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Adsorption heat pump using porous materials - Development of environmental friendly energy system

Research Project

Project/Area Number 09355026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 触媒・化学プロセス
Research InstitutionNagoya University

Principal Investigator

HATTORI Tadashi  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (50023172)

Co-Investigator(Kenkyū-buntansha) SATSUMA Atsushi  Nagoya University, Graduate School of Engineering, Associate Professor, 大学院・工学研究科, 助教授 (00215758)
KUNO Satoru  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (70153319)
HASATANI Masanobu  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (50021788)
WATANABE Fujio  Nagoya University, Graduate School of Engineering, Research Associate, 大学院・工学研究科, 助手 (70109312)
SAITOH Teruyukii  Nagoya University, Graduate School of Engineering, Assistant Professor, 大学院・工学研究科, 講師 (30281067)
吉田 寿雄  名古屋大学, 大学院・工学研究科, 助手 (80273267)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥30,200,000 (Direct Cost: ¥30,200,000)
Fiscal Year 1999: ¥5,500,000 (Direct Cost: ¥5,500,000)
Fiscal Year 1998: ¥7,200,000 (Direct Cost: ¥7,200,000)
Fiscal Year 1997: ¥17,500,000 (Direct Cost: ¥17,500,000)
Keywordsenvironmental friendly energy system / Adsorption heat pump / Chemical heat pump / porous material / adsorption / porous silica / local energy system / comfortableness / マイクロカロリメトリー / 吸着式ヒートポンプ / 微分吸着熱 / 伝熱促進型吸着材モジュール / 地域冷暖房 / コージェネレーション
Research Abstract

In this project, adsorption heat pump (AHP) technology was investigated by the researchers in the field of chemistry, chemical engineering and architecture. The aim of this project is (1) increase in the output of AHP system, (2) the promotion of heat and mass transfer diffusion in the AHP module, and (3) the optimization and controlling technology of the effective system for use of cold heat energy. As for the system design, the alcohol/activated carbon absorption heat pump (AHP) with a disk-module -type absorber was also proposed for producing of high quality and high power cold heat energy. The heat and mass transfer characteristics in adsorption and regeneration processes of the AHP operation were experimentally investigated. It was found that the adsorption/regeneration cycle period was about 10 times shorter than that of the packed-bed-type adsorber of SAC. The equilibrium adsorption capacity per weight was reduced by SAC modulation, but the cold heat output per unit time of the proposed AHP system was enlarged. The present system works well with regeneration temperatures of around 350 K and readily generates cold heat at around 270 K. It is concluded that AHP fabricated with the proposed disk-module adsorber units can be used as a compact refrigeration unit for generating cold heat energy below 273 K by using a low temperature waste heat energy source. Secondly, the adsorption properties of porous silica materials, i.e., zeolites, FSM-16, MCM-41 and amorphous silica, were characterized by various physico-chemical techniques. It was found that they have radical sites which is active for some chemical reactions on their surfaces. Finally, the local heat energy system, including offices, residences and stores, with AHP drove by cold heart from factories as heat sources was simulated. The effectiveness of the use of AHP for the local energy system was clarified.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (44 results)

All Other

All Publications (44 results)

