• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Design of Reaction Metal Sites toward Unique Activation of Small Molecules

Research Project

Project/Area Number 09102004
Research Category

Grant-in-Aid for Specially Promoted Research

Allocation TypeSingle-year Grants
Review Section Chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

HIDAI Masanobu  U of Tokyo.Dept.of Chem.& Biotech., Professor, 大学院・工学系研究科, 教授 (60011011)

Co-Investigator(Kenkyū-buntansha) NISHIBAYASHI Yoshiaki  U of Tokyo, Dept.of Chem.& Biotech., Research Assistant, 大学院・工学系研究科, 助手 (40282579)
ISHII Youichi  U of Tokyo, Dept.of Chem.& Biotech., Assoc.Professor, 大学院・工学系研究科, 助教授 (40193263)
MIZOBE Yasushi  U of Tokyo, Institute of Industrial Sci., Assoc.Professor, 生産技術研究所, 助教授 (40175609)
SEINO Hidetake  U of Tokyo, Institute of Industrial Sci., Research Assistant, 生産技術研究所, 助手 (50292751)
KUWATA Shigeki  U of Tokyo, Dept.of Chem.& Biotech., Research Assistant, 大学院・工学系研究科, 助手 (10292781)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥201,000,000 (Direct Cost: ¥201,000,000)
Fiscal Year 1999: ¥33,000,000 (Direct Cost: ¥33,000,000)
Fiscal Year 1998: ¥33,000,000 (Direct Cost: ¥33,000,000)
Fiscal Year 1997: ¥135,000,000 (Direct Cost: ¥135,000,000)
Keywordsdinitrogen complex / ammonia / molybdenum / tungsten / sulfur / polynuclear complex / chalcogenide cluster / catalytic reaction / ピロール
Research Abstract

The present study revealed that the cationic ruthenitum dihydrogen complexes trans-[RuCl (H_2)(diphosphine)_2]^+ derived from the coordinatively unsaturated ruthenium complexes and dihydrogen react with the tungsten dinitrogen complex cis-[W (N_2)_2 (PMe_2Ph)_4] to afford ammonia under mild conditions. This is the first esample of the transformation of coordinated dinitrogen into ammonia by using dihydrogen gas. Activation of dihydrogen gas on the sulfurbridged dimolybdenum complexes [(CpMo)_2S(SR)(S_2CH_2)]^+ and subsequent reactions with the tungsten dinitrogen complex also led to the formation of ammonia.
In connection with the structure of the active site of nitrogenase, general synthetic methods for homo-and heterometallic sulfur clusters ranging from trinuclear to pentanuclear clusters was established. A variety of homo-, heterobi-, and heterotrimetallic sulfido clusters containing group 4 -11 metals were systematically synthesized by these rational approaches. Furthermore, these polynuclear complexes were demonstrated to provide multimetallic centers effective for novel activation and transformation of reactivities of small molecules such as alkynes.alkenes. and isocyanides.

Report

(4 results)
  • 2000 Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (179 results)

All Other

All Publications (179 results)

