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Development of a Passive Sampling/Monitoring Device Suitable for Acid Gas in Atmospheric Environment in China and Its Field Evaluation

Research Project

Project/Area Number 09041126
Research Category

Grant-in-Aid for Scientific Research (A).

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionUniversity of Tokushima

Principal Investigator

KORENAGA Takashi  University of Tokushima, Graduate School of Engineering and Faculty of Integrated Arts & Sciences, Professor, 総合科学部, 教授 (30124788)

Co-Investigator(Kenkyū-buntansha) MURATA Katsuo  Naruto University of Teacher Education, Professor, 学校教育学部, 教授 (60028206)
MURATA Akihiro  University of Tokushima, Faculty of Integrated Arts & Sciences, Associate Professor, 総合科学部, 助教授 (20143373)
MIZUNO Tateki  National Institute for Resources and Environment, AIST, MITI, Dupty Director, 資源環境技術総合研究所, 次長(研究職)
YAMADA Etsu  Kyoto Institute of Technology, Associate Professor, 工芸学部, 助教授 (30159214)
揚 屹  中国北京化工大学, 応用化学系, 副教授
張 新祥  中国北京大学, 化学学院, 副教授
池田 早苗  徳島大学, 工学部, 教授 (20035801)
胡 敏  北京大学, 環境科学中心, 副教授
楊 屹  北京化工大学, 応用化学系, 副教授
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥14,600,000 (Direct Cost: ¥14,600,000)
Fiscal Year 1999: ¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 1998: ¥5,100,000 (Direct Cost: ¥5,100,000)
Fiscal Year 1997: ¥5,100,000 (Direct Cost: ¥5,100,000)
Keywordspassive sampler / nitrogen dioxide / sulfur dioxide / atmosphere / air pollution / environment / monitoring / China / 微量物質 / 有害物質 / 酸性大気汚染物質 / 中国 / 簡易測定 / 大気汚染 / 硫黄酸化物 / 窒素酸化物 / イオウ酸化物 / チッ素酸化物
Research Abstract

A new type of passive sampler, which can easily determine sulfur dioxide (SOィイD22ィエD2) and nitrogen dioxide (NOィイD22ィエD2) simultaneously air, has developed. The passive sampling method for analysis of SOィイD22ィエD2 has more difficult than NOィイD22ィエD2 chiefly because of following two problems. The first one is that SOィイD22ィエD2 has high absorptivity. Therefore, it is much absorbed in the materials used as the absorption and diffusion filter in sampler, and the second one is that the sulfate ion, to which absorbed SOィイD22ィエD2 is oxidized, is usually contained in filter used as sampler parts. Thus, blank concentration of sulfur ion is sampler is higher. As a result of exposure experiments using a wind tunnel to evaluate the materials used as absorption and diffusion filter, the passive sampler which polyethelene membrane is used as an absorption layer, and polyethylene and polypropylene as the first and second diffusion layer was found to have the most suitable sampler for analyzing SOィイD22ィエD2 and NOィイD22ィエD2. The precision and detection limit of this method was found to be satisfactory. The method established in this study has been applied to the evaluation of air quality at the five major cities in China since September 1997.
The passive samplers are easily influence by wind. However, the newly developed samplers are found to have minimum influence by sampling conditions such as wind, humidity and temperature. So this method is applied to investigate the air in six cities, Beijing, Lonzhou, Wuhan, Dalian, Shenyang which are high in China. The concentrations of SOィイD22ィエD2 and NOィイD22ィエD2 are two days averages. These obtained data has good agreement with the annual average concentration. The weekly change of SOィイD22ィエD2 and NOィイD22ィエD2 concentration (7 days average) in Beijing. Since temperature dropped, SOィイD22ィエD2 and NOィイD22ィエD2 concentrations tend to increase. One of the causes of it is the increase of using coal for heating.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (59 results)

All Other

All Publications (59 results)

