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A Study on the adsorption of organic compounds to fibers and design of materials with good adsorption property by use of waste fibers

Research Project

Project/Area Number 08680002
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 家政学
Research InstitutionFUKUSHIMA UNIVERSITY

Principal Investigator

KANAZAWA Hitoshi  Faculty of Education, FUKUSHIMA UNIVERSITY, Professor, 教育学部, 教授 (50143128)

Project Period (FY) 1996 – 1998
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 1998: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1997: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1996: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywordsadsorption / silk fibroin / silk sericin / wool keratin / synthetic polypeptides / amino acids / dye / volatile organic compounds / アルコール / 絹 / 羊毛 / フィブロイン / セリシン / ケラチン / 酸性染料
Research Abstract

Adsorption of low-molecular-weight organic compounds to silk fibroin, silk sericin and wool keratin was investigated ; the adsorption of dyes in water (1), vapor of organic compounds in air (2), amino acids in water (3) and organic compounds in water (4) were examined. Following results were obtained.
l) "Adsorption of dyes in water" Five kinds of acid dyes to keratin or fibroin fiber and their powder was observed. The dyes adsorbed more at higher temperature to wool fiber. On the other hand, no temperature effect was observed in the adsorption to silk fibroin. When regenerated powder keratin was used, the adsorption of dyes did not depend on temperature. Thus, the roll of cuticle in wool fiber was important.
2) "Adsorption of vapor of organic compounds in air "Each protein showed similar adsorption property to each other but the amount of adsorbed compounds was different. Specific adsorption property was seen for each of synthetic polypeptides.
3) "Adsorption of amino acids in water "Fibroin fiber and powder adsorbed lysine predominantly from the mixture of amino acids. On the other hand, poly (glycine), poly (L-alanine) and poly (L-valine) etc. gave the adsorption of acid amino acids such as glutamic acid and aspartic acid.
4) "Adsorption of organic compounds in water " It was seen that contamination of organic compounds such as chloroform in water could be removed by the adsorption with fibroin fiber.

Report

(4 results)
  • 2000 Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • 1996 Annual Research Report
  • Research Products

    (28 results)

All Other

All Publications (28 results)

  • [Publications] H.KANAZAWA: "Amino Acid N-Carboxy Anhydrides with High Polymerizability in the Solid State."Molecular Crystals and Liquid Crystals. 313. 205-210 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA, M-Akuma tsu, T.ONAMI: "Adsorption of Amino Acids on Proteins and Synthetic Polypeptides"Science Report, Fukushima Univ.. 63. 20-25 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA: "Polymerization of DL-Leucine NCA in the Solid State"Science Report, Fukushima Univ.. 63. 25-30 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA: "Structure of N-carboxy-L-phenylalanine anhydride"Acta Crystallographica. 56. 469-470 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA, M.Aka MATSU.T.ONAMI: "Adsorption of Volatile Organic Compounds on Proteins and Protein Modelsl"Science Report, Fukushima Univ.. 63. 21-26 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA, T.HA YAKAWA: "Kinetics of N-carboxy Anhydride of DL-Leucine in the Solid State"Science Report, Fukushima Univ.. 63. 27-31 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA: "Amino Acid N-Carboxy Anhydrides with High Polymerizability in the Solid State."Molecular Crystals and Liquid Crystals. Vol.313. 205-210 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA, M.AKAMATSU and T.Onami: "Adsorption of Amino Acids on Proteins and Synthetic Polypeptides"Science Report, Fukushima Univ.. No.63. 20-25 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA: "Polymerization of DL-Leucine NCA in the Solid"State, Science Report, Fukushima Univ.. No.63. 25-30 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA: "Adsorption of Volatile Organic Compounds on Proteins and Protein Models l."Science Report, Fukushima Univ.. 63. 21-26 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA and T.HAYAKAWA: "Kinetics of N-carboxy Anhydride of DL-Leucine in the Solid State."Science Report, Fukushima Univ.. 63. 27-31 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.KANAZAWA: "Structure of N-carboxy-L-phenylalanine anhydride"Acta Crystallographica. 56. 469-470 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kanazawa: "Amino Acid N-Carboxy Anhydrides with High Polymerizability in the Solid State." Molecular Crystals and Liquid Crystals. 313. 205-210 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kanazawa, T.Onami: "Reaction of Aromatic Azo Compounds with t-Butyl Hypochlorite." Science Report,Fukushima Univ.61. 27-32 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kanazawa: "Convenient Method for the Estimation of Vapor Pressure of Some Organic Compounds." Science Report,Fukushima Univ.60. 25-31 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kanazawa, H.Uekusa, Y.Ohashi: "Structure of DL-Phenylalanine NCA,C10H9NO3." Acta Crystallographica. C53. 1154-1156 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kanazawa, Y.Ohashi: "Polymerization of N-Carboxy Anhydrides of L- and DL-Valine,and L-and DL-Phenylalanine in the Solid State." Molecular Crystals and Liquid Crystals. 277. 45-54 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Onami, H.Kanazawa: "A Simple Method for Isolation of Caffein from Black Tea Leaves." J.Chemical Education. 73. 556-557 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] 金澤 等: "実験で学ぶ化学の世界 3.有機・高分子の化学,「繊維の種類を色で見分ける」" 日本化学会編 丸善, 6 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kanazawa: "Convenient Method for the Estimation of Vapor Pressure of Some Organic Compounds" Science Report,Fukushima Univ.No.60. 25-31 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kanazawa, H.Uekusa and Y.Ohashi: "Structure of DL-Phenyl alanine NCA,C10H9NO3" Acta Crytallographica. C53. 1154-1156 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kanazawa and T.Onami: "Reaction of Aromatic Azo Compounds with t-Butyl Hypochlorite." Science Report,Fukushima Univ.No.61. 27-32 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kanazawa, K.Takahashi and T.Onami: "Characterization of Water-Insoluble Products in the Degradation of Orange G by Sodium Hypochlorite" Science Report,Fukushima Univ.No.61. 33-39 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kanazawa,Y.Ohashi: "Polymerization of N-Carboxy Anhydrides of L-and DL-Valine,and L-and DL-Phenylalanine in the Soild State." Molecular Crystals and Liquid Crystals. 277. 45-54 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] T.Onami,H.Kanazawa: "A Simple Method for Isolation of Caffein from Black Tea Leaves." Journal of Chemical Education. 73. 56-57 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kanazawa,Y.Matsushima: "Adsorption of Dye onto Silk and Wool Proteins." Science Report of Fukushima University. 59. 7-11 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kanazawa and Y.Sato: "Kinetics of the Polymerization of N-Carboxy Anhydride of beta-Benzyl-L-aspartate in the Solid State." Science Report of Fukushima University. 59. 11-15 (1996)

    • Related Report
      1996 Annual Research Report
  • [Publications] H.Kanazawa,H.Uekusa,Y.Ohashi: "Structure of N-Carboxy-dl-Phenylalanine Anhydride." Acta Crystallographica. C52. (1997)

    • Related Report
      1996 Annual Research Report

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Published: 1996-04-01   Modified: 2016-04-21  

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