  • [Publications] H.Seino: "Synthesis and Structure Determination of Complexes Containing a Five-Membered Lactam Structures Based on Organohydradizo (2-) Ligands"Inorg.Chem.. 36. 162-171 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Z.Tang: "The hydrosulfido-Bridged Diiridium and Dirhodium Complexes [CP^*MCl(μ_2-SH)_2MC_p^*Cl] (M=Ir Rh ; Cp^*=η_5-C_5Me_5) as Versatile Precursors for Tri-and Tetranuclear Sulfido Clusters"Organometallics. 16. 151-154 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Synthesis, Structures, and Reactivites of Rhodium and Ruthenium Complexes with a Novel Chiral Cyclopentadienyl-Ferrocenyldiphenylphosphine Bidentate Ligand"Organometallics. 16. 3091-3093 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Takagi: "Synthesis and Reactivities of Cationic Diruthenium Complexes with Terminal Vinylidene Ligands. Hydration and Novel Cyclization of Acetylenes on the Diruthenium Center"Organometallics. 16. 4445-4452 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata: "Structural Diversity of Tetranuclear Tungsten Sulfide Clusters : Syntheses and Crystal Structures of Cluster Containing Raft-Type W_4(μ_3-S)_2(μ-S)_4 and Tetrahedral W_4(μ-S)_6 Cores"J.Chem.Soc., Dalton Trans.. 1753-1758 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium Complexes"Chem.Commun.. 859-860 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Ishii: "Selective Hydroforylation of Internal Acetylenes by PdCl_2(PCy_3)_2 : Remarkable Synergistic Effect Cobalt"J.Am.Chem.Soc.. 119. 6448-6449 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Nishio: "Preparation of a series of Dinuclear Ir (III) and Ir (II) Complexes Containing Bridging Thiolate Ligands"Inorg.Chim.Acta. 263. 119-123 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Nishio: "Synthesis of Diiridium Complexes Containing Bridging Thiolate and Thioether Ligands [(η_5-C_5Me_5) Ir (-SR)(-MeSR) Ir (η_5-C_5Me_5)][OSO_2CF_3 and Their Reactivities Toward CO and H_2"Inorg.Chim.Acta. 265. 59-63 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Rhodium (I)-, Iridium (I)-, and Ruthenium (II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides as CHiral Ligands"J.Organomet.Chem.. 531. 13-18 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and Oxazolinylferrocenylphosphines, and their Rhodium (I)-complexes"J.Organomet.Chem.. 545-546. 381-398 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 桑田繁樹: "開かれる金属一硫黄クラスターの化学"現代化学. 32-37 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Bimetallic System for Nitrogen Fixation : Ruthenium-Assisted Protonation of Coordinated N_2 on Tungsten with H_2"Science. 279. 540-542 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Z.Tang: "Syntheses, Structures and Properties of Hydrosulfido-Bridged Diiridium and Dirhodium Complexes [Cp^*MCl(μ_2-SH)_2MCp^*Cl] and [Cp^*MCl(μ_2-SH)_3MCp^*Cl]_+(M=Ir, Rh ; Cp^*=η_5-C_5Me_5)"Inorg.Chim.Acta. 267. 73-79 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada: "Reactivities or Molybdenum and Tungsten Diazoalkane-Isocyanide Complexes Derived from Dinitrogen Compleses"Bull.Chem.Soc.Jpn.. 71. 183-190 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino: "Reactivities of the Coordinated Organonitriles in Molybdenum and Tungsten Phosphine Complexes : Protonation of the Nitrile Carbon and Cleavage of the CN Triple Bond"Inorg.Chim.Acta. 280. 163-171 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Nakamura: "Unprecedented Conversion of Benzylideneanilines into Arylisocyanides Promoted by a Low-Valent Molybdenum Complexes. X-ray Structure of [Mo (CNPh)(N_2)(Ph_2PCH_2CH_2PPh_2)_2]"Organometallics. 17. 1010-1012 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Mizobe: "Syntheses of Ruthenium Hydridotris (1-pyrazoryl) borato Complexes Having Sulfur-Donor Coligands"Inorg.Chim.Acta. 273. 238-243 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ishino: "Synthesis of Boryldiazenido Complexes from Tungsten Dinitrogen Complexes"Chem.Left.. 677-678 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Ruthenium-Catalyzed Asymmetric Hydrosilylation of Ketones and Imine"Organometallics. 17. 3420-3422 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata: "Structures and Reactivities of Diruthenium Dithiolene Complexes and Triruthenium Sulfido Clusters Derived from a Hydrosulfido-Bridged Diruthenium Complex"Organometallics. 17. 3429-3436 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Masui: "Regioselective Addition of Alcohols to Internal 1-Aryl-1-alkynes Catalyzed by a Triangular Heterobimetallic Ir_2 Pd Sulfido Cluster"Chem.Lett.. 717-718 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata: "Hydrosulfido-Bridged Titanium-Ruthenium Heterobimetallic Complex : Stepwise-Construction of Ti_2Ru_2S_4 Cubane-Type Sulfido Cluster"Chem.Lett.. 885-886 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Ikada: "Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Trimetallic M_2M'S_4(M = Mo, W ; M' = Pd, Pt) and Tetrametallic Cubane-Type Mo_2Pd_2S_4 Cores"Inorg.Chem.. 37. 5793-5797 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Takagahara: "Synthesis and Molecular Structure of Tetranuclear Tungusten-Gallium Complexes with Bridging Dinitrogen Ligands"Chem.Lett.. 897-898 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Z.Tang: "Metal-Metal Bonding in Pentanuclear Bow-Tie Metal Sulfide Clusters. Synthetic and Structural Studies on the Cationic Pentanuclear Clusters [(Cp^*Ir)_2 (μ_3-S)_2 M(μ_3-S)_2 (IrCp^*)_2]"^+ (M = Fe, Co, Ni ; n = 1, 2)"Inorg.Chem.. 37. 4909-4920 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.-P.Qu: "Head-to-head Z Dimerization of Terminal Alkynes Catalyzed by Thiolato-Bridged Diruthenium Complexes"Chem.Lett.. 1003-1004 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "A Model for Protonation of Dinitrogen by Nitrogenase : Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Diruthenium Complexes"J.Am.Chem.Soc.. 120. 10559-10560 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Sato: "Synthesis and Reactivities of the Indenyl-Ruthenium Cluster [(η^5-C_9H_7) Ru (μ-SEt)]_3 ; Indenyl Effect in the Trinuclear Ruthenium Cluster"J.Organomet.Chem.. 569. 