  • [Publications] Y.Yang,X.Zhang,T.Korenaga,and K.Higuchi: "Determination of Passive-Sampled Sulphur Dioxide in Ambient Air as sulphate Ion by Flow Injection Analysis with an ln-Line Reaction Coluimn"Talanta. 45(2). 445-450 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Yang,X.Zhang,T.Korenaga: "Determination of Sulfur Dioxide in Southeast Asia by Flow Injection Analysis with on-line Reaction Column"Analytical Sciences. 13(S). 475-478 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] X.Zhang,Y.Yang,and T.Korenaga: "Determination of Polynuclear Aromatic Hydrocarbons(PAHs)in Environmental Samples by Capillary Electrophoresis"Analytical Sciences. 13(S). 235-238 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Yang,Q.Ln,J.Cao,G.Wang,R.Men,and T.Korenaga: "Determination of Iron( III ) with Methylene Blue by Stopped-Flow Photochemical Analysis"Analytical Sciences. 13(S). 63-66 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Huang,R.Cai,T.Korenaga,X.Zhang,Y.Yang,Y.Du,and Y. Zeng: "Micelle Enhanced Spectrofltuorimetric Determination of L-Ascorbic Acid Based on Laccase-linked Couplillg Reaction Using Flow-Injection Stopped-Flow Technique"Analytical Sciences. 13(S). 67-70 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Korenaga,T.: "simultaneous SO_2 NO_2 Monitoning With Passive Sampliug and Advanced Micro-Sensig Devices in China"Proc.International Forum on the Measurement and Environment. 2. 1-10 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Korenaga,T.,Shintani,Y.: "Passive Sampler Technology For Simultaneous SO_2,NO_2 Monitoring"Proc.Atmospheric Sciences and Applications to Air Quality 6th lnternational Conference. 2. 33-34 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Yang,Y.,Zhang,Xinxiang.,Korenaga,T.,Shintaani,Y.: "Monitorind of SO_2 and NC_x by Passive Samplers in China Cities"Proc.Atmospheric Sciences and Applications to Air Quality 6th lnternational Conference. 2. 36 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Korenaga,T.: "Passive Sampler as a Simple Indoor/Outdoor/Personal Air Pollution Monitoring Device"Proc.4th Asian Symposium on Academic Activities for Waste Management. Aug.19〜21. 27-31 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Korenaga.T.,Yamauchi,T.,Hara,C.: "Development of a Passive Sampling/Atmospheric Analysis Device Using Droplet Method and Its Microfabrication"Proc.4th Asian Symposium on Academic Activities for Waste Management. 4. 63-64 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "室内外環境汚染とモニタリング"日本学術会議第14回環境工学連合講演会講演論文集. 14. 25-32 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 柳沢幸雄,伊永隆史,他12名: "パッシブサンプラー方式有害大気物資簡易測定器"環境研究. 115. 8-11 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "室内外環境汚染とモニタリング"日本学術会議50周年記念環境工学連合講演論文集. 14. 25-32 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Korenaga: "Simple Determination of NO_2 and SO_2 Using Passive Samplers in Air Pollution Monitoring"Waste Management. 3. 94-103 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Korenaga,Y.Shintani,Y.Yang,X.Zhang: "Development or Passive Technology for Simultaneous Sulfur Dioxide and Nitrogen Dioxide Monitoring"Air Quality and Atmospheric Science. 6. 40-46 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "マイクロチップテクノロジーによるパッシブサンプラーのデバイス化"室内環境学会セミナー公園要旨集. 11・3. 1-25 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "ぶんせき"日本分析化学会. 162 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "環境分析とISO14000"大学教育出版. 18 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 檜山為次郎、澤田嗣郎、伊永隆史: "日本化学会季刊化学総説No39,透明ポリマーの屈折率制御"学会出版センター. 232 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 檜山為次郎、澤田嗣郎、伊永隆史: "日本化学会季刊化学総説No36,光化学の基礎と先端研究"学会出版センター. 275 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "中国の酸性大気汚染物資モニタリングに適する簡易測定器の開発と評価"文部省科学研究費補助金国際学術研究(学術調査). 