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Electrochemistry of Ordered Interfaces

Research Project

Project/Area Number 09237102
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

UOSAKI Kohei  Hokkaido Univ., Grad. School of Sci., Prof., 大学院・理学研究科, 教授 (20133697)

Co-Investigator(Kenkyū-buntansha) YONEYAMA Hiroshi  Anan Coolege of Technoloyg, Principal, 校長 (80029082)
AIZAWA Masuo  Tokyo Institute of Tech., Grad. School of Bioscience and Biotechnology, Prof., 生命理工学部, 教授 (00016742)
FUJISHIMA Akira  Tokyo Univ., Grad School of Eng., Prof., 大学院・工学系研究科, 教授 (30078307)
NAKATO Yoshihiro  OSAKA Univ., Grad.School of Eng. Sci., Prof., 大学院・基礎工学研究科, 教授 (70029502)
TANIGUCHI Isao  Kumamoto Univ., Faculty of Eng., Prof., 工学部, 教授 (90112391)
Project Period (FY) 1997 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥105,900,000 (Direct Cost: ¥105,900,000)
Fiscal Year 2000: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1999: ¥8,000,000 (Direct Cost: ¥8,000,000)
Fiscal Year 1998: ¥48,000,000 (Direct Cost: ¥48,000,000)
Fiscal Year 1997: ¥46,900,000 (Direct Cost: ¥46,900,000)
Keywordselectrochemistry / electron transfer dynamics / battery / molecular recognition / sensing / photoelectrochemistry / 光機能界面
Research Abstract

The ultimate goal of this project is to understand and control electrode reactions in atomic and molecular levels. To achieve this goal, 19 core members and 67 (1997 and 1998) or 73 (1999) other members, who were selected from many applicants, worked hard. Each member belonged to one of four research groups, i.e., Group A01 : "Interfacial Structures and Electron Transfer Dynamics", Group A02 : "Fabrication of Novel Interfaces by Using Electrochemical Techniques and Development of High Performance Batteries", Group A03 : "Ordered Functional Interfaces for Molecular Recognition and Sensing" and Group A04 : "Photoelectrode Reactions and Photofunctional Interfaces".
In addition to the two meetings attended by all members, meetings attended by only core members were held twice a year to exchange information more closely. Furthermore, several symposia were organized jointly with the Electrochemical Society of Japan (ECSJ) or the Chemical Society of Japan (CSJ) so that activity of this group would be widely known to scientific community. Furthermore, symposia on "Electrochemistry of Ordered Interfaces" were held three times (1998 : Sapporo, 1999 : Honolulu and 2000 : Sapporo) and two special issues on "Electrochemistry of Ordered Interfaces" were published in J.Electroanal. Chem. and Electrochemistry 1999.

Report

(5 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (43 results)

All Other

All Publications (43 results)

