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分子認識機能界面とセンシング

Research Project

Project/Area Number 09237106
Research Category

Grant-in-Aid for Scientific Research on Priority Areas (A)

Allocation TypeSingle-year Grants
Research InstitutionKumamoto University

Principal Investigator

谷口 功  熊本大学, 工学部, 教授 (90112391)

Co-Investigator(Kenkyū-buntansha) 末永 智一  東北大学, 大学院・工学研究科, 教授 (70173797)
佐々木 陽一  北海道大学, 大学院・理学研究科, 教授 (30004500)
山添 昇 (山添 のぼる)  九州大学, 大学院・総合理工学研究科, 教授 (40037817)
Project Period (FY) 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥76,500,000 (Direct Cost: ¥76,500,000)
Fiscal Year 1999: ¥29,000,000 (Direct Cost: ¥29,000,000)
Fiscal Year 1998: ¥21,000,000 (Direct Cost: ¥21,000,000)
Fiscal Year 1997: ¥26,500,000 (Direct Cost: ¥26,500,000)
Keywords分子認識 / センシング / 構造規制界面 / 電極反応 / 電子移動 / 無機・有機複合界面 / 生体機能界面 / 固体型センサ
Research Abstract

本研究では、新しいセンシング機能界面の創製を目指して、1)制御無機・有機複合化界面の創製、2)酵素モデル構造性金属錯体等を用いた生体機能界面の構築、3)無機固体界面を用いたガスセンサ機能界面の構築、などの研究を進め、以下のような研究成果を得た。
1.制御無機・有機複合化界面での分子認識機能の発現に関して、シトクロムcの電気化学応答に対する明確な界面構造依存性を2-、4-ピリジンチオール(2-PySH、4-PySH)、2-ピリミジンチオール(2-PymSH)等を用いて示し、その界面構造や吸着分子のピリジン窒素のpKaは変化などをSTM測定および表面赤外分光測定から明らかにした。4-PySHの金(100)面上での吸着構造やアントラキノン部位を持つアルキルチオールの金電極上へ吸着挙動を明らかにした。
2.生体機能界面の創製と応用において、ヘムエリトリン酵素機能を有する多電子移動型のルテニウムニ核錯体の電極上への固定化に成功し、その特性を明らかにした。また、2-PymSH修飾金電極上では銅タンパク質であるアズリンの速い電子移動反応を観測した。電気化学顕微鏡を用いて単一細胞および細胞膜の機能を明らかにすると共に自己集合的に電極上にパターニングした酵素等のイメージングに成功した。
3.高選択制・無機固体型センサ機能界面の創製に関して、半導体型ガスセンサの高感度化のため酸化スズゾル粒子の分散性を制御してメソポア構造の制御によりセンサ感度を一桁向上できた。また、100ppmレベルの二酸化炭素測定用の高耐湿性・低温動作機能を持つ固体電解質型ガスセンサを開発し選択性発現のための界面構造を明らかにすると共に高機能化のメカニズムを示した。
これらの研究は、いずれも新しい機能材料・機能素子創出の基礎の確立に大きく寄与する世界をリードする研究である。

Report

(3 results)
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (94 results)

All Other

All Publications (94 results)