207 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 池田早苗、伊永隆史: "SOx,NOx簡易測定による東南アジア地域酸性雨の特性評価"文部省科学研究費補助金国際学術研究(学術調査). 167 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 檜山為次郎、伊永隆史外: "高次機能触媒の設計-環境調和型触媒の開発を目指した新展開"日本化学会(季刊化学総説). 228 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yang, X. Zhang, T. Korenaga, and K. Higuchi: "Determination of Passive-Sampled Sulphur Dioxide in Ambient Air as Sulphate Ion by Flow Injection Analysis with an In-Line Reation Column"Talanta. 45(2). 445-450 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yang, X. Zhang, T. Korenaga: "Determination of Sulfur Dioxide in Southeast Asia by Flow Injection Analysis with on-line Reaction Column"Analytical Sciences. 13(S). 475-478 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yang, X. Zhang, T. Korenaga: "Determination of Polynuclear Aromatic Hydrocarbons (PAHs) in Environmenta Samples by Capillary Electrophoresis"Analytical Sciences. 13(S). 235-238 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yang, Q. Lu, J. Cao, G. Wang, R. Men, and T. Korenaga: "Determination of Iron (III) with Methylene Blue by Stopped-Flow Photochemical Analysis"Analytical Sciences. 13(S). 63-66 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Huang, R. Cai, T. Korenaga, X. Zhang, Y. Yang, Y. Du, and Y. Zeng: "Micelle Enhanced Spectrofluorimetric Determination of L-Ascorbic Acid Based on Laccase-linked Coupling Reaction Using Flow-Injection Stopped-Flow Technique"Analytical Sciences. 13(S). 67-70 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Korenaga: "Simultaneous SOィイD22ィエD2, NOィイD22ィエD2 Monitoring With Passive Sampling and Advanced Micro-Sensing Devices in China"Proc. International Forum on the Measurement and Environment. 2. 1-10 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Korenaga, Y. Shintani: "Passive Sampler Technology For Simultaneous SOィイD22ィエD2, NOィイD22ィエD2 Monitoring"Proc. Atmospheric Sciences and Applications to Air Quality 6th International Conference. 2. 33-34 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yang, X. Zhang, T. Korenaga, Y. Shintani: "Monitoring of SOィイD22ィエD2 and NOィイD2XィエD2 by Passive Samplers in China Cities"Proc. Atmospheric Sciences and Applications to Air Quality 6th International Conference. 2. 36 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Korenaga: "Passive Sampler as a Simple Indoor/Outdoor/Personal Air Pollution Monitoring Device"Proc. 4th Asian Symposium on Academic Activities for Waste Management. Aug. 19〜21. 27-31 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Korenaga, T. Yamauchi, C. Hara: "Development of a Passive Sampling Atmospheric Analysis Device Using Droplet Method and Its Microfabrication"Proc. 4th Asian Symposium on Academic Activities for Waste Management. 4. 63-64 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Korenaga: "Simple Determination of NOィイD22ィエD2 and SOィイD22ィエD2 Using Passive Samplers in Air Pollution Monitoring"Waste Management. 3. 94-103 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Korenaga, Y. Shintani, Y. Yang, X. Zhang: "Development of Passive Technology for Simutaneous Sulfur Dioxide and Nitrogen Dioxide Monitoring"Air Quality and Atmospheric Science. 6. 40-46 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊永隆史: "マイクロチップテクノロジーによるパッシブサンプラーのデバイス化"室内環境学会セミナー講演要旨集. 11・3. 1-25 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Korenaga,Y.Shintani,Y.Yang,X Zhang: "Development of Passive Technology for Simultaneous Sulfur Dioxide and Nitrogen Dioxide Monitoring"Air Quality and Atmospheric Science. 6. 40-46 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Korenaga: "Simple Determination of NQ and SQ Using Passive Samplers in Air Pollution Monitoring"Waste Management. 3. 94-103 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊永隆史: "室内外環境汚染とモニタリング"日本学術会議50周年記念環境工学連合講演論文集. 14. 