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Development of mass spectroscopic technique for nitric acid measurements

Research Project

Project/Area Number 09358012
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Environmental dynamic analysis
Research InstitutionNagoya University

Principal Investigator

KONDO Yutaka  Nagoya Univ., Solar-Terr.Env.Lab., Professor, 太陽地球環境研究所, 教授 (20110752)

Co-Investigator(Kenkyū-buntansha) NISHI Noriyuki  Kyoto Univ., Dep.of Science, Research Associate, 大学院・理学研究科, 助手 (00222183)
KAWASAKI Masahiro  Kyoto Univ., Dep.of Engineering, Professor, 大学院・工学研究科, 教授 (70110723)
ZHAO Yongjing  Nagoya Univ., Solar-Terr.Env.Lab., Research Associate, 太陽地球環境研究所, 助手 (00303595)
KOIKE Makoto  Nagoya Univ., Solar-Terr.Env.Lab., Associate Professor, 太陽地球環境研究所, 助教授 (00225343)
MATSUMI Yutaka  Nagoya Univ., Solar-Terr.Env.Lab., Professor, 太陽地球環境研究所, 教授 (30209605)
高木 望  日本真空技術(株), 研究室長(研究職)
中島 英彰  国立環境研究所, 主任研究員 (20217722)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥25,600,000 (Direct Cost: ¥25,600,000)
Fiscal Year 1998: ¥9,600,000 (Direct Cost: ¥9,600,000)
Fiscal Year 1997: ¥16,000,000 (Direct Cost: ¥16,000,000)
KeywordsNitric acid / nitrogen oxides / absorption / nitrogen dioxide / mass spectrometer / troposphere / stratosphere / ozone
Research Abstract

In order to measure nitric acid (HNO3) accurately, we need to establish a reliable method of calibration. For this purpose, we generated HNO3 vapor from permeation tube heated at 40 C.It was then mixed with zero air to be introduced into total reactive nitrogen (NOy) detector. HNO3 mixing ratios were determined from the NOy signals. In addition, the rate of HNO3 generation agreed with that estimated from the NOy data to within 10 %. When the air containing HNO3 was introduced into the inlet of HNO3 measuring system, significant hysterisis continued for over 20 minutes. Bu reducing the length of the inlet tube, significant improvement was observed.
When air with HNO3 mixing ratios of 0.1-10 ppbv was introduced into the mass spectrometric system, HNO3 signals were observed, roughly proportional to the HNO3 mixing ratios. However, HNO3 signals corresponding to 0.05-0.1 ppbv were observed even in the case where no HNO3 was added. This signal is interpreted to be due to the release of HNO3 from the wall of the mass spectrometric system. This shows that it is important to suppress the background signals in order to measure HNO3 with high temporal resolutions.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] Kondo,Y.,et al.: "Impact of lightning and convection on reactive nitrogen in the tropical free troposphere" J.Geophys.Res.102. 28367-28384 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo,Y.,et al.: "Reactive nitrogen and its correlation with O_3 and CO over the Pacific in winter and early spring" J.Geophys.Res.102. 28385-28404 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo,Y.,et al.: "Profiles and partitioning of reactive nitrogen over the Pacific Ocean in winter and early spring" J.Geophys.Res.102. 28405-28424 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo,Y.,et al.: "A Monte Carlo study of the upper tropospheric reactive nitrogen on PEM-West-B" J.Geophys.Res.102. 28437-28446 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo,Y.,et al.: "The performance of an aircraft instrument for the measurement of NO_y" J.Geophys.Res.102. 28663-28671 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo,Y.,et al.: "NO_y-N_2O correlation observed inside the Arctic vortex in February 1997:Dynamical and chemical effects" J.Geophys.Res.(1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kawakami, S., Y.Kondo, M.Koike, H.Nakajima, G.L.Gregory, G.W.Sachse, R.E.Newell, E.Browell, D.R.Blake, J.M.Rodriguez, and J.T.Merrill: "Impact of lightning and convection on reactive nitrogen in the tropical free troposphere" J.Geophys.Res.102. 28367-28384 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Koike, M., Y.Kondo, S.Kawakami, H.Nakajima, G.L.Gregory, G.W.Sachse, H.B.Singh, E.V.Browell, J.T.Merrill, and R.E.Newell: "Reactive nitrogen and its correlation with O_3 and CO over the Pacific in winter and early spring" J.Geophys.Res.102. 28385-28404 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo, Y., M.Koike, S.Kawakami, H.B.Singh, R.Talbot, H.Nakajima, G.L.Gregory, D.R.Blake, G.W.Sachse, and J.T.Merrill: "Profiles and partitioning of reactive nitrogen over the Pacific Ocean in winter and earlt spring" J.Geophys.Res.102. 28405-28424 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Thompson, A.M., H.B.Singh, R.W.Stewart, T.L.Kucsera, and Y.Kondo: "A Monte Carlo study of the upper tropospheric reactive nitrogen on PEM-West-B" J.Geophys.Res.102. 28437-28446 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo, Y., S.Kawakami, M.Koike, D.W.Fahey, H.Nakajima, Y.Zhao, N.Toriyama, M.Kanada, G.W.Sachse, and G.L.Gregory: "The performance of an aircraft instrument for the measurement of NO_y" J.Geophys.Res.102. 28663-28671 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondo, Y., M.Koike, A.Engel, U.Schmidt, M.Mueller, T.Sugita, H.Kanzawa, T.Nakazawa, S.Aoki, H.Irie, N.Toriyama, T.Suzuki, and Y.Sasano: "NO_y-N_2O correlation observed inside the Arctic vortex in February 1997 : Dynamical and chemical effects" J.Geophys.Res.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Kondoh,Y.,et al.: "Denitrification observed inside the Arctic vortex in February 1995" J.Geophys.Res. 103. 16221-16233 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kondo,Y.,et al.: "Correlations of NO_y with O_3 and CO over the western Pacific during PEM-West B" Procceedings of the Quadren.Ozone Symposium 1996. 387-390 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kondo,Y.,et al.: "Spectroscopic measurements of carbon monoxide at 34.5°N and 43.5°N in Japan" Proceedings of the Quadren.Ozone Symposium 1996. 643-646 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kondo,Y.,et al: "Balloon-borne optical counter for in situ aerosol measurement." J.Atmos.Chem.(1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kondo,Y.,et al: "Assessment of the uncertainties in the NO_2 and O_3 measurements by visible spectrometers" J.Atmos.Chem.(1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kondo,Y.,et al: "NO_yーN_2O correlation observed inside the Arctic vortex in February 1997:Dynamical and chemical effects" J.Geophys.Res.(1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kondo,Y., et al.: "Impact of lightning and convection on reactive nitrogen in the tropical free troposphere" J.Geophys.Res.102. 28367-28384 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kondo,Y., et al.: "Reactive nitrogen and its correlation with O_3 and CO over the Pacific in winter and early spring" J.Geophys.Res.102. 28385-28404 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kondo,Y., et al.: "Profiles and partitioning of reactive nitrogen over the Pacific Ocean in winter and early spring" J.Geophys.Res.102. 28405-28424 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kondo,Y., et al.: "A Monte Carlo study of the upper tropospheric reactive nitrogen on PEM-West-B" J.Geophys.Res.102. 28437-28446 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kondo,Y., et al.: "Evidence of heterogeneous chemistry on sulfate aerosols in stratospheric air masses measured in PEM-West B" J.Geophys.Res.102. 28425-28436 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Kondo,Y., et al.: "Implication of large scale shifts in tropospheric No_x levels in the remote tropical Pacific" J.Geophys.Res.102. 28447-28468 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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