  • [Publications] Nishiyama,Katsuhiko: "Photochemical Reduction of NADP+ by Zinc Porphyrin Reconstituted Myoglobin as a Simple Model of Photosystem I"Chem.Lett.,. 357-358 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Uemura,Shinobu: "In situ STM visualization of Fullerlene Epitaxial Adlayers on Au(111) Surfaces Prepared by the Transfer of Langmuir Films"Chem.Lett.,. 279-280 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Nishiyama,Katsuhiko: "Phase Separation of an Unsymmetrical Disulfide SAM at an Evaporated Au(111) Electrode Monitored by Reductive Desorption and the Electrochemical Response of Cytochrome c"Chem.Lett.,. 753-754 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Taniguchi,Isao: "Electroanalytical chemistry of myoglobin with modification of distal histidine by cyanated imidazole"J.Electroanal.Chem.,. 468,. 9-18 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimoto,Soichiro: "Electorochemical study on competitive adsorption of pyridinethiol with sulfide onto Au(111) surfaces"J.Electroanal.Chem.,. 473,. 85-92 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Azehara,Hiroaki: "Investigation of structure of self-assembled monolayers of asymmetrical disulfide on Au(111) electrodes by electrochemical desorption"J.Electroanal.Chem.,. 473,. 68-74 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akashi,Tetsuyuki: "Comparison of the Electrostatic Binding Sites on the Surface of Ferredoxin for Two Ferredoxin-dependent Enzymes,Ferredoxin-NADP+Reductase and Sulfate Reductase"J.Biol.Chem.,. 274,. 29399-29405 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Ohira,Akihiro: "Self-organization of a-cyclodextrin on Au(111) surfaces induced by potential controlled adsorption"J.Electroanal.Chem.,. 472,. 163-167 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Nishiyama,Katsuhiko: "Structural differences in self-assembled monolayers of anthraquinone derivatives of silver and gold electrodes studied by cyclic voltammmetry and in situ SERS spectroscoy"J.Electroanal.Chem.,. 478,. 83-91 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Taniguchi,Isao: "Potential and pH Dependencies of Adsorbed Species of 2,4-Pyridinethiol and 2-Pyrimidinethiol on Au(111) Electrode"Electrochemistry,. 67(12),. 1197-1199 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Azehara,Hiroaki: "Electrochemical Desorption of Binary Self-Assembled Monolayers of Butyl Hexadecayl Disulfide on Au(111) Electrodes"Electrochemistry,. 67(12),. 1227-1230 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimoto,Soichiro: "STM and Voltammetric Studies on Structure of 4-Pyridinethiolate Monolayer Chemisorbed on Au(100)-(1x1) surface"Electrochemistry Communications,. 2(1),. 39-43 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Ohira,Akihiro: "Formation of the "nanotube"structure of b-cyclodextrin on Au(111) surfaces induced by potential controlled adsorption"Colloids and Surfaces A:Physicochemical and Engineering Aspects,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Taniguchi,Isao: "Simple methods for preparation of a well-defined 4-pyridinethiol modified surface on Au(111) electrodes for cytochrome c electrochemistry"Electrochim.Acta,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Sawaguchi,Takahiro: "Voltammetric and In Situ STM Studies on Self-Assembled Monolayers of 4- and 2-Mercaptopyridines and Thiophenol on Au(111) Electrodes"Electrochim.Acta,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Mie,Yasuhiro: "Electrochemical analysis of heme functions of myogloblin using semi-artificial myoglobins"Bioelectrochemistry and Bioenergetics.,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimoto,Soichiro: "Direct Observation of Structurl Change Induced by Redox Reaction of Bis(2-Anthraquinyl)disulfide SAM on Au(100)-(1x1) by in situ High Resolution STM"Langmuir,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 谷口,功: "ポイントミューテーションによるタンパク質電子機能の改変"Electrochemistry(電気化学). 68(5)(印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shimanoe,K.: "Sensing Properties and Intergfacial Structure of Solid Electrolyte CO_2 Sensor Attached with Na_2CO_3-based Auxiliary Phase"Electrochemistry,. 67,. 1258-1261 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kida,T: "Interfacial structure of NASICON-based sensor attached with Li_2CO_3-CaCO_3 auxiliary phase for detection of CO_2"Solid State Ionics,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Baik,N.-S: "Hydrothermal treatment oftin oxide sol solution for preperation of thin-film sensor with enhanced thermal stability and gas sensitivity"Sensors and Actuators B,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Baik,N.-S: "Hydrothermally treated sol solution of tin oxide for thin-film gas sensor"Sensors and Actuators B,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yamazoe,N: "Solid State Gas Sensor Design Using Froeign Receptors"Electrochemistry,. 67,. 224-231 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山添,昇: "酸素を測る"化学と教育. 47巻,10号. 660-664 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Xu,L: "[Ru(CO)(O^2CMe)(tpa)]ClO_4・C_6H_5Me(tpa=tris(2-pyridylmethyle)amine),the First Ruthenium Carbonyl Complex of tpa"Inorg.Chem.Commun.,. 2(4),. 121-123 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Inomata,T: "Interaction of Some Lewis Acids with the Oxo-bridge of(μ-Oxo)di(μ-acetato)diruthenium(III,III)Complexes and Their Electrochemical Consequence"Electorochem.,. 67(5),. 427-430 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimura,T.: "Hexarhenium(III) Clusters [Re_6(μ_3-S)_8X_6]^<2->(X=Cl.Br,I)are Luminescent at Room Temperature"Chem.Lett.,. (7),. 