25-32 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 柳沢幸雄,伊永隆史,他12名: "パッシブサンプラー方式有害大気物質簡易測定器"環境研究. 115. 8-11 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊永隆史: "中国の酸性大気汚染物質モニタリングに適する簡易測定器の開発と評価"文部省科学研究費補助金国際学術研究(学術調査). 207 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 池田早苗,伊永隆史: "SOx,NOx簡易測定による東南アジア地域酸性雨の特性評価"文部省科学研究費補助金国際学術研究(学術調査). 167 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 檜山爲次郎,伊永隆史外: "高次機能触媒の設計-環境調和型触媒の開発を目指した新展開"日本化学会(季刊化学総説). 228 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊永隆史: "室内外環境汚染とモニタリング" 日本学術会議第14回環境工学連合講演会講演論文集. 14. 25-32 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Korenaga,T.: "Passive Sampler as a Simple Indoor/Outdoor/Personal Air Pollution Monitoring Device" Proc.4th Asian Symposium on Academic Activities for Waste Management. Aug.19〜21. 27-31 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Korenaga,T.,Yamauchi,T.,Hara,C.: "Development of a Passive Sampling/Atmospheric Analysis Device Using Droplet Method and Its Microfabrication" Proc.4th Asian Symposium on Academic Activities for Waste Management. 4. 63 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Korenaga,T.,Shintani,Y.: "Passive Sampler Technology For Simultaneous SO_2,NO_2 Monitoring" Proc.Atmospheric Sciences and Applications to Air Quality 6th International Conference. 2. 33-34 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Yang,Yi.,Zhang,Xinxiang.,Korenaga,T.,Shintani,Y.: "Monitoring of SO_2 and NO_x by Passive Samplers in China Cities" Proc.Atmospheric Sciences and Applications to Air Quality 6th International Conference. 2. 36 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Korenaga,T.: "Simultaneous SO_2,NO_2 Monitoring With Passive Sampling and Advanced Micor-Sensing Devices in China" Proc.International Forum on the Measurement and Environment. 2. 1-10 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 檜山為次郎、澤田嗣郎、伊永隆史: "日本化学会季刊化学総説No36,光化学の基礎と先端研究" 学会出版センター, 275 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 檜山為次郎、澤田嗣郎、伊永隆史: "日本化学会季刊化学総説No39,透明ポリマーの屈折率制御" 学会出版センター, 232 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Yang, Y., Zhang, X., T., Higuchi, K.Korenaga,: "Determination of passive-sampled sulphur dioxide in ambient air as sulphuate ion by flow injection analysis with an in-line reaction column" Talanta. 45・2. 445-450 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yang, Y., Zhang, X., Korenaga, T.: "Determination of Sulfur Dioxide in Southeast Asia by Flow Injection Analysis with on-lone Reaction Column" Analytcal Sciences. 13・13. 475-478 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Zhang, X., Yang, Y., Korenaga, T.: "Determination of Polynuclear Aromatic Hvdrocarbons (PAHs)in Environmental Samples by Capillary Electrophoresis" Analytical Sciences. 13・13. 235-238 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yang, Y., Lu, Q., Cao, J., Wang, G., Men, R., Korenaga: "Determination of Iron(III)with Methylene Blue by Stopped-flow Photocheminal Analysis" Analytical Sciences. 13・13. 63-66 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Huang, H., Cai, R., Korenaga, T.Zhang, X., Yang, Y., Du, Y., Zeng, Y: "Mlcelle Enhanced Spectrofluorlmetrlc Determlnatton of L-ascorblc Acld Based on Laccase-linked Coupling Reaction Using Flow-injection Stopped-flow Technique" Analytical Sciences. 13・13. 67-70 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Levy, J., Lee.K., Spengler.D, J.Korenaga, T., et al.: "Impact of Residential Nitrogen Dioxide Exposure on Personal Exposure ; An Intemational Study." Journal of Air and Waste Management. 48(印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 伊永 隆史: "ぶんせき、" 日本分析化学会, 162 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 伊永 隆史: "環境分析とISO14000" 大学教育出版, 18 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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