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Study on Phase Transformations for New Materials and under Special Conditions

Research Project

Project/Area Number 09242104
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionTokyo Institute of Technology

Principal Investigator

NITTONO Osamu  Dept.Mat.& Ceramics Science, Tokyo Institute of Technology, Professor, 大学院・理工学研究科, 教授 (40016564)

Co-Investigator(Kenkyū-buntansha) TERASAKI Osamu  U.Tohoku, Dept. Sci., Associate Professor, 大学院・理学研究科, 助教授 (30004401)
INO Hiromitsu  U.Hosei, Fac. Eng., Professor, 工学部, 教授 (20029466)
HONO Kazuhiro  NRIM, Physcal Analysis G.Chief Researcher, 物性解析研究部, 主任研究員
HIROTSU Yoshihiko  U.Osaka, ISIR, Professor, 産研, 教授 (70016525)
MATSUI Masaaki  U.Nagoya, Dept. Eng., Professor, 大学院・工学研究科, 教授 (90013531)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥96,300,000 (Direct Cost: ¥96,300,000)
Fiscal Year 1999: ¥18,900,000 (Direct Cost: ¥18,900,000)
Fiscal Year 1998: ¥28,800,000 (Direct Cost: ¥28,800,000)
Fiscal Year 1997: ¥48,600,000 (Direct Cost: ¥48,600,000)
Keywordsphase transformation / metastable phase / atomic scale / amorphous alloy / magnetic material / nanocrystalline material / artificial multilayer / nano-composite / 原子的尺度 / アモルファス合金 / 金属人工格子 / 非晶質磁性材料 / 原始的尺度 / 準結晶 / 非晶質磁性合金 / クラスター / アトムプローブ / ナノ結晶磁性
Research Abstract

The characteristics of phase transformations have been invsestigated for new materials such as amorphous alloys and zeolite clusters, and also under various specific circumstances. About 80% of initial project planes was done in successfully. The study was done for three subjects. Main results are as follows : (1) Experimental and theoretical appoaches for understanding of phase transformations under specific circumstances ; Dr.HONO studied initial stages of phase transformations in nano-composite types of soft magnetic materials in atomic scale, and demonstrtaed that some impurities such as copper and niobium play an important role for soft magnetic properties and proposed a new concept to fabricate new types of soft materials. Dr.TERASAKI examined crystal structures in various zeolites by a combination of X-ray diffraction and electron microscopy, and also demostrated a new concept to fabricate new types of materials by controlling micro-meso spacial structures. (2)Material propertie … More s in artificially fabricated materials such as multilayers and metastable phases ; Dr.MATSUI examined the magnetic properties of arificial multilayer films containing iron element, and proposed a new model to explain the phase stability of metastable fcc and bcc iron phases. Dr.NITTONO examined various metastable phases which are hard to be formed thermodymanically, and demostrated that various metastable phases and alloys are easily fabricated under plasma states by sputtering, and various types of phase transformations are applicable to the improvement of practical materials. (3)Analysis of non-crystal to crystal types of phase transformations in amorphous alooys and quaisi-crystals ; Dr.INO examined magnetic properties of amorphous alloys containing Sm element, and explained successfully the mechanism of magmetic transformation in terms of temperature. Dr.HIROTSU developped new types of analytical techniques for amorphous alloys by the combination of electron diffraction, radial distribution analysis and structursl simulation method, and applied to the analysis of microstructures in amorphous soft magnetic materials. Some of researchers also collaborated with each other to elucidate the mechanism of the initial stage of phase separation. A lot of new knowledges which are applicable and useful were also obtained from this study. Less