99-108 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada: "Syntheses of Tungsten Diazoalkane Complexes from a Dinitrogen Complex and Diketones.Conversion of Molecular Nitrogen into Pyrazoles via the Diazoalkane Complexes as Intermediates"Bull.Chem.Soc.Jpn.. 71. 2701-2708 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Retbφll: "Dinuclear Pyridine- 1 -Imine-Bridged Rhodium (III) Complexes. Intramolecular Carbon-Hydrogen Bond Activation"Chem.Lett.. 1217-1218 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Matsukawa: "Reactions of Iridium and Ruthenium Arenethiolato Complexes with Propylene Sulfide. X-ray. Structures of 1 -Arylthio-2-Propanethiolato-S,S' Iridium and Ruthenium Complexes"Inorg.Chem.Commun.. 1. 368-371 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takemoto: "Synthesis of Heterobimetallic Fe-M (M = Ni, Pd, Pt) Complexes Containing the 1,1'- Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes"Inorg.Chem.. 37. 6428-6434 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Ikada: "Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Incomplete Cubane-Type M_2M'S_4 and Cubane-Type M_2 M'_2 S_4 Cores (M = Mo, W ; M' = Rh, Ir)"Inorg.Chem.. 38. 64-69 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Retbφll: "Synthesis and Reductive N-N Bond Cleavage of Neutral and Cationic Titanium (1-Pyridinio) imido Complexes"Organometallics. 18. 150-155 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Hidai: "Chemical Nitrogen Fixation by Molybdenum and Tungsten Complexes"Coord.Chem.Rev.. 185.186. 99-108 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Arita: "Formation of Novel Tetradentate Phosphine Ligand o-C_6H_4 (PPhCH_2CH_2PPh_2)_2 by Coupling of Two Diphosphine Ligands Bound to Low-Valent Mo or W Center"Chem.Lett.. 611-612 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Kochi: "Synthesis and Reactivities of Ir_2Ru Heterobimetallic Sulfido Clusters Derived from a Hydrogensulfio-bridged Diiridium Complex"J.Chem.Soc., Dalton Trans.. 2575-2582 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Kochi: "Rh_4S_7 and Ir_3CuS_6 Clusters with Di- and Trisulfido Ligands Derived from Dinuclear Hydrogensulfido Complexes"Chem.Lett.. 1279-1280 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino: "Conversion of Benzaldehyde Imines into Isocyanides at a Low-Valent Molybdenum Center. Preparation and Reactivities of Isocyanide-Dinitrogen Complexes"Organometallics. 18. 4165-4173 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex"Angew.Chem.Int.Ed.Engl.. 38. 3047-3050 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Taniguchi: "Hydrosulfurization of Benzothiophene over Zeolite-Supported Catalysts Prepared from Mo and Mo-Ni Sulfide Clusters"J.Catal.. 187. 139-150 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Arikawa: "Ruthenium (II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxazolinylferrocenylphosphines and One of Their Ru (II) Complex"J.Organomet.Chem.. 572. 163-168 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ishino: "Synthesis and Structures of Tungsten (1-Pyridinio) imido Complexes and Their Facile N-N Bond Cleavage"Inorg.Chem.. 38. 2489-2496 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada: "Condensation of Triketones with Tungsten Hydrazido (2-) Complexes Derived from a Dinitrogen Complex : Formation of Mononuclear or Dinuclear Diazoalkane Complexes"J.Organomet.Chem.. 574. 24-31 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada: "Syntheses and Structures of Tungsten Ferrocenyldiazoalkane Complexes Derived from a Dinitrogen Complex"Inorg.Chim.Acta. 285. 336-340 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Sasagawa: "Selective N-N and W-N Bond Cleavage of Tungsten Pyrrolylimido Complexes Derived from Tungsten Dinitrogen Complex"Bull.Chem.Soc.Jpn.. 72. 425-432 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Amemiya: "Syntheses of Mixed-metal M_2Ti_2S_4 Cubane-type Sulfido Clusters (M = Ru, Rh, Ir, Cu) from a Dinuclear Organometallic Thiotitanate Anion"Chem.Commun.. 711-712 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kabashima: "Electron-Deficient Early-Late Heterobimetallic Sulfido Clusters. Unusual Reactivities of Ti_2Ru_2S_4 Cubane-type Clusters with Four Cyclopentadienyl Colignds"J.Am.Chem.Soc.. 121. 7837-7845 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.Takei: "Iridium-Catalyzed Asymmetric Hydrosilylation of Imines Using Chiral Oxazolinyl-Phosphine Ligands"Organometallics. 18. 2271-2274 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi: "Extremely High Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl_2(PPh_3)(oxazolinylferrocenylphosphine)"Organometallics. 18. 2291-2293 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Iwasa: "Preparation of Cationic Dinuclear Hydrido Complexes of Ruthenium, Rhodium, and Iridium with Bridging Thiolato Ligands and Their Reactions with Nitrosobenzene"Inorg.Chem.. 38. 2851-2859 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino: "Preparation of Sulfide-Bridged Di- or Trinuclear Pyrrolylimido and Diazoalkane Complexes Derived from a Tungsten Dinitrogen Complex"Bull.Chem.Soc.pn. 73. 631-639 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Masui: "Synthesis and Characterization of Mixed-Metal Sulfido Clusters with the Cubane-Type PtMo3S4 Core"Bull.Chem.Soc.Jpn. 73. 931-938 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kabashima: "Crossed Condensation of Two Different Hydrosulfido-Bridged Dinuclear Complexes : Structures and Reactivities of TiRu_3S_4 Cubane-Type Sulfido Clusters"Angew.Chem.Int.Ed.Engl.. 39. 1128-1131 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Ishii: "Reactions of Cationic Dirhodium and Diiridium Complexes [Cp^* M(μ-Cl)(μ-SPr)_2 MCp^*][OTf](M = Rh, Ir) with Terminal Alkynes"J.Oragnomet.Chem.. 599. 221-231 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Matsukawa: "Syntheses, Structures,and Reactivities of Mono- and Dinuclear Iridium Thiolato Complexes Containing Nitrosyl Ligands"Inorg.Chem.. 39. 