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STUDY ON IMPROVEMENT OF MECHANICAL PROPERTIES OF CFRP DUE TO RUBBER MODIFICATION OF EPOXY MATRIX USING SUBMICRON SPHERES

Research Project

Project/Area Number 08650125
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Materials/Mechanics of materials
Research InstitutionDOSHISHA UNIVERSITY

Principal Investigator

FUJII Toru  DOSHISHA UNIV., DEPT.MECH.ENG., PROFESSOR, 工学部・機械システム工学科, 教授 (20156821)

Co-Investigator(Kenkyū-buntansha) MATSUOKA Takashi  DOSHISHA UNIV., DEPT.MECH.ENG., ASSOC.PROFESSOR, 工学部・エネルギー機械工学科, 助教授 (80173813)
Project Period (FY) 1996 – 1997
Project Status Completed (Fiscal Year 1997)
Budget Amount *help
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1997: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1996: ¥1,300,000 (Direct Cost: ¥1,300,000)
KeywordsCFRP / RUBBER MODIFICATION / SUBMICRON SPHERES / CNBR / ADHESIVE STRENGTH / EPOXY RESIN / FATIGUE / INTER-LAMINAR STRENGTH / エポキン樹脂
Research Abstract

Firstly, in order to obtain information on improvement of interfacial strength properties between rpoxy eesin and substrate due to rubber modification using submicron CNBR (Cross-linked acrylo Nitrile Butadiene Rubber : 70-100 nm in diameter) spheres, adhesive strenghts of an epoxy resin under Mode I loadings (both static and cyclic) were examined using DCB specimens. The experimental results revealed that The adhesive strength of the epoxy resin became maximum when the CNBR volume fraction was 10%. The interfacial strengths were greatly improved due to CNBR rubber modification under static loading as well as under cyclic loading when the fatigue crack growth rate was relatively high. In both cases, fracture occurred in a cohesive manner while interfacial failure occurred at low crack velocity including near threshold. In this case, the threshold was not improved due to rubber modification.
Crabon fabric was used to evaluate the effect of rubber modification of epoxy matrix on strength … More properties of CFRP.The laminates used in the study were fabricated by the hand-lay-up method. Tensile and compressive strenghts under static loading and fatigue strength at several temperatures were measured as well as inter-laminar strength under Mode I loading. The following conclusions were drawn from the experiment. Mode I inter-laminar strength (fracture toughness) is greatly improved due to CNBR modification at a wide range of environmental temperature. It is more than two times higher than that for unmodified cases. Impact strength is also improved while on strength reduction in tension at any test temperature occurs as well as in compression. No reduction in Tg (glassy transition temperature) due to CNBR modification is found as well. That is one of reason for no degradaiton in both tensile and compressive strength properties. CNBR modification of epoxy matrix does not badly affects on the fatigue life of CFRP.Any life reduction was found due to inclusion of submicron spheres of CNBR. Less

Report

(3 results)
  • 1997 Annual Research Report   Final Research Report Summary
  • 1996 Annual Research Report
  • Research Products

    (26 results)

All Other

All Publications (26 results)

  • [Publications] 藤井 透 他: "エポキシ系接着剤のモードI荷重下における接着破面とフラクタル(第1報,静的き裂進展特性とフラクタル次元)" 日本機械学会論文集(A編). 62. 2594-2600 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 藤井 透 他: "エポキシ系接着剤のモードI荷重下における接着破面とフラクタル(第2報,疲労き裂進展特性とフラクタル次元)" 日本機械学会論文集(A編). 63. 893-900 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 藤井 透 他: "高じん性化エポキシ系接着剤のモードI荷重下における疲労亀裂進展特性 -き裂進展特性に及ぼすガラスビーズ混入/ゴム変性,接着剤層暑さの影響-" 日本機械学会論文集(A編). 63. 1634-1641 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru FUJII et.al.: "Effect of Temperature and Crack Tip Opening Rate on Fracture Behavior of CNBR Modified Epoxy Adhesives under Mode I loading" SAE Tech.Paper Series 970661. (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] 藤井 透 他: "高じん性エポキシ系接着剤のモードI荷重下における疲労き裂進展特性 -疲労き裂進展に及ぼすゴム/ガラス粒子体積含有率及び粒子径の影響-" 日本接着学会誌. 33. 364-357 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] Toru FUJII et.al.: "Effects of rubber modification of matrix and temperature on strength properties of cabon/epoxy composites" Proc,of MACM "98,The Int.Conf.on Marine Applications of Compo.Mate.(1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and Toru FUJII: "Fatigue Fracture Characterisitics of Toughened Epoxy Adhesive under Mode I loading-Effect of Glass Beads and CNBR Rubber Modification" SAE Tech.Paper Series 960576. (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and Toru FUJII: "Fractured surfaces of epoxy adhesibes and fractals under Mode I loading (1st Report, Static crack growth properties and fractal dimensions)" Trans.of the Japan Soc.of Mech.Engineers A,JSME. Vol.62, No.603. 2594-2600 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and Toru FUJII: "Fractured surfaces of epoxy adhesives and fractals under Mode I loacing (2nd Report, Fatigue crack growth propertties and fractal dimensions)" Trans.of the Japan Soc.of Mech. Engineers A,JSME. Vol.63, No.609. 893-900 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and T.FUJII: "Fatigue crack propagation properties of toughened epoxy adhesives under mode I loading (Effects of glass bead reinforcement, rubber modification and adhesive thickness on crack growth" Trans.of the Japan Soc.of Mech.Engineers A,JSME. Vol.63, No.612. 1634-1641 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and T.FUJII: "Effect of temperature and crack tip opening rate on fracture behavior of CNBR modified epoxy adhesives under mode I loading" SAE Tech.Paper Series 970661. (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and T.FUJII: "Fatigue crack propagation properties of toughened epoxy adhesives under Mode I loading-Effects of volume fraction and particle size on fatigue crack growht-" J.of Adhesion Soc.of Japan.Vol.33, No.9. 349-357 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito and T.FUJII: "Fraactured surfaces of Adhesives and Fractals-Basics and their applications for characterizing fractured surfaces-" J.of Adhesion Soc.of Japan.Vol.34, No.3. 111-117 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] H.Kurochi, K.Takemura and T.FUJII: "Effect of rubber modification of matrix and temperature on strength properties of cabon/epoxy composites" Proc.of MACM "98, The Int.Conf.on Marine Applications of Compo. Mate, Composites Education Association. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] K.Naito, H.HIRAKATA and T.FUJII: "Effect of Surface Treatment for steel adherends on static and ftgiue crack growth of epoxy adhesives" Composite Interfaces. (to appear). (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1997 Final Research Report Summary
  • [Publications] TORU FUJII et. al.: "Fatigue Fracture Characteristics of Toughened Epoxy Adhesive under Mode I loading-Effect of Glass Beads and CNBR Rubber Modification" SAE Tech. Paper Series 960576. (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 藤井 透 他: "エポキシ系接着剤のモードI荷重下における接着破面とフラクタル(第1報,静的き裂進展特性とフラクタル次元)" 日本機械学会論文集(A編). 62巻603号. 2594-2600 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 藤井 透 他: "エポキシ系接着剤のモードI荷重下における接着破面とフラクタル(第2報,疲労き裂進展特性とフラクタル次元)" 日本機械学会論文集(A編). 63巻609号. 893-900 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 藤井 透 他: "高じん性化エポキシ系接着剤のモードI荷重下における疲労亀裂進展特性〜き裂進展特性に及ぼすガラスビーズ混入/ゴム変性,接着剤層暑さの影響〜" 日本機械学会論文集(A編). 63巻612号. 1634-1641 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Toru FUJII et.al.: "Effect of Temperature and Crack Tip Opening Rate on Fracture Behavior of CNBR Modified Epoxy Adhesives under Mode I loading" SAE Tech. Paper Series 970661. (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Toru FUJII et.al.: "Effect of rubber modification of matrix and temperature on strength properties of cabon/epoxy composites" Proc. of MACM '97(USA). (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Toru FUJII et.al.: "Fatigue Fracture Characteristics of Toughened Epoxy Adhesive under Mode I Ioading-Effect of Glass Beads and CNBR Rubber Modification" SAE Tech. Paper series 960576. (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Toru FUJII et.al.: "Effect of Loading Path on the Stress-Strain Relation and Progressive Damage of Polymer-Matrix Composites under Tension/Torsion Biaxial Loading" J.Thermoplastic Composite Materials. Vol.9. 329-341 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 藤井透他: "エポキシ系接着剤のモードI荷重下における接着破面とフラクタル" 日本機械学会論文集(A編). 62巻603号. 2594-2600 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Toru FUJII et.al.: "Benchmark tests on adhesive strengths in butt,single and doudle lap joints and double-cantilever beams" Int.J.Adhesion and Adhesives. Vol.16,No.4. 219-226 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] Toru FUJII et.al.: "Effect of Temperature and Crack Tip Opening Rate on Fracture Behavior of CNBR Modified Epoxy Adhesives under Mode I loading" SAE Tech.Paper Series 970661. (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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