetic region revealed a phase transition between an antiferromagnetic and spin-flop state at Hc-3.5T,and that between the spin-flop and paramagnetic state at a particular field Hs<15T.The magnetic phase diagram in the applied field and temperature plane is accurately determined based on the results of Hc (Ta) and Hs (T). The results will be published.

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (17 results)

All Other

All Publications (17 results)

  • [Publications] Y.Yosida: "Variable range hopping conduction in LaC_2,CeC_2,or GdG_2 crystals encapsalated in carbon nanocages" Applied Physics Letters. 69. 586-588 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "A new type of ultrafine particles:Rare earth dicarbides crystals encapsulated in carbon nanocages" Physica B. 229. 301-305 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Structural Property of single crystals of graphite obtained in DC arc experiments" Carbon. 35. 1837-1838 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Variable range hopping conduction in multiwalled carbon nanotubes" Journal of Applied Phgsics. (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Observations of a prewrsor for carbon nanotubes in the hard deposit obtrined in dc arc experiments" Carbon. (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Variable range hopping conduction in LaC_2, CeC_2, or GdC_2 crystals encapsulated in carbon nanocages" Applied Physics Letters. 69-4. 586-588 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "A new type of ultrafine particles : Rare earth dicarbides crystals encapsulated in carbon nanocages" Physica B. 229. 301-305 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Structural property of single crystals of graphite obtained in DC arc experiments" Carbon. 35-12. 1837-1838

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Variable range hopping conduction in multiwalled carbon nanotubes" Journal of Applied Physics. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yosida: "Observations of a precursor for carbon nanotubes in the hard deposit obtained in dc arc experiments" Carbon. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Y.Yoshida: "Variable range hopping conduction in LaC_2,CeC_2,or GdC_2 crgstals encapsulated in carbon nanocages" Applied Physics Letters. 69・4. 586-588 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yoshida: "A new tye ultrafine particles : Rare earth dicarbide ergstrls encapsulated in carbon nanocages" Physica B. 229. 301-305 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yoshida: "Structural Property of single crystals of graphite oftained in DC are experiments" Carbon. 35・12. 1837-1838 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yoshida: "Variable range hopping oenduction in multtualled carbon nanotubes" Journal of Applied Physics. (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yoshida: "Observatims of a precurs or for carbon nanotubos in the harddeposct obtained in dc are experiments" Carbon. (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Yosida: "Variable-Range Hopping Conduction in Lac_2,Cec_2,or Gdc_2 Crystals Encapsulated Carbon Nanocagas" Applied Physics Letters. 69・4. 586-588 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Y.Yosida: "A new-type of Ultrafine Particles-Rare-certh Dicarbide crystals Encapsulated in Carbon Nanocages" Physpica B. 229・3-4. 301-305 (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2020-05-15  

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