791-798 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Hidai: "Synthesis and Reactivities of Cubane-Type Sulfido Clusters Containing Noble Metals "Acc.Chem.Res.. 33. 46-52 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Tanabe: "Reaction Mechanism of the C≡N Triple Bond Cleavage of β-Ketonitrile on a Molybdenum (O) Center"J.Am.Chem.Soc.. 122. 1690-1699 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino, Y.Ishii, and M.Hidai: "Synthesis and Structure Determinations of Complexes Containing a Five-Membered Lactam Structure Based on Organohydrazido (2-) Ligands"Inorg.Chem.. 36. 161-171 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Z.Tang, Y.Nomura, Y.Ishii, Y.Mizobe, and M.Hidai: "The Hydrosulfido-Bridged Diiridium and Dirhodium Complexes [Cp^*MCl (μ_2-SH)_2MCp^*Cl](M=Ir, Rh ; Cp^*=η^5-C_5Me^5) as Versatile Precursors for Tri-and Tetranuclear Sulfido Clusters"Organometallics. 16. 151-154 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, I.Takei, and M.Hidai: "Synthesis, Structures, and Reactivities of Rhodium and Ruthenium Complexes with a Novel Chiral Cyclopentadienyl-Ferrocenyldiphenylphosphine Bidentate Ligand"Organometallics. 16. 3091-3093 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Takagi, H.Matsuzaka, Y.Ishii, and M.Hidai: "Synthsis and Reactivities of Cationic Diruthenium Complexes with Terminal Vinylidene Ligands. Hydration and Novel Cyclization of Acetylenes on the Diruthenium Center"Organometallics. 16. 4445-4452 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata, Y.Mizobe, and M.Hidai: "Structural Diversity of Tetranuclear Tungsten Sulfide Clusters : Syntheses and Crystal Structures of Clusters Containing Raft-Type W_4 (μ_3-S)_2(μ-S)_4 and Tetrahedral W_4(μ-S)_6 Cores"J.Chem.Soc.Dalton Trans.. 1753-1758 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, M.Yamanashi, Y.Takagi, and M.Hidai: "Allylation of Arenes Catalyzed by Thiolate-Bradged Diruthenium Complexes"Chem.Commun.. 859-860 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Ishii, K.Miyashita, K.Kamita, and M.Hidai: "Selective Hydroformylation of Internal Acetylenes by PdCl_2(PCy_3)_2 : Remarkable Synergistic Effect of Cobalt"J.Am.Chem.Soc.. 119. 6448-6449 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Nishio, H.Matsuzaka, Y.Mizobe, and M.Hidai: "Preparation of a Serices of Dinuclear Ir (III) and Ir(II) Complexes Containing Bridging Thiolate Ligands"Inorg.Chem.Acta. 263. 119-123 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Nishio, Y.Mizobe. H.Matsuzaka. and M.Hidai: "Synthesis of Diiridium Complexes Containing Bridging Thiolate and Thioether Ligands [(η^5-C_5Me_5) Ir (μ-SR)(μ-MeSR) Ir (η^5-C_5Me_5)][OSO_2CF_3] (R=Pri.cyclohexyl) and Their Reactivities toward CO and H_2"Inorg.Chim.Acta. 265. 59-63 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, J.D.Singh, Y.Arikawa, S.Uemura, and M.Hidai: "Rhodium (I)-, Iridium (I)-, and Ruthenium (II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Diferrocenyl Dichalcogenides as Chiral Ligands"J.Organomet.Chem.. 531. 13-18 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, K.Segawa, Y.Arikawa, K.Ohe, M.Hidai, and S.Ueyama: "Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and Oxazolinylferrocenylphosphines, and Their Rhodium (I)-Complexes"J.Organomet.Chem.. 545-546. 381-398 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata and M.Hidai: "Chemistry of Metal Sulfur Clusters"Gendai Kagaku. 314. 32-37 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, S.Iwai, and M.Hidai: "Bimetallic System for Nitrogen Fixation : Ruthenium-assisted Protonation of Coordinated N_2 on Tungsten with H_2"Science. 279. 540-542 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Z.Tang, Y.Nomura, Y.Ishii, Y.Mizobe, and M.Hidai, Syntheses: "Structures and Properties of Hydrosulfido-Bridged Diiridium and Dirhodium Complexes, [Cp*MCl(μ_2-SH)_2MCp*Cl] and [Cp*M(μ_2-SH)_3MCp*] + (M=Ir.Rh ; Cp*=η^5-C_5Me_5)"Inorg.Chim.Acta.. 267. 73-79 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada, Y.Mizobe, T.Aoshima, H.Oshita, and M.Hidai: "Reactivities of Molybdenum and Tungsten Diazoalkane-Isocyanide Complexes Derived from Dinitrogen Complexes"Bull.Chem.Soc.Jpn.. 71. 183-190 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino, Y.Tanabe, Y.Ishii, and M.Hidai: "Reactivities of the Coordinated Organonitriles in Molybdenum (0) and Tungsten (0) Phosphine Complexes : Protonation of the Nitrile Carbon and Cleavage of the C≡N Triple Bond"Inorg.Chim.Acta.. 280. 163-171 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Nakamura, Y.Harada, C.Arita, H.Seino, Y.Mizobe, and M.Hidai: "Unpreccdented Conversion of Benzylidencs into Aryl Isocyanides Promoted by a Low-Valent Molybdenum Complex. X-ray Structure of trans-|Mo(CNPh)(N_2)(Ph_2PCH_2CH_2PPh_2)_2|"Organometallics. 17. 1010-1012 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Mizobe, M.Hosomizu, and M.Hidai: "Syntheses of Ruthenium Hydridotris (1-pyrazoryl) borale Complexes Having Sulfur-donor Coligands"Inorg.Chim.Acta. 273. 238-243 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ishino, Y.Ishii, and M.Hidai: "Synthesis of Boryldiazenido Complexes from Tungsten Dinitrogen Complexes"Chem.Lett. 677-678 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, I.Takei, S.Uemura, and M.Hidai: "Ruthenium-Catalyzed Asymmetric Hydrosilylation of Ketones and Imine"Organometallics. 17. 3420-3422 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata, M.Andou, K.Hashizume, Y.Mizobe, and M.Hidai: "Structures and Reactivities of Diruthenium Dithiolene Complexes and Triruthenium Sulfido Clusters Derived from a Hydrosulfido-Bridged Diruthenium Complex"Organometallics. 17. 3429-3436 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Masui, Y.Ishii, and M.Hidai: "Regioselective Addition of Alcohols to Internal 1-Aryl-alkenes Catalyzed by a Triangular Heterobimetallic Ir_2Pd Sulfido Cluster"Chem.Lett.. 717-718 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kuwata and M.Hidai: "Hydrosulfido-Bridged Titanium-Ruthenium Heterobimetallic Complex : Stepwise Construction of Ti_2Ru_2S_4 Cubane-Type Sulfido Cluster"Chem.Lett.. 885-886 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Ikada, S.Kuwata, Y.Mizobe, and M.Hidai: "Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Trimetallic M_2M'S_4 (M=Mo, W ; M'=Pd, Pt) and Tetrametallic Cubane-Type Mo_2Pd_2S_4 Cores"Inorg.Chem.. 37. 