  • [Publications] 渡辺藤雄、架谷昌信: "吸着ヒートポンプの吸着剤充填吸着器内熱・物質移動"伝熱研究. 36巻140号. 12-17 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 窪田光宏、松田仁樹、架谷昌信: "ヒートポンプ技術の概要-化学反応式ヒートポンプを中心に-"燃料及燃焼. 64巻3号. 12-21 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Kanamori, M. Hiramatsu, K. Katsurayama, F. Watanabe, H, Matsuda, M. Hasatani: "Production of Cold Heat Energy by Alcohol/Activated Carbon Adsorption Heat Pump with a Disk-Module-Type Adsorber"J. Chem. Eng. Japan. 30巻3号. 434-439 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Yoshida, T. Yoshida, T. Tanaka, F. Funabiki, S. Yoshida, T. Abe, K. Kimura, and T. Hattori: "Mg K-edge XAFS Study of Silica-Magnesia Systems"J. Phys. IV. 7. C2-900-912 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Yoshida, K. Kiumura, Y. Inaki and T. Hattori: "Catalytic Activity of FSM-16 for Photometathesis of Propene"Chem. Commun.. 1997. 129-130 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 金森道人、葛山弘一、渡辺藤雄、松田仁樹、架谷昌信、辻本聡一郎、栢原義孝: "平板状スーパー活性炭/伝熱版一体型吸着器で構成されるエタノール系吸着ヒートポンプの冷熱生成特性"化学工学論文集. 24巻1号. 131-141 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 金森道人、平松正義、柴田貴之、渡辺藤雄、松田仁樹、架谷昌信: "低相対水蒸気圧下におけるゼオライト/水系の吸着平衡と吸着蓄熱に関する実験的検討"化学工学論文集. 24巻2号. 243-247 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Hattori and S. Kito: "Neural Networks in Catalyst Design : An Art Turning into a Science"Proc. 15th World Petroleum Congress. 15. 783-790 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 鬼頭繁治、服部忠: "触媒化学におけるニューラルネットワークの利用"触媒. 40号3号. 169-175 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Nishi, K. Shimizu, M. Takamatsu, H. Yoshida, A. Satsuma, T. Tanaka, S. Yoshida and T. Hattori: "Deconvolution Analysis of Ga K-Edge XANES for Quantification of Gallium Coordinations in Oxide Environment"J. Phys. Chem. B. 102(50). 10190-10195 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Yoshida, C. Murata and T. Hattori: "Photooxidation of Propene to Propene Oxide by Molecular Oxygen over Zinc Oxide Dispersed on Silica"Chem. Lett.. 1999. 901-902 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 久野覚: "温熱環境における快適性-Comfortとpleasantness"The Japanese Journal of Psychonomic Science. Vol.18, No.1. 102-106 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] E. Yamamoto, K. Katsurayama, F. Watanabe, H. Matsuda, M. Hasatani: "Heat and Mass Transfer Characteristics in Adsorption of Water Vapor For Silica Gel Packed Bed Asdorber"J. Chem. Eng. Japan. 33(1). 12-18 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] A. Shichi, A. Satsuma, S. Komai and T. Hattori: "Influence of intracrystalline diffusion on the selective catalytic reduction of NO by hydrocarbons Cu-MFI zeolite"Appl. Catal. B. 24. 97-105 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] F. Watanabe, M. Hasatani: "Heat and Mass Transfer in Packed Bed Adsorber of Adsorption Heat Pump"Den-netsu Kenkyu. 36(140). 12-17 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Kubota, F. Watanabe, M. Hasatani: "Outline of Heat Pump -Focusing on Reaction Heat Pump-"Fuel and Combustion. 64(3). 12-21 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Kanamori, M. Hiramatsu, K. Katsuyama, F. Watanabe, H. Matsuda, M. Hasatani: "Production of Cold Heat Energy by Alcohol/Activated Carbon Adsorption Heat Pump with a Disk-Module-Type Adsorber"J. Chem. Eng. Japan. 30(3). 434-439 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Yoshida, T. Yoshida, T. Yoshida, T. Tanaka, F. Funabiki, S. Yoshida, T. Abe, K. Kimura, and T. Hattori: "Mg K-edge XAFS Study of Silica-Magnesia Systems"J. Phys. IV. 7. C2-900-C2-912 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Yoshida, K. Kimura, Y. Inaki and T. Hattori: "Catalytic Activity of FSM-16 for Photometathesis of Propene"Chem. Commun.. 129-130 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Kanamori, R. Fujisawa, F. Watanabe, H. Matsuda, M. Hasatani, M. Hisamatsu: "Experimental Study of Adsorption Equilibrium of Water on Zeolite and Adsorption Heat Storage under Low Relative Vapor Pressure"Kagakukougaku Ronbunshu. 24(2). 243-247 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Kanamori, R. Fujisawa, F. Watanabe, H. Matsuda, M. Hasatani, M. Hisamatsu: "Numerical Analysis of Heat and Mass Transfer Characteristics of Ethanol Adsorption Heat Pump Composed of Plate Super Activated Carbon (PSAC) and Heat Transfer Sheet"Kagakukougaku Ronbunshu. 24-6. 845-850 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Hattori and S. Kito: "Neural Networks in Catalyst Design : An Art Turning into a Science"Proc. 15ィイD1thィエD1 World Petroleum Congress. 783-790 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kito and T. Hattori: "Application of Neural Networks on Catalysis"Syokubai. 40(3). 169-175 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Nishi, K. Shimizu, M. Takamatsu, H. Yoshida, A. Satsuma, T. Tanaka, S. Yoshida and T. Hattori: "Deconvolution Analysis of Ga K-Edge XANES for Quantification of Gallium Coordinations in Oxide Environment"J. Phys. Chem. B. 102(50). 10190-10195 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Yoshida, C. Murata and T. Hattori: "Photooxidation of Propene to Propene Oxide by Molecular Oxygen over Zinc Oxide Dispersed on Silica"Chem. Lett.. 901-902 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kuno: "Comfort on Thermal Environment -Comfort and Pleasantness"The Japanese Journal of Psychonomic Science. Vol.18, No.1. 102-106 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] E. Yamamoto, K. Katsurayama, F. Watanabe, H. Matsuda, M. Hasatani: "Heat and Mass Transfer Characteristics in Adsorption of Water Vapor for Silica Gel Packed Bed Adsorber"J. Chem. Eng. Japan. 33(1). 12-18 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] A. Shichi, A. Satsuma, S. Komai and T. Hattori: "Influence of intracrystalline diffusion on the selective catalytic reduction of NO by hydrocarbons over Cu-MFI zeolite"Appl. Catal. B. 24. 97-105 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yoshida,C.Murata and T.Hattpri: "Photooxidation of Propene to Propene Oxide by Molecular Oxygen over Zinc Oxide Dispersed on Silica"Chem.Lett.. 1999. 901-902 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 久野覚: "温熱環境における快適性―Comfortとpleasantness"The Japanese Journal of Psychonomic Science. Vol.18,No.1. 102-106 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] E.Yamamoto,K.Katsurayama,F.Watanabe,H.Matsuda,M.Hasatani: "Heat and Mass Transfer Characteristics in Adsorption of Water Vapor for Silica Gel Packed Bed Adsorber"J.Chem.Eng.Japan. 33(1). 12-18 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] A.Shichi,A.Satsuma,S.Komai and T.Hattori: "Influence of intracrystalline diffusion on the selective catalytic reduction of NO by hydrocarbons over Cu-MFI zeolite"Appl.Catal. B. 24. 97-105 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 金森道人ら: "平板状スーパー活性炭/伝熱板一体型吸着器で構成されるエタノール系吸着ヒートポンプの冷熱生成特性" 化学工学論文集. 24巻. 131-133 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 金森道人ら: "低相対水蒸気圧下におけるゼオライト/水系の吸着平衡と吸着蓄熱に関する実験的検討" 化学工学論文集. 24巻. 243-247 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 金森道人ら: "平板状スーパー活性炭/伝熱板一体型吸着器の熱・物質移動に関する理論的検討" 化学工学論文集. 24巻. 845-850 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.hattori ら: "Neural Network in Catalyst Design:An Art Turning into Science" Proc.15th World Petroleum Congress. 783-790 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 坪井奈穂美ら: "広域エネルギー供給システムの最適化に関する研究 名古屋大学キャンパスへの集中式冷暖房システムの適用可能性" 日本建築学会学術講演梗概集. D-1. 557-558 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 坪井奈穂美ら: "キャンパスにおけるエネルギー供給システムの最適化に関する研究 その3:集中式冷暖房システムを適用した場合の環境評価" 空気調和・衛生工学会学術講演会講演論文集. 769-772 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 坪井奈穂美ら: "キャンパスにおける自然エネルギー利用の可能性に関する検討 その1 ヒートソース/ヒートシンクとしての貯水池利用の可能性" 太陽/風力エネルギー講演論文集. 769-772 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 石原健太郎ら: "地球環境問題とエネルギー利用に対する住民意識に関する研究 その1 調査の概要と環境問題に対する意識" 空気調和・衛生工学会学術講演会講演論文集. 1561-1564 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Michito KANAMORI, et al.: "Production of Cold Heat Energy by Alcohol/Activated Carbon Adsorption Heat Pump with a Disk-Module Type Adsorber" J.Chem.Eng.Jpn.30. 434-439 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 金森道人: "平板状スーパー活性炭/伝熱板一体型吸着器で構成されるエタノール系吸着ヒートポンプの冷熱生成特性" 化学工学論文集. 24. 131-133 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 坪井奈穂美: "広域エネルギー供給システムの最適化に関する研究-名古屋大学工学部キャンパスを対象とした予備検討-" 日本建築学会大会学術講演梗概集. D-2. 871-872 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 吉田典彦: "建物の空調負荷予測に関する研究 その1.GMDHを用いた負荷予測の検討、" 空気調和・衛生工学会学術講演会論文集. II. 521-524 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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