  • [Publications] R.Yamada: "Two-Dimensional Crystals of Alkanes Formed on Au(111) Surface in Neat Liquid-Structural Investigation by Scanning Tunneling Microscopy"J.Phys.Chem.B. 104・25. 6021-6027 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Takahasi: "Pseudomorphic growth of Pd monolayer on Au(111) electrode surface"Surf.Sci.. 461 1-3. 213-218 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tamura: "Structural Study of Electrochemically Deposited Copper on p-GaAs(001) by Atomic Force Microscopy and Surface X-ray Absorption Fine Structure Measurement"J.Phys.Chem.B. 104・38. 9017-9024 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Torimoto: "Preparation of Size-Quantized ZnS Thin Films Using Electrochemical Atimic Layer Epitaxy and Their Photoelectrochemical Properties"Langmuir. 16・13. 5820-5824 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Yoshimoto: "Direct Observation of Structural Change Induced by Redox Reaction of Bis (2-Anthraquinyl) Disulfide SAM on Au(100)-(1x1) by in situ High Resolution STM"Langmuir. 16・10. 4399-4404 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Tsujiko: "Selective Formation of Nano-Holes with the (100)-Face Walls by Photoetching of n-TiO2 (Rutile) Electrodes. Accompanied by Increases in Water-Oxidation Photocurrent"J.Phys.Chem.B. 104・20. 4873-4879 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] R.Yamada et al.: "Two-Dimensional Crystals of Alkanes Formed on Au (111) Surface in Neat Liquid-Structural Investigation by Scanning Tunneling Microscopy"J.Phys.Chem.B. 104 (25). 6021-6027 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Takahasi et al.: "Pseudomorphic growth of Pd monolayer on Au (111)electrode surface"Surf.Sci.. 461 (1-3). 213-218 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tamura et al.: "Structural Study of Electrochemically Deposited Copper on p-GaAs (001) by Atomic Force Microscopy and Surface X-ray Absorption Fine Structure Measurement"J.Phys.Chem.B. 104 (38). 9017-9024 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Torimoto et al.: "Preparation of Size-Quantized ZnS Thin Films Using Electrochemical Atomic Layer Epitaxy and Their Photoelectrochemical Properties"Langmuir. 16 (13). 5820-5824 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Yoshimoto et al.: "Direct Observation of Structural Change Induced by Redox Reaction of Bis (2-Anthraquinyl) Disulfide SAM on Au (100)-(1x1) by in situ High Resolution STM"Langmuir. 16 (10). 4399-4404 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Tsujiko et al.: "Selective Formation of Nano-Holes with the (100)-Face Walls by Photoetching of n-TiO2 (Rutile) Electrodes, Accompanied by Increases in Water-Oxidation Photocurrent"J.Phys.Chem.B. 104 (20). 4873-4879 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] R.Yamada: "Two-Dimensional Crystals of Alkanes Formed on Au (111) Surface in Neat Liquid-Structural Investigation by Scanning Tunneling Microscopy"J.Phy.Chem.B. 104・25. 6021-6027 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Takahasi: "Pseudomorphic growth of Pd monolayer on Au (111) electrode surface"Surf.Sci.. 461・1-3. 213-218 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Tamura: "Structural Study of Electrochemically Deposited Copper on p-GaAs (001) by Atomic Force Microscopy and Surface X- ray Absorption Fine Structure Measurement"J.Phy.Chem.B. 104・38. 9017-9024 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Torimoto: "Preparation of Size-Quantized ZnS Thin Films Using Electrochemical Atimic Layer Epitaxy and Their Photoelectrochemical Properties"Langmuir. 16・13. 5820-5824 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Yoshimoto: "Direct Observation of Structural Change Induced by Redox Reaction of Bis (2-Anthraquinyl) Disulfide SAM on Au (100)-(1x1) by in situ High Resolution STM"Langmuir. 16・10. 4399-4404 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] A.Tsujiko: "Selective Formation of Nano-Holes with the (100)-Face Walls by Photoetching of n-TiO2(Rutile)Electrodes, Accompanied by Increases in Water-Oxidation Photocurrent"J.Phys.Chem.B. 104・20. 4873-4879 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Uosaki: "Formation of Two-Dimensional Crystals of Alkanes on Au(111) Surface in Neat Liquid"J.Am.Chem.Soc.. 121・16. 4090-4091 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] R.Yamada: "Solvent Effect on the Structure of the Self-Assembled Monolayer of Alkanethiol"Chem.Lett.. 7. 667-668 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Ye: "Coverage Dependent Behavior of Redox Reaction Induced Structure Change and Mass Transport at an 11-ferrocenyl-1-undecanethiol Self-assembled Monolayer on a Gold electrode Studied by an in situ IRRAS/EQCM Combined System"PCCP. 1・15. 