| Project/Area Number |
08CE2005
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| Research Category |
Grant-in-Aid for COE Research
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| Allocation Type | Single-year Grants |
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| Research Institution | Kyushu-University |
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Principal Investigator |
SHINKAI Seiji (1998-2002) Graduate School of Engineering, Professor, 大学院・工学研究院, 教授 (20038045)
岩村 秀 (1996-1997) 九州大学, 有機化学基礎研究センター, 教授 (10011496)
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| Co-Investigator(Kenkyū-buntansha) |
TSUTSUI Tetsuo Interdisciplinary Graduate School of Engineering Science, Professor, 大学院・総合理工学研究院, 教授 (40037982)
KAJIYAMA Tisato 九州大学, 総長 (60037976)
NARUTA Yoshinori Institute for Fundamental Research of Organic Chemistry, Inst. for Fund. Res. Org. Chem, Professor, 有機化学基礎研究センター, 教授 (00108979)
KOGA Noboru Graduate School of Pharmaceutical Sciences, Professor, 大学院・薬学研究院, 教授 (60161890)
OKAWA Hisashi Graduate School of Science, Professor, 大学院・理学研究院, 教授 (00037219)
稲津 孝彦 九州大学, 大学院・理学研究院, 教授 (60037207)
青山 安宏 九州大学, 有機化学基礎研究センター, 教授 (00038093)
岩村 秀 放送大学, 教授 (10011496)
君塚 信夫 九州大学, 大学院・工学研究院, 教授 (90186304)
國武 豊喜 九州大学, 大学院・工学研究科, 教授 (40037734)
新海 征治 九州大学, 大学院・工学研究科, 教授 (20038045)
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| Project Period (FY) |
1996 – 2002
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥1,603,545,000 (Direct Cost: ¥1,549,650,000、Indirect Cost: ¥53,895,000)
Fiscal Year 2002: ¥233,545,000 (Direct Cost: ¥179,650,000、Indirect Cost: ¥53,895,000)
Fiscal Year 2001: ¥130,000,000 (Direct Cost: ¥130,000,000)
Fiscal Year 2000: ¥190,000,000 (Direct Cost: ¥190,000,000)
Fiscal Year 1999: ¥240,000,000 (Direct Cost: ¥240,000,000)
Fiscal Year 1998: ¥420,000,000 (Direct Cost: ¥420,000,000)
Fiscal Year 1997: ¥390,000,000 (Direct Cost: ¥390,000,000)
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| Keywords | high spin molecule / molecular magnetic complex / organic zeolite / nitrogen-containing cage molecule / molecular orientation / synthetic bilayer unit / molecular recogition unit / multi-nuclear metal complex |
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| Research Abstract |
In this project, we first established strategies for assembling and organizing molecules on the basis of two guiding principles that, when properly designed, molecules can attract or repel each other selectively, and that dimensionality of the structures is most instrumental in controlling the properties and functions of molecular assemblies. We then designed molecules that have the functional groups for exhibiting weak intermolecular interactions such as coordination bonds, hydrogen bonds, hydrophobic interactions, dispersion force, exchange interaction, etc. The varieties, numbers, locations and vectors of such groups will tailor the size and shape of the resulting molecular assemblies. After the synthesis of the designed component molecules, the assemblage and organization of them have been performed by : 1. Self-assembly, 2. crystallographic technology, 3. monolayer/bilayer methods, 4. molecular manipulation by scanning probe microscopy. These methods will be applied not only for s
… More
ingle components but also for two or more components.
Since mechanical, optical, electronic, magnetic and chemical interactions are expected to be directional and anisotropic in these organized molecular assemblies of mesoscopic scale, the following molecular functions and functional molecular materials which have never been attained by assemblies of naive molecules will be produced. One-dimensional materials : Double-helix information storage mimicking DNA, molecular sensing, highly ordered metal-ion array catalysts, Two-dimensional materials : Creation of morphologies found in living organism, interfaces enabling chiral recognition, two-dimensional metal complexes Three-dimensional materials : Two-dimensional reaction environments by multiplication of artificial molecular bilayers, organic zeolites, molecular optomagnetic recording devices, transparent magnets.
We believe that research achievements obtained through this Project will become a milestone linking the 20th century to the 21st century and open a door toward the new era of science. Less
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