5793-5797 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Takagahara, H.Ishino, Y.Ishii, and M.Hidai: "Synthesis and Molecular Structure of Tetranuclear Tungsten-Gallium Complexes with Bridging Dinitrogen Ligands"Chem.Lett.. 897-898 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Z.Tang, Y.Nomura, S.Kuwata, Y.Ishii, Y.Mizobe, and M.Hidai: "Metal-Metal Bonding in Pentanuclear Bow-Tie Metal Sulfido Clusters. Synthetic and Structural Studies on the Cationic Pentanuclear Clusters [(Cp_*Ir)_2(μ_3-S)_2M (μ_3-S)_2)-(IrCp_*)_2]^<n+> (M=Fe, Co, Ni : n=1,2)"Inorg.Chem.. 37. 4909-4920 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.-P, Qu, D.Masui, Y.Ishii, and M.Hidai: "Head-to-head Z Dimerization of Terminal Alkynes Catalyzed by Thiolate-Bridged Diruthenium Complexes"Chem.Lett.. 1003-1004 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, S.Iwai, and M.Hidai: "A Model for Protonation of Dinitrogen by Nitrogenase : Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Dinuclear Complexes"J.Am.Chem.Soc.. 120. 10559-10560 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T Sato, M.Nishio, Y.Ishii, H.Yamazaki, and M.Hidai: "Synthesis and Reactivities of the Indenyl-Ruthenium Cluster [(η^5-C_9H_7)Ru(μ-SEt)]_3 : Indenyl Effect in the Trinuclear Ruthenium Cluster]"J.Organomer.Chem.. 569. 99-108 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada, Y.Mizobe, Y.Ishii, and M.Hidai: "Syntheses of Tungsten Diazoalkane Complexes from a Dinitrogen Complex and Diketones.Conversion of Molecular Nitrogen into Pyrazoles via the Diazoalkane Complexes as Intermediates"Bull.Chem.Soc.Jpn.. 71. 2701-2708 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Retboll, Y.Ishii, and M.Hidai: "Dinuclear Pyridine-1-Imine-Bridged Rhodium (III) Complexes. Intramolecular Carbon-Hydrogen Bond Activation"Chem.Lett.. 1217-1218 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Matsukawa, S.Kuwata, and M.Hidai: "Reactions of Iridium and Ruthenium Arenethiolato Complexes with Propylene Sulfide. S-ray Structures of 1-Arylthio-2-propanethiolato-S,S' iridium and Ruthenium Complexes"Inorg.Chem.Commun.. 1. 368-371 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takemoto, S.Kuwata, Y.Nishibayashi, and M.Hidai: "Synthesis of Heterobimetallic Fe-M (M=Ni, Pd, Pt) Complexes Containing the 1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes"Inorg.Chem.. 37. 6428-6434 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Ikada, S.Kuwata, Y.Mizobe, and M.Hidai: "Syntheses and Stuctures of Mixed-Metal Sulfido Clusters Containing Incomplete Cubane-Type M_2M'S_4 and Cubane-Type M_2M'_2S_4 Cores (M=Mo, W ; M'=Rh, Ir)"Inorg.Chem.. 38. 64-69 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Retboll, Y.Ishii, and M.Hidai: "Synthesis and Reductive N-N Bond Cleavage of Neutral and Cationic Titanium (1-Pyridinio)-imido Complexes"Organometallics. 18. 150-155 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Hidai: "Chemical Nitrogen Fixation by Molybdenum and Tungsten Complexes"Coord.Chem.Rev.. 185-186. 99-108 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Arita, H.Seino, Y.Mizobe, and M.Hidai: "Formation of Novel Tetradentate Phosphine Ligand o-C_6H_4 (PPhCH_2CH_2PPh_2)_2 by Coupling of Two Diphosphine Lignds Bound to Low-Valent Mo or W Center. Synthesis and Structure of [M{o-C_6H_4 (PPhCH_2PPh_2)_2}(Ph_2PCH_2CH_2PPh_2)] (M=Mo, W)"Chem.Lett.. 611-612 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Kochi, Y.Nomura, Z.Tang, Y.Ishii, Y.Mizobe, and M.Hidai: "Synthesis and Reactivities of Ir_2Ru Heterobimetallic Sulfido Clusters Derived from a Hydrogensulfido-bridges Diiridium Complex"J.Chem.Soc., Dalton Trans.. 2575-2582 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Kochi, Y.Tanabe, Z.Tang, Y.Ishii, and M.Hidai: "Rh_4S_7 and Ir_3CuS_6 Clusters with Di-and Trisulfido Ligands Derived from Dinuclear Hydrogensulfido Complexes"Chem.Lett.. 1279-1280 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino, C.Arita, D.Nonokawa, G.Nakamura, Y.Harada, Y.Mizobe, and M.Hidai: "Conversion of Benzaldehyde Imines into Isocyanides at a Low-Valent Molybdenum Center Preparation and Reactivities of Isocyanide-Dinitrogen Complexes trans-[Mo(RNC)(N_2)-(Ph_2PCH_2CH_2PPh_2)_2] (R=Aryl, Alkyl)"Organometallics. 18. 4165-4173 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, I.Takei, and M.Hidai: "Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex"Angew.Chem., Int.Ed.. 38. 3047-3050 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Taniguchi, D.Imamura, H.Ishige, Y.Ishii, T.Murata, M.Hidai, and T.Tatsumi: "Hydrodesulfurization of Benzothiophene over zeolite-Supported Catalysts Prepared from Mo and Mo-Ni Sulfide Clusters"J.Catal.. 187. 139-150 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Arikawa, M.Ueoka, K.Matoba, Y.Nishibayashi, M.Hidai, and S.Uemura: "Ruthenium (II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxazolinylferrocenylphosphines and One of Their Ru (II) Complexes"J.Organoment.Chem. 572. 163-168 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Isino, S.Tokunaga, H.Seino, Y.Ishii, and M.Hidai: "Synthesis and Structures of Tungsten (1-Pyridinio) imido Complexes and Their Facile N-N Bond Cleavage"Inorg.Chem.. 38. 2489-2496 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada, Y.Mizobe, and M.Hidai: "Condensation of Triketones with Tungsten Hydrazido (2-) Complexes Derived from a Dinitrogen Complex : Formation of Mononuclear or Dinuclear Diazoalkane Complexes"J.Organoment.Chem.. 574. 24-31 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Harada, Y.Mizobe, and M.Hidai: "Synthesis and Structures of Tungsten Ferrocenyldiazoalkane Complexes Derived from a Dinitrogen Complex"Inorg.Chim.Acta.. 285. 