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Polymerization of Dendritic Macromonomer and Preparation of its membrane for Permseparation

Research Project

Project/Area Number 08651048
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionNiigata University

Principal Investigator

OIKAWA Eizo  Niigata University, Faculty of Engineering, Professor, 工学部, 教授 (00018467)

Co-Investigator(Kenkyū-buntansha) KANEKO Takashi  Niigata University, Faculty of Engineering, Assistant, 工学部, 助手 (90272856)
Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1998: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1997: ¥600,000 (Direct Cost: ¥600,000)
Keywordsdendrimer / monodendron / polydendron / poly (phenylacetylene) / phenyleneethynylene / rhodium catalyst / palladium catalyst / permselective membrane / デンドリマ-
Research Abstract

The well-defined side-chain structure of dendrimers is expected to play an important role on the permselectivity for highly selective membranes. We synthesized dendritic phenylacetylene monomers containing tert-butyl group, trimethylsilyl group, or oligodimethylsiloxane, as the peripheral group using the convergent approach. The monomers were polymerized with rhodium catalyst at the terminal acetylene unit to yield the corresponding poly(phenylacetylene) derivatives as yellow powders with a high degree of polymerization, e.g., DP=2.8 x 10^3, in spite of their steric bulkiness. Some reasons why the monodendrons gave the polydendrons with high molecular weight in spite of their steric bulkiness were probably considered as follows. The terminal acetylene was exposed from dendritic crowd, and the polymerization proceeded stereoregularly to give the reasonable packing of the side-chain dendrons. The polymers were soluble in common organic solvents, such as chloroform and tetrahydrofuran, but insoluble in alcohols, and the solubility of these polydendrons was better than that of the corresponding zero generation poly(phenylacetylene) derivatives. The wide angle X-ray scattering of the polymers suggested the pseudohexagonal lattice of rod-like molecules. The interplanar d spacing increased with increasing generation or size of the peripheral silyl group. The polydendrons indicated good membrane forming ability, and the gas permeability of the membrane was examined. The oxygen permselectivity of the polydendrons showed good performance in comparison with the corresponding zero generation of poly(phenylacetylene) derivatives. It was found that the well-defined dendritic and rod-like structure of the polydendrons was useful for pemselective membrane.

Report

(4 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (21 results)

All Other

All Publications (21 results)

  • [Publications] Kaneko, Takashi: "Polydendron : Polymerization of Dendritic Phenylacetylene Monomers" Macromolecules. 30巻10号. 3118-3121 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 金子 隆司: "フェニルアセチレンモノデンドロンの合成と重合" 日本化学会第72回春季年会予稿集. 72巻1号. 734-734 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 金子 隆司: "空間の制御されたかさ高い側鎖を持つフェニルアセチレンモノマーの合成と重合" 高分子学会予稿集(第46回高分子討論会). 46巻7号. 1245-1246 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 金子 隆司: "フェニルアセチレンモノデンドロンの合成と重合およびポリマーの特性" 高分子学会予稿集(第47回高分子学会年次大会). 47巻2号. 295-295 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 金子 隆司: "シリル基を有するフェニルアセチレンモノデンドロンの合成と重合および酸素選択透過膜素材としての性能" 高分子学会予稿集(第47回高分子討論会). 47巻8号. 1716-1717 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kaneko, Takashi: "Polymerization of(p-Vinylphenyl)hydrogalvionoxyl and Formation of a Stable Polyradical Derivative" Journal of Polymer Science : Part A : Polymer Chemistry. 37巻2号. 189-198 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Keneko, Takahiro Horie, Motohiro Asano, Toshiki Aoki, Eizo Oikawa: ""Polydendron : Polymerization of Dendritic Phenylacetylene Monomers"" Macromolecules. 30 (10). 3118-3121 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Kaneko, Motohiro Asano, Takahiro Horie, Toshiki Aoki, Eizo Oikawa: ""Syntheisi and Polymerization of Dendritic Phenylacetylene Macromonomer"" Chemical Society of Japan. 72 (2). 734 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Kaneko, Takahiro Horie, Toshiki Aoki, Eizo Oikawa: ""Synthesis and Polymerization of Phenylacetylene Monomers with Space-persistent Side-chain"" Polymer Preprints, Japan. 46 (7). 1245-1246 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Kaneko, Motohiro Asano, Toshiki Aoki, Eizo Oikawa: ""Synthesis and Polymerization of Phenylacetylene Monodendrons and Characterization of the Polymers"" Polymer Preprints, Japan. 47 (2). 295 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Kaneko, Motohiro Asano, Kazuto Yamamoto, Toshiki Aoki, Eizo Oikawa: ""Synthesis and Polymerization of Phenylacetylene Monodendrons Containing Silyl group, and Application for Oxygen Permselective Membrane Materials"" Polymer Preprints, Japan. 47 (8). 1716-1717 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Kaneko, Hiroyuki Tatsumi, Toshiki Aoki, Eizo Oikawa, Hajime Yoshiki, Naoki Yoshioka, Eishun Tsuchida, Hiroyuki Nishide: ""Polymerization of (p-Vinylphenyl) hydrogalvinoxyl and Formation of a Stable Polyradical Derivative"" Journal of Polymer Science. A37. 189-198 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 金子 隆司: "フェニルアセチレンモノデンドロンの合成と重合およびポリマーの特性" 高分子学会予稿集(第47回高分子学会年次大会). 47巻2号. 295-295 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 金子 隆司: "シリル基を有するフェニルアセチレンモノデンドロンの合成と重合および酸素選択透過膜素材としての性能" 高分子学会予稿集(第47回高分子討論会). 47巻8号. 1716-1717 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 金子 隆司: "オリゴジメチルシロキサン鎖を持つ分岐フェニルアセチレンモノマーの合成と重合" 第47回高分子学会北陸支部研究発表会予稿集. 47巻1号. 22-22 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kaneko,Takashi: "Polymerization of (p-Vinylphenyl)hydrogalvinoxyl and Formation of a Stable Polyradical Derivative" Journal of Polymer Science:Part A:Polymer Chemistry. 37巻2号. 189-198 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kaneko,Takashi: "Polydendron:Polymerization of Dendritic Phenylacetylene Monomers" Macromolecules. 30巻10号. 3118-3121 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 金子 隆司: "フェニルアセチレンモノデンドロンの合成と重合" 日本化学会第72回春季年会予稿集. 72巻2号. 734-734 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 金子 隆司: "空間の制御されたかさ高い側鎖を持つフェニルアセチレンモノマーの合成と重合" 高分子学会予稿集. 46巻7号. 1245-1246 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 金子隆司: "樹上に広がった側鎖を持つポリ(フェニルアセチレン)誘導体の合成" 日本化学会第70春季年会予稿集. 70(2). 771-771 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] 金子隆司: "剛直な樹状側鎖を持つポリ(フェニルアセチレン)誘導体の合成" 高分子学会北陸支部第45回研究発表会講演要旨集. 45. 7-7 (1996)

    • Related Report
      1996 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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