| Project/Area Number |
08672437
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | Nagoya City University |
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Principal Investigator |
SATO Yoshiro Nagoya City University Faculty of Pharmaceutical Sciences, Professor, 薬学部, 教授 (80080183)
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| Project Period (FY) |
1996 – 1997
|
| Project Status |
Completed (Fiscal Year 1997)
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| Budget Amount *help |
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1997: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1996: ¥1,800,000 (Direct Cost: ¥1,800,000)
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| Keywords | ammonium ylide / sulfonium ylide / [2,3]sigmatropic rearrangement / Sommelet-Hauser rearrangement / Stevens rearrangement / organosilicon compound / organotin compound / fluoride ion / Sommelet-Hauser転位 / [2,3]シグマトロピー転位 / フッ素化合物 |
|---|
| Research Abstract |
Many new types of medium sized hetero-cyclic compounds were synthesized by [2,3] sigmatropic rearrangement of alpha-aryl cyclic ammonium methylides or sulfonium methylides which were generated by fluoride ion-induced desilylation of alpha-aryl-[(trimethylsilyl)methyl]-cyclic ammonium or sulfonium salts in DMF or DMSO at room temperature.
The results have been published in J.Org.Chem. (2 articles) and J.Chem.Soc., Perkin Trans 1.(4 articles).
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