697-698 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Xu,L: "Syntheses and Characterization of a Series of Carbonylruthenium(I) and (II) Complexes Containing Pyridyl Ligands"J.Organomet.Chem.,. 585(2),. 246-252 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Abe,M: "Synthesis and Electochemical Characterization of Self-Assembled Monolayers of Redox-Active Oxide-Bridged Trirruthenium(III) Clusters on Au(111)"J.Electroanal,Chem.,. 473(1-2),. 93-98 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Inomata,T: "Self-Assembled Monlayers of Non-Heme Diiron(III) Model Complexes on Au(111) Electrode:Synthesis and Proton-Coupled Redox Behavior in Water"Chem.Lett.,. (10),. 1097-1098 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimura,T.: "Unusual Capping Chalcogenide Dependence of the Luminescense Quantum Yield of the Hexarhenium(III) Cyano Complexes[Re_6(μ_3-E)_8(CN)_6]^<4->,E^2=Se^2>S^2>Te^2"Chem.Lett.,. (10),. 1121-1122 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimura,T.: "Synthesis,Structures and Redox Properties of Octa(μ_3-sulfido)hexarhenium(III) Complexes Having Terminal Pyridine Ligands"Inorg.Chem.,. 38(24),. 5557-5564 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Abe,M: "Electrochemical and Infrared Spectroelectrochemical Characterization of self-Assembled Monolayers of a Carbonyl-Coordinated Trinuclear Ruthenium Complex on a Gold Electrode"Electorochem.,. 67(12),. 1162-1164 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshimura,T.: "Emission and Metal-and Ligand-Centered-Redox Characteristics of the Hexarhenium(III) Clusters trans-and-cis-[Re_6(μ_3-S)_8Cl_4(L)_4],Where L Is a Pyridine Derivative or Pyrazine"Inorg.Chem.,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Zhou,H: "Imaging the Activity of Immobilized Horse Radish Peroxidase with Scannnig Electrochemical/chemiluminescence Microscopy"Electorochemistry,. 67,. 1135-1137 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kasai,S: "Chemiluminescensce Imaging of Localized Enzymes by Scanning Chemical Reaction Microscopy"Chem.Lett.,. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yasukawa,T: "Imaging of Diaphorase Activity Micropatterned at Gold Arrays with Scanning Electrochemical Microscopy"Chem.Lett.. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 末永,智一: "マイクロ電極システムを用いた生体材料の局所機能探索と応用"表面技術. 50巻. 705-709 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 珠玖,仁: "微小空間の生物電気化学.走査型電気化学顕微鏡による生体分子機能表面の構築と評価"化学. 54巻,11号. 72-73 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 珠玖,仁: "電気化学顕微鏡の基礎と応用"表面技術. 51巻,. 46-52 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hawkridge,F.M.: "Electrochemistry of Heme Proteins in The Porphyrin Handbook(eds.)K.M.Kadish and K.M.Smith Vol.8(Electron Transfer),"Academic Press,. 200 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 谷口,功: "電気化学便覧(第9章 生物電気化学:生体内の電気化学反応)"丸善(印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Sawaguchi,T.: "Direct Observation of 4-Mercaptopyridine and Bids(4-pyridyI)disulfide Monolayyers on Au(111) in Perchloric Acid Solution Using In situ Scanning Tunneling Microscopy" Langmuir. 14,. 3565-3569 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] MIE,Y.: "Electrochemisry of myoglobins reconstituted with azahemes and mesohemes" Biolectrochem.Bioenerg.,. 46. 175-184 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] NISHIYAMA,K.: " Reductive Degradation of a [2Fe-2S] Cluster of Chlorella Ferredoxin Studied by Circular Dichroism Spectroscopy" Chem.Lett.,. 155-156 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] TANIGUCHI,I.: "Electroanalytical chemistry of myoglobin with modification of distal histidine by cyanated imidazole" J.Electroanal.Chem.,. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] TANIGUCHI,I.: "Electrochemical study on competitive adsorption of pyridinethiol with sulfide onto Au(111) surfaces" J.Electroanal.Chem.,. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] UEMURA,S.: "In situ STM visualization of Fullerlene Epitaxial Adlayers on Au(111) Surface Prepared by the Transfer of Langmuir Films" Chem.Lett.,. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] YAMAZOE,Noboru: "Potentionmetric Gas Sensors for Oxidic Gases" Journal of Electroceramics,. 2(4). 243-255 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 三浦,則雄: "酸化物半導体ガスセンサと食品品質管理" 食品工場長. 1998・6. 12-14 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山添,昇: "環境ガスセンサ研究の最近の動向" 電気学会論文誌E,. 11・2. 60-63 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] YAMAZOE,Noboru: "Hydrothermal treatment of tin oxide sol solution for preparation of thin-films sensor with enhanced thermal stability and gas sensitivity" Sensors and Actuators B,. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] XU,L.: "Syntheses,Structures and Fluctional Behavior of Tricarbonyl Mo(0)snd Trioxo Mo(VI)Complexes of Tris(2-pyridylmethl)amine with One Free Arm" Chem.Lett.,. No.2,. 163-164 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] UMAKOSHI,K.: "Synthesis and Redox Properties of Amino Acid-Bridged Dinuclear Iron(III)Complexes" Bull.Chem.Soc.Jpn.,. 72(3)(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] YOSHIMURA,T.: "Structural and Kinetic Study on the Ligand Rearrangement Reaction of 2-Aminomethylpyridine on a Di(μ-acetato)dirhodium(II) Center" Chem.Lett.,. No.3(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Xu,L.: "[Ru(CO)(O_2CMe)(tpa)]ClO_4・C_6H_5Me(tpa = tris(2-pyridylmethyl)amine),the First Ruthenium Carbonyl Complex of tpa" Inorg.Chem.Commun.,. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] INOMATA,T.: "Interaction of Some Lewis Acids with the Oxo-bridge of(μ-Oxo)di(μ-acetato)diruthenium(III,III) Complexes and Their Electrochemical Consequence" Electrochem.,. 