336-340 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Sasagawa, H.Seino, Y.Ishii, M.Mizobe, and M.Hidai: "Selective N-N and W-N Bond Cleavage of Tungsten Pyrrolylimido Complexes Derived from Tungsten Dinitrogen Complex"Bull.Chem.Soc.Jpn.. 72. 425-432 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Amemiya, S.Kuwata, and M.Hidai: "Syntheses of Mixed-metal M_2Ti_2S_4 Cubane-type Sulfido Clusters (M=Ru, Rh, Ir, Cu) from a Dinuclear Organometallic Thiotitanate Anion"Chem.Commun.. 711-712 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kabashima, S.Kuwata, and M.Hidai: "Electron-Deficient Early-Late Heterobimetallic Sulfido Clusters, Unusual Reactivities of Ti_2Ru_2S_4 Cubane-type Clusters with Four Cyclopentadienyl Coligands"J.Am.Chem.Soc.. 121. 7837-7845 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.Takei, Y.Nishibayashi, Y.Arakawa, S.Uemura, and M.Hidai: "Iridium-Catalyzed Asymmetric Hydrosilylation of Imines Using Chiral Oxazolinyl-Phosphine Ligands"Organometallics. 18. 2271-2274 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishibayashi, I.Takei, S.Uemura, and M.Hidai: "Extremely High Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl_2(PPh_3)(oxazolinylferrocenylphosphine)"Organometallics. 18. 2291-2293 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Iwasa, H.Shimada, A.Takami, H.Matsuzaka, Y.Ishii, and M.Hidai.: "Preparation of Cationic Dinuclear Hydrido Complexes of Ruthenium. Rhodium. and Iridium with Bridging Thiolato Ligands and Their Reactions with Nitrosobenzene"Inog.Chem.. 38. 2851-2859 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Seino, Y.Mizobe, and M.Hidai: "Preparation of Sulfide-Bridged Dior Trinuclear Pyrrolylimido and Diazoalkane Complexes Derived from a Tungsten Dinitrogen Complex"Bull.Chem.Soc.Jpn.. 73. 631-639 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Masui, Y.Ishii, and M.Hidai: "Synthesis and Characterization of Mixed-Metal Sulfido Clusters with the Cubane-Type PtMo_3S_4Core"Bull.Chem.Soc.Jpn.. 73. 931-938 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kabashima, S.Kuwata, K.Ueno, M.Shiro, and M.Hidai: "Crossed Condensation of Two Different Hydrosulfido-Bridged Dinuclear Complexes : Structures and Reactivities of TiRu_3S_4Cubane-Type Sulfido Cluters"Angew.Chem.Int.Ed.. 39. 1128-1131 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Ishii, K.Ogio, M.Nishio, M.Retboll, S.Kuwata, H.Matsuzaka, and M.Hidai: "Reactions of Cationic Dirhodium and Diiridium Complexes [Cp^*M(μ-Cl)(μ-SPr)_2MCp^*][OTf](M=Ph, Ir) with Terminal Alkynes. Comparison with the Diruthenium System"J.Organomet.Chem.. 599. 221-231 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Matsukawa, S.Kuwata, and M.Hidai: "Syntheses, Structures, and Reactivities of Mono-and Dinuclear Iridium Thiolato Complexes Containing Nitrosyl Ligands"Inorg.Chem.. 39. 791-798 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Hidai, S.Kuwata, and Y.Mizobe: "Synthesis and Reactivities of Cubane-Type Sulfido Clusters Containing Noble Metals"Acc.Chem.Res.. 33. 46-52 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Tanabe, H.Seino, Y.Ishii, and M.Hidai: "Reaction Mechanism of the C≡N Triple Bond Cleavag of β-Ketonitrile on a Molybdenum (0) Center"J.Am.Chem.Soc.. 122. 1690-1699 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T. Amemiya: "Syntheses of Mixed-metal M_2Ti_2S_4 Cubane-type Sulfido Clusters (M=Ru, Rh, Ir, Cu) from a Dinuclear Organometallic Thiotitanate Anion"Chem. Commun.. 711-712 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Ishino: "Synthesis and Structures of Tungsten (1-Pyridinio)imido Complexes and Their Facile N-N Bond Cleavage"Inorg. Chem.. 38. 2489-2496 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I. Takei: "Iridium-Catalyzed Asymmetric Hydrosilylation of Imines Using Chiral Oxazolinyl-Phosphine Ligands"Organometallics. 18. 2271-2274 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Nishibayashi: "Extremely High Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl_2(PPh_3)(oxazolinylferrocenylphosphine)"Organometallics. 18. 2291-2293 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Iwasa: "Preparation of Cationic Dinuclear Hydrido Complexes of Ruthenium, Rhodium, and Iridium with Bridging Thiolato Ligands and Their Reactions with Nitrosobenzene"Inorg. Chem.. 38. 2851-2859 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S. Kabashima: "Electron-Deficient Early-Late Heterobimetallic Sulfido Clusters. Unusual Reactivities of Ti_2Ru_2S_4 Cubane-type Clusters with Four Cyclopentadienyl Colignds"J. Am. Chem. Soc.. 121. 7837-7845 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] C. Arita: "Formation of Novel Tetradentate Phosphine Ligand o-C_6H_4(PPhCH_2CH_2PPh_2)_2 by Coupling of Two Diphosphine Ligands Bound to Low-Valent Mo or W Center"Chem. Lett.. 611-612 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Kochi: "Synthesis and Reactivities of Ir_2Ru Heterobimetallic Sulfido Clusters Derived from a Hydrogensulfio-bridged Diiridium Complex"J. Chem. Soc., Dalton Trans.. 2575-2582 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Kochi: "Rh_4S_7 and Ir_3CuS_6 Clusters with Di- and Trisulfido Ligands Derived from Dinuclear Hydrogensulfido Complexes"Chem. Lett.. 1279-1280 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Seino: "Conversion of Benzaldehyde Imines into Isocyanides at a Low-Valent Molybdenum Center Preparation and Reactivities of Isocyanide-Dinitrogen Complexes"Organometallics. 18. 4165-4173 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Nishibayashi: "Novel Catalytic Hydrogenolysis of Trimethylsilyl Enol Ethers by the Use of an Acidic Ruthenium Dihydrogen Complex"Angew. Chem. Int. Ed. Engl.. 3047-3050 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Taniguchi: "Hydrosulfurization of Benzothiophene over Zeolite-Supported Catalysts Prepared from Mo and Mo-Ni Sulfide Clusters"J. Catal.. 187. 139-150 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S. Kabashima: "Crossed Condensation of Two Different Hydrosulfido-Bridged Dinuclear Complexes : Structures and Reactivities of TiRu_3S_4 Cubane-Type Sulfido Clusters"Angew. Chem. Int. Ed. Engl.. (印刷中).