Report

(4 results)
  • 2000 Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] O.Nittono, M.Azumi, Y.Hashiba M.Wakamori: "Common features of phase chnages in metastable transition metal carbides such as Fe-C, Ni-C and Co-C prepared by reactive sputtering"Proc.Intl.Conf.Solid State Phase Transformation. 1309-1312 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.G.Roy, O.Nittono: "Pelation between phase separation and properties of Al-N-Co and Al-N-Co/Al-Co films"Proc.Intl.Conf.Solid State Phase Transformation. 1313-1316 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ino, K.Tokumitsu: "Atomic and magnetic structures of Fe-Cu alloys prepared by mechanical alloying technique"Proc.Intl.Conf.Solid State Phase Transformation. 1255-1258 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Hono, M.Maruyama, L.Reich: "Clustering an segregation of Mg and Ag atoms during the precipitation processes in Al(-Li)-Cu-Mg-Ag alloys"Proc.Intl.Conf.Solid State Phase Transformation. 97-104 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] B.Sadeh, Y.Yamada, Y.Kondo M.Matsui: "Magnetic transformation of low dimensional magnetic materials"Proc.Intl.Conf.Solid State Phase Transformation. 1287-1290 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kai, T.Ohkubo, Y.Nakata Y.Hirotsu, A.Makino: "Nanostructure analysis of amorphous Fe-Zr-B(-Cu) alloys in the early stage of crystallization"Proc.Intl.Conf.Solid State Phase Transformation. 1223-1226 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] O.NITTONO, M.Azumi, Y.Hashiba, M.Wakamori: "Common features of phase changes in metastable transition metal carbides such as Fe-C, Ni-C and Co-C prepared by reactive sputtering"Proc.Intl.Conf.Solid State Phase Transformation. 1309-1312 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.G.Roy, O : NITTONO: "Relation between phase separation and properties of Al-N-Co and Al-N-Co/Al-Co films"Proc.Intl.Conf.Solid State Phase Transformation. 1313-1316 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.INO, K.Tokumitsu: "Atomic and magnetic structures of Fe-Cu alloys prepared by mechanical alloying technique"Proc.Intl.Conf.Solid State Phase Transformation. 1255-1258 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.HONO, M.Maruyama, L.Reich: "Clustering and segregation of Mg and Ag atoms during the precipitation processes in Al (Li)-Cu-Mg-Ag alloys"Proc.Intl.Conf.Solid State Phase Transformation. 97-104 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] B.Sadeh, Y.Yamada, Y.Kondo, M.MATSUI: "Magnetic transformation of low dimensional magnetic materials"Proc.Intl.Conf.Solid State Transformation. 1287-1290 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kai, T.Ohkubo, Y.Nakata, Y.HIROTSU, A.Makino: "Nanostructure analysis of amorphous Fe-Zr-B(-Cu) alloys in the early state of crystallization"Proc.Intl.Conf.Solid State Transformation. 1223-1226 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] O. Nittono, M. Azumi, Y. Hashiba, M. Wakamori: "Common features of phase changes in metastable transition metal carbides such as Fe-C, Ni-C and Co-C prepared by reactive sputtering"Proc. Intl. Conf. Solid State Phase Transformation. 1309-1312 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] A.G. Roy, O. Nittono: "Pelation between phase separation and properties of Al-N-Co and Al-N-Co/Al-Co films"Proc. Intl. Conf. Solid State Phase Transformation. 1313-1316 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Ino, K. Tokumatsu: "Atomic and magnetic structures of Fe0Cu alloys prepared by mechanical alloying technique"Proc. Intl. Conf. Solid State Phase Transformation. 1255-1258 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K. Hono, M. Maruyama, L. Reich: "Clustering and segregation of Mg and Ag atoms during the precipitation processes in Al (-Li)-Cu-Mg-Ag alloys"Proc. Intl. Conf. Solid State Phase Transformation. 97-104 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] B. Sadeh, Y. Yamada, Y. Kondo, M. Matsui: "Magnetic transformation of low dimensional magnetic materials"Proc. Intl. Conf. Solid State Phase Transformation. 1287-1290 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Kai, T. Ohkubo, Y. Nakata, Y. Hirotsu, A. Makino: "Nanostructure analysis of amorphous Fe-Zr-B (-Cu) alloys in the early stage of crystallization"Proc. Intl. Conf. Solid State Phase Transformation. 1223-1226 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.Ye,Y.Nakamura O.Nittono: "Crystal structures and phase transformation in In2Se3 compound semiconductor" Jpn.J.Appl.Phys.37. 4264-4271 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hono,Y.Zhang,A.Inoue,T.Sakurai: "Microstructure of a rapidly solidified Al-4V-2Fe ultrahigh strength aluminium alloy" Mater.Sci.Eng.A. A250. 152-157 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Yoshiike,H.Adachi H.Ino: "Structure of Melt-quenched Pr-Fe Alloy and Analysis of the Magnetization based on Super-ferromagnetism" Mater.Trans.JIM. 39. (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.R.Agger,M.E.Pemble O.Terasaki: "Growth of Quantum-Confined Indium Phosphide Inside MCM-41" J.Phys.Chem.102B. 3345-3353 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Arita,M.Matsui A.Kuwahara: "Microstructure of Fe/Cu(Au)artificial superlattice Multilayers" Thin Solid Films. 318. 180-185 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Hirotsu,T.Ohkubo: "Study of amorphou alloy structures with medium range atomic ordering" Microsc.Res.and Tech.40. 284-312 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hono, Y.Zhang, A.Inoue, T.Sakurai: "APFIM studies on nanocrystallization of amorphous alloys" Mater. Sci. Eng.A226/228. 498-502 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] O.Terasaki, T.Ohsuna N.Ohnishi, K.Hiraga: "Zeolite and related materials studied by electron microscopy" Current Opinion in Solid State & Materials Science. 2. 94-100 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Kaneko, O.Nittono: "Improved design of inverted magnetrons used for deposition of thin films on wires" Sur. & Coating Tech.90. 268-272 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Y.Kamada, M.Matsui T.Asaka: "Structure and magnetic properties of metastable Ni/bcc-Fe Multilayers" J. Phys. Soc. Japan. 66. 466-471 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Adaci, H.Ino H.Miwa: "Effect of conduction electron polarization on the magnesium of HCP samarinium metal" Physical Review. 856. 349-354 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] B.Bian, Y.Hirotsu: "Preparation of thin films of oriented iron nanocrystals" Jpn. J. Appl. Phys.36・9. L1232-1235 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2019-02-15  

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