67(5)(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] XU,L.: "Syntheses and Characterization of a Series of Carbonyl Carboxylator uthenium(I) and (II) Complexes Containing Pyridyl Ligands" J.Organomet.Chem.,. (in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] YASUKAWA,T.: "Permeation of Redox Species Through a Cell Membrane of a Single,Living Algal Protoplast Studied by Microamperometry" Biochim.Biophys.Acta,. 1369. 152-158 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] YASUKAWA,T.: "Microamperomeltic Detemination of Photosynthtic Oxygen Generation from a Single Protoplast" Denki Kagaku,. 66. 660-661 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 末永,智一: "マイクロ電極システムを用いた細胞操作とセンシング" 応用物理,. 67. 314-317 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] YASUKAWA,T.: "Microamperometric Measurements of PhotosyntheticActivity in a Single Algal Protoplast" Biophys.J.,. 76. 1129-1135 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] HAWKRIDGE,F.M.: ""Electrochemistry of Heme Proteins",Prophyrines,ed.by K.Kadish" Academic Press,New York,(in press), (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 谷口,功: "「生体分子機能電極界面の構築とセンシング-生物電気化学の新しい展開-」第11回分析化学フォーラム -極微分析法の最前線- 資料" 日本分析化学界, 42-51 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 三浦,則雄: "食品の品質管理用酸化物半導体においセンサ「半導体セラミックス」" 264-275 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] SIMADA,K.: ""reagents for Electrochemical Detections",Modern Derivatization Method for Separation Sciences,ed.T.Tovooka." John Wiley & Sons,Chapter 5, (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "Effect of the Structure of Modifiers Adsorbed on Gold Single Crystal Surfaces on the Promotion of the Electrode Reaction of Cytochrome c" Chem. Lett.353-354 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "Electrochemical Study of Biological functions of Amino Acid Residues Using Mutated Molecules of Maize Ferredoxin" Chem. Lett.929-930 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "Atomically-defined Surfaces and Artificially-designed Molecules for New Protein Electrochemistry" Proc. The 3rd Korea-Japan Joint Seminar on Electrochemistry. 127-132 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "Functional Electrodes for Probing Metalloproteins and Bioelectrochemical Systems" Interface. 6(4). 34-37 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] FUSHINUKI, Yoshito: "Determination of Methylamphetamine in Urine by Differential Pulse Polarography" Anal. Sci. 14(4). 147-158 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "Electrochemical and spectroelectrochemical properties of manganese reconstituted myoglobin" J. Electroanal. Chem.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] WANG, X.: "Sub-ppm NO2 sensing Characteristics of WO3 Thin Film Prepared by Sol-Gel Method" Jpn. Sensor Newsletter. 11(2). 12-18 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 三浦則雄: "牛肉の鮮度評価を目指した酸化物半導体ガスセンサの開発" Trans. IEE of Japan. 117-E(6). 306-313 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] YAMAURA, H: "Highly Selective CO sensor Using Indium oxide Doubly Promoted by Cobalt Oxi de and Gold" J. Electrochem. Soc.144(6). L158-L160 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] WANG, X.: "Spin-coated thin films of SiO2-WO3 composites for detection of sub-ppm NO2" Sensors & Actuators B. 45. 141-146 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] KAWATE, H.: "Interfacial Structure of CO2 Sensing Devices Using Li2CO3-BaCO3/NASICON Junction," Chem. Sens.13, Suppl. B. 97-100 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山添〓: "化学センサ" ニューセラミックス. 12. 1-5 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] KOSHI, Chikako: "Oxo-Carboxylato Bridged Diruthenium(III)Complexes of Tris(2-pyridylmethyl)amine" Chem. Lett.1155-1156 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] TACHIBANA, Junichi: "A Reversible Metalloporphyrin Oxygen Carrier Both in the Solid State and Solution : Preparation, Characterization and Kinetics of Formation of a Molybdenum(VI)Tetramesitylporphyrin Dioxygen Complex" Bull. Chem. Soc. Jpn.71(2). 363-369 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] SUGIMOTO, Hideki: "Oxorhenium(V)Complex of Amidophenolate : Structure and Redox Characteristics" Chem. Lett.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] FUKUMOTO, Tatsuma: "Preparation and Properties of a Series of the(μ-Oxo)di(μ-acetato)diruthenium(III)Complexes, [Ru2(μ-O)(μ-CH_3COO)_2(pyridine)_4(L)_2]^<2+> and [Ru2(μ-O)(μ-CH_3COO)_2(AA)_2(L)_2]^<2+>, where AA is 2, 2'-Bipyridine or 1, 10-Phenanthroline, and L is a Monodenatte Ligand" Inorg. Chim. Acta. (in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] AKIBA, Masaharu: "A Platinum(II)Complex Containing Carbon-Bonded"Nitromethane" : [Pt(CH_2NO_2)(2,2':6,2"-terpyridine)]^+" Inorg. Chem. Commun.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] JIN, Hai-Ying: "A Pair of Seven Coordinate Oxorhenium Complexes, [ReIV(O)(tpen)]^<2+> and [ReV(O)(tpen)]^<3+>(tpen=N,N,N',N'-tetrakis(2-pyridylmethyl)ethylenediamine)" Inorg. Chem.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] SHIKU, H.: "Dual Immunoassay of Human Chorionic Gonadotropin and Human Placental Lactogen at a Microfabricated Substrate by Scanning Electrochemical Microscopy" J. Electroanal. Chem.438. 187-190 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] MATSUE, T.: "Rapid Micropatterning of Living Cells by Repulsive Dielectrophoretic Force" Electrochim. Acta. 42. 3251-3256 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] YOKOYAMA, H.: "Hydorogen Peroxide Augmentation in a Rat Striatum After Methamphetamine Injec tion as Monitored in vivo by a Pt-disk microelectrode Biosens" Bioelectrn.12. 1037-1041 (1997)

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  • [Publications] SHIKU, H.: "Microfabrication of Alkylsilanized Glass Substrate by Electrogenerated Hydro xyl Radical Using Scanning electrochemical Microscopy" Langmuir,. 13. 7239-7244 (1997)

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  • [Publications] YOKOYAMA, H.: "Analysis on Microelectrode-Detected ESR(MEDESR)Signals of Nitroxide Radicals in Electrolyte Solutions" Bull. Chem. Soc. Jpn.70. 3159-3162 (1997)

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  • [Publications] 末永智一: "走査型電気化学顕(SECM)による局所センシング" 化学センサ. 13. 8-13 (1997)

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      1997 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "Novel Trens in Electroorganic Synthesis(Ed. by S. Torii)" Springer-Verlag, Tokyo, 461(175-176, 405-408) (1998)

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      1997 Annual Research Report
  • [Publications] TANIGUCHI, Isao: "New Challenge in Organic Electrochemistry(Ed. by T. Osa)" Gordon & Breach Publ., Tokyo, 361(237-252) (1998)

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  • [Publications] 山添〓: "ガスセンサ(梅澤喜夫・澤田嗣郎・中村洋監修)" エヌ・ティー・エス、東京, 550(408-415) (1997)

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      1997 Annual Research Report
  • [Publications] SHIKU, H: "Microfabrication and Characterization of Patterned Surfaces with Enzymes or Antigen-Antibodies by Scanning Electrochemical Microscopy Electron Spectroscopy and STM/AFM Analysis of Solid/Liquid Electrochemical I nterface, (G. Jerkiewicz, M. P. Soriaga, K. Uosaki, and A. Wieckowski Eds)" American Chemical Society, 202-209 (1997)

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Published: 1997-04-01   Modified: 2016-04-21  

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