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Ishii: "Reactions of Cationic Dirhodium and Diiridium Complexes [Cp*M(μ-Cl)(μ-SPr)_2MCp*][Otf](M=Rh, Ir) with Terminal Alkynes"J. Oragnomet. Chem.. (印刷中).

    • Related Report
      1999 Annual Research Report
  • [Publications] S. Matsukawa: "Syntheses, Structures, and Reactivities of Mono- and Dinuclear Iridium Thiolato Complexes Containing Nitrosyl Ligands"Inorg. Chem.. 39. 791-798 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Hidai: "Synthesis and Reactivities of Cubane-Type Sulfido Clusters Containing Noble Metals"Acc. Chem. Res.. 33. 46-52 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Tanabe: "Reaction Mechanism of the C≡N Triple Bond Cleavage of β-Ketonitrile on a Molybdenum(0) Center"J. Am. Chem. Soc.. (印刷中).

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Seino: "Preparation of Sulfide-Bridged Di- or Trinuclear Pyrrolylimido and Diazoalkane Complexes Derived from a Tungsten Dinitrogen Complex"Bull. Chem. Soc. Jpn. (印刷中).

    • Related Report
      1999 Annual Research Report
  • [Publications] S. Nagano: "Syntheses of Dinuclear Ir Complex Containing Bridging Tetraselenide Ligands [(C_5Me_5)Ir(μ-Se_4)_2Ir(C_5Me_5)]and its Conversion into Ir_2Pd_2Se_3 and Ir_2Pd_3Se_5"Chem. Commun. (印刷中).