3653-3659 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Ye: "An Attenuated Total Reflection Fourier Transform Infrared Spectroscopy Study of the Adsorption of Organic Contaminants on a Hydrogen-terminated Si(111) Surface in Air"Appl.Phys.Lett.. 75・11. 1562-1564 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Naohara: "Electrochemical Epitaxial Growth of Palladium Layer on an Au(100) Electrode"J.Electroanal.Chem.. 473・1-2. 2-9 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Baum: "Formation of Self-Assembled Monolayers of Alkanethiols on GaAs Characterized By ATR-FTIR Spectroscopy"Langmuir. 15・25. 8577-8579 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Yoneyam: "Effects of Surface Charges and Surface States of Chemically Modified Cadmium Sulfide Nanoparticles Immobilized to Gold Electrode Substrates on Photoinduced Charge Transfers"Langmuir. 15・8. 2714-2718 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Yoneyama: "Fabrication of CdS Nanoparticle Chains along DNA Double Strands"J.Phys.Chem.B. 103・42. 8799-8803 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Taniguchi: "Structural differences in self-assembled monolayers of anthraquinone derivatives of silver and gold electrodes studied by cyclic voltammmetry and in situ SERS spectroscopy"J.Electroanal.Chem. 473. 83-91 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Taniguchi: "Eletrochemical Desorption of Binary Self-Assembled Monolayers of Butyl Hexadecayl Disulfide on Au(111) Electrodes"Electrochemistry. 67・12. 1227-1230 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Nakato: "Electrochemical Metal Deposition on Atomically Nearly-flat Silicon Surfaces Accompanied by Nano-hole Formation"Electrochim.Acta. 44. 3725-3729 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Nakato: "Mechanism and Simulation of Electrochemical Current Oscillantions Observed in the H_2O_2-Reduction Reaction on Platinum Electrodes in Acidic Solutions"Bull.Chem.Cos.Jpn.. 72・12. 1247 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] R.Yamada: "In situ STM Observation of the Self-Assembly Process of Alkanethiols on Au (111) in Solutio" Langmuir. 14/4. 855-861 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Ye: "An In Situ EQCM Study of the Anodic Dissolution Process of a Gold Electrode in Perchloric Acid Solution Containing Chloride Ion" J.Electrochem.Soc.145/5. 1614-1623 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] I.Yagi: "In Situ Optical Second Harmonic Rotational Anisotropy Measurements of an Au(111) Electrode during Electrochemical Deposition of Tellurium" J.Phys.Chem.B.102/15. 2677-2683 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Naohara: "Electrchemical Layer-by-Layer Growth of Palladium on an Au (111) Electrode Surface : Evidence for Important Role of Absorbed Pd Complex" J.Phys.Chem.B.102/22. 4366-4377 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Kondo: "Electrochemical Control of Second Harmonic Generation Property of Self-Assembled Monolayers Containg trans-Ferrocenyl-Nitrophenyl Ethylene Group on Gold"" J.Am.Chem.Soc.121/2. 391-398 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Ye: "Electrochemical Layer-by-Layer Growth of Palladium on an Au (111) Electrode Surface : Evidence Surface for Important Role of Adsorbed Pd Complex" J.Phys.Chem.B.102/22. 4366-4373 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Yoneyama: "Characteristic Feature of Size-Selective Photoetching of CdS Nanoparticles As a Means of Preparation of Monodisperse Particles" J.Electrochem.Soc.145/6. 1964-1968 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] I.Taniguchi: "Determination of Methylamphetamine in Urine by Differential Pulse Polarography" Anal Sci.14/4. 147-150 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Nakato: "High Photocurrent Quantum Yields in Short Wavelengths for Nanocrystalline Anatase-Type TiO_2 Film Electrodes Compared with Those for Rutile-Type" Bull.Chem.Soc.Jpn.71/9. 2119-2125 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiroshi Yoneyama: "Selective Desorption of 3-Mercaptopropionic Acid from a Mixed Monolayer with Hexadecanethiol Assembled on a Cold Electrode" J.Electroanal.Chem. 436. 213-218 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] I.Taniguchi: "Effect of the Structure of Modifiers Adsorbed on Gold Single Crystal Surfaces on the Promotion of the Electrode Reaction of Cytochromec" Chem.Lett.353-354 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Nakato: "Improvement of 〈indium-tin-oxide/silicon oxide/n-Si〉 junction solar cell characteristics by cyanide treatment" J.Appl.Phys.81. 7630-7634 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Uosaki: "Electrochemical Epitaxial Growth of a Pt(111)Phase on an Au(111)Electrode" J.Phys.Chem.B. 101/98. 7566-7572 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2019-02-15  

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