    • Related Report
      1999 Annual Research Report
  • [Publications] D. Masui: "Synthesis and Characterization of Mixed-Metal Sulfido Clusters with the Cubane-Type PtMo3S4 Core"Bull. Chem. Soc. Jpn. (印刷中).

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Mizobe: "Syntheses of Ruthenium Hydridotris(1-pyrazoryl)borato Complexes Having Sulfur-Donor Coligands" Inorg.Chim.Acta. 273. 238-243 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Ishino: "Synthesis of Boryldiazenido Complexes from Tungsten Dinitrogen Complexes" Chem.Lett.677-678 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Nishibayashi: "Ruthenium-Catalyzed Asymmetric Hydrosilylation of Ketones and Imine" Organometallics. 17. 3420-3422 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kuwata: "Structures and Reactivities of Diruthenium Dithiolene Complexes and Triruthenium Sulfido Clusters Derived from a Hydrosulfido-Bridged Diruthenium Complex" Organometallics. 17. 3429-3436 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] D.Masui: "Regioselective Addition of Alcohols to Internal 1-Aryl-1-alkynes Catalyzed by a Triangular Heterobimetallic Ir_2Pd Sulfido Cluster" Chem.Lett.717-718 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kuwata: "Hydrosulfido-Bridged Titanium-Ruthenium Heterobimetallic Complex : Stepwise Construction of Ti_2Ru_2S_4 Cubane-Type Sulfido Cluster" Chem.Lett.885-886 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Takagahara: "Synthesis and Molecular Structure of Tetranuclear Tungusten-Gallium Complexes with Bridging Dinitrogen Ligands" Chem.Lett.897-898 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Z.Tang: "Metal-Metal Bonding in Pentanuclear Bow-Tie Metal Sulfido Clusters. Synthetic and Structural Studies on the Cationic Pentanuclear Clusters[(Cp^*Ir)_2(μ_3-S)_2M(μ_3-S)_2(IrCp^*)_2]^<n+>(M=Fe,Co,Ni;n=1,2)" Inorg.Chem.37. 4909-4920 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.-P.Qu: "Head-to-head Z Dimerization of Terminal Alkynes Catalyzed by Thiolato-Bridged Diruthenium Complexes" Chem.Lett.1003-1004 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Nishibayashi: "A Model for Protonation of Dinitrogen by Nitrogenase : Protonation of Coordinated Dinitrogen on Tungsten with Hydrosulfido-Bridged Diruthenium Complexes" J.Am.Chem.Soc.120. 10559-10560 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Sato: "Synthesis and Reactivities of the Indenyl-Ruthenium Cluster [(η^5-C_9H_7)Ru(μ-SEt)]_3 : Indenyl Effect in the Trinuclear Ruthenium Cluster" J.Organomet.Chem.569. 99-108 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Harada: "Syntheses of Tungsten Diazoalkane Complexes from a Dinitrogen Complex and Diketones. Conversion of Molecular Nitrogen into Pyrazoles via the Diazoalkane Complexes as Intermediates" Bull.Chem.Soc.Jpn.71. 2701-2708 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ikada: "Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Trimetallic M_2M′S_4(M=Mo,W;M′=Pd,Pt) and Tetrametallic Cubane-Type Mo_2Pd_2S_4 Cores" Inorg.Chem.37. 5793-5797 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Retbφll: "Dinuclear Pyridine-1-Imine-Bridged Rhodium(III) Complexes. Intramolecular Carbon-Hydrogen Bond Activation" Chem.Lett.1217-1218 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Matsukawa: "Reactions of Iridium and Ruthenium Arenethiolato Complexes with Propylene Sulfide. X-ray Structures of 1-Arylthio-2-Propanethiolato-S,S′ Iridium and Ruthenium Complexes" Inorg.Chem.Commun.1. 368-371 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Takemoto: "Synthesis of Heterobimetallic Fe-M(M=Ni,Pd,Pt) Complexes Containing the 1,1′-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes" Inorg.Chem.37. 6428-6434 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ikada: "Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Incomplete Cubane-Type M_2M′S_4 and Cubane-Type M_2M′_2S_4 Cores(M=Mo,W;M′=Rh,Ir)" Inorg.Chem.38. 64-69 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Retbφll: "Synthesis and Reductive N-N Bond Cleavage of Neutral and Cationic Titanium(1-Pyridinio)imido Complexes" Organometallics. 18. 150-155 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Arikawa: "Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxazolinylferrocenylphosphines and One of Their Ru(II) Complex" J.Organomet.Chem.572. 163-168 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Hidai: "Chemical Nitrogen Fixation by Molybdenum and Tungsten Complexes" Coord.Chem.Rev.(in press). (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Ishino: "Synthesis and Structures of Tungsten(1-Pyridinio)imido Complexes and Their Facile N-N Bond Cleavage" Inorg.Chem.38(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Harada: "Condensation of Triketones with Tungsten Hydrazido(2-) Complexes Derived from a Dinitrogen Complex : Formation of Mononuclear or Dinuclear Diazoalkane Complexes" J.Organomet.Chem.(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Harada: "Syntheses and Structures of Tungsten Ferrocenyldiazoalkane Complexes Derived from a Dinitrogen Complex" Inorg.Chim.Acta. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Sasagawa: "Selective N-N and W-N Bond Cleavage of Tungsten Pyrrolylimido Complexes Derived from Tungsten Dinitrogen Complex" Bull.Chem.Soc.Jpn.72(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Seino: "Synthesis and Structure Determination of Complexes Containing a Five-Membered Lactam Structures Based on Organohydradizo(2-)Ligands" Inorg.Chem.36. 162-171 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Z.Tang: "The hydrosulfido-Bridges Diiridium and Dirhodium Complexes [Cp^*MCl(μ_2-SH)_2MCp^*Cl](M=Ir,Rh; Cp^*=η_5-C_5Me_5)as Versatile Precursors for Tri- and Tetranuclear Sulfido Clusters" Organometallics. 16. 151-154 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nishibayashi: "Synthesis,Structures,and Reactivities of Rhodium and Ruthenium Complexes with a Novel Chiral Cyclopentadienyl-Ferrocenyldiphenylphosphine Bidentate Ligand" Organometallics. 16. 3091-3093 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Takagi: "Synthesis and Reactivities of cationic Diruthenium Complexes with Terminal Vinylidene Ligands. Hydration and Novel Cyclization of Acetylenes on the Diruthenium Center" Organometallics. 16. 4445-4452 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Kuwata: "Structural Diversity of Tetranuclear Tungsten Sulfide Clusters : Syntheses and Crystal Structures of Cluster Containing Raft-Type W_4(μ_3-S)_2(μ-S)_4 and Tetrahedral W_4(μ-S)_6 Cores" J.Chem.Soc.,Dalton Trans.1753-1758 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nishibayashi: "Allylation of Arenes Catalysed by Thiolate-Bridged Diruthenium Complexes" Chem.Commun.859-860 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Ishii: "Selective Hydroforylation of Internal Acetylenes by PdCl_2(PCy_3)_2 : Remarkable Synergistic Effect Cobalt" J.Am.Chem.Soc.119. 6448-6449 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Nishio: "Preparation of a series of Dinuclear Ir(III)and Ir(II)Complexes Containing Bridging Thiolate Ligands" Inorg.Chim.Acta. 263. 119-123 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Nishio: "Synthesis of Diiridium Complexes Containing Bridging Thiolate and Thioether Ligands[(η_5-C_5Me_5)Ir(-SR)(-MeSR)Ir(η_5-C_5Me_5)][OSO_2CF_3 and Their Reactivities Toward CO and H_2" Inorg.Chim.Acta. 265. 59-63 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nishibayashi: "Rhodium(I)0,Iridium(I)-,and Ruthenium(II)-catalyzed Asymmetric Transfer Hydrogenation of Ketones using Diferrocenyl Dichalcogenides as CHiral Ligands" J.Organomet.Chem.531. 13-18 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nishibayashi: "Synthesis and Structure of Novel Chiral Oxazolinylferrocenes and Oxazolinylferrocenylphosphines,and their Rhodium(I)-complexes" J.Organomet.Chem.545-546. 381-398 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 桑田繁樹: "開かれる金属-硫黄クラスターの化学" 現代化学. 5. 32-37 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nishibayashi: "Bimetallic System for Nitrogen Fixation : Ruthenium-Assisted Protonation of Coordinated N_2 on Tungsten with H_2" Science. 279. 540-542 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Z.Tang: "Syntheses,Structures and Properties of Hydrosulfido-Bridged Diiridium and Dirhodium Complexes [Cp^*MCl(μ_2-SH)_2MCp^*Cl]and[Cp^*MCl(μ_2-SH)_3MCp^*Cl]^+(M=Ir,Rh;Cp^*=η_5-C_5Me_5)" Inorg.Chim.Acta. 267. 73-79 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Harada: "Reactivities of Molybdenum and Tungsten Diazoalkane-Isocyanide Complexes Derived from Dinitrogen Compleses" Bull.Chem.Soc.Jpn.71. 183-190 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Seino: "Reactivities of the Coordinated Organonitriles in Molybdenum and Tungsten Phosphine Complexes : Protonation of the Nitrile Carbon and Cleavage of the CN Triple Bond" Inorg.Chim.Acta. (in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] G.Nakamura: "Unprecedented Conversion of Benzylideneanilines into Arylisocyanides Promoted by a Low-Valent Molybdenum Complexes. X-ray Structure of[Mo(CNPh)(N_2)(Ph_2PCH_2CH_2PPh_2)_2]" Organometallics. (in press). (1998)

    • Related Report
      1997 Annual Research Report

URL: 

Published: 1997-04-01   Modified: 2018-03-28  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi