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The Theory of Material Design for Transition Metal Oxides

Research Project

Project/Area Number 09440129
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

MAEKAWA Sadamichi  Institute for Materials Research, TOHOKU UNIVERSITY, Professor, 金属材料研究所, 教授 (60005973)

Co-Investigator(Kenkyū-buntansha) KOSHIBAE Wataru  Institute for Materials Research, TOHOKU UNIVERSITY, Research Associate, 金属材料研究所, 助手 (20273253)
ISHIHARA Sumio  Institute for Materials Research, TOHOKU UNIVERSITY, Research Associate, 金属材料研究所, 助手 (30292262)
TOHYAMA Takami  Institute for Materials Research, TOHOKU UNIVERSITY, Associate Professor, 金属材料研究所, 助教授 (70237056)
TAKAHASHI Saburo  Institute for Materials Research, TOHOKU UNIVERSITY, Research Associate, 金属材料研究所, 助手 (60171485)
KOYAMA Tomio  Institute for Materials Research, TOHOKU UNIVERSITY, Research Associate, 金属材料研究所, 助手 (30153696)
Project Period (FY) 1997 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥13,000,000 (Direct Cost: ¥13,000,000)
Fiscal Year 2000: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1999: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1998: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1997: ¥5,400,000 (Direct Cost: ¥5,400,000)
Keywordstransition metal oxides / spin / charge / orbital / orbital ordering / resonant X-ray scattering / 銅酸化物絶縁体 / 高温超伝導 / 共鳴非弾性X線散乱 / ハバードバンド / 数値的厳密対角化法 / Mn酸化物 / 巨大磁気抵抗 / 金属絶縁体転移 / 強磁性 / 強相関電子系 / 交換相互作用 / 異常X線錯乱 / 異常X線散乱 / 電荷・スピン分離 / 軌道配列 / 金属・絶縁体転移
Research Abstract

In transition metal oxides, the separation of internal degrees of freedom of election, spin charge orbital, occurs due to the strong electron correlation, thus, the degrees behave independently and complete each other. As a result, symmetry breaking quantum states (phases) appear. Than order to make the material design possible, it is of primary importance to construct the theory of observation of the order parameters of the degrees and their elementary excitations. In this research project, we have examined the possibility of observing the elementary excitations of spin and charge, i.e., spinons and holons, and succeeded in observing them, for the first time, in the angle-resolved-photoemission spectroscopy (APRES) experiment in a one-dimensional cuprate, SrCuO_2. This work has been done in collaboration with the experimental groups in University of Tokyo and Stanford University. Also developed was the theory of observation of orbital ordering by using resonant X-ray scattering (RXS) … More . The elementary excitation in the Raman scattering experiment. It was shown that the orbital governs the transport (charge degree) and magnetic (spin degree) properties in transition metal oxides. In La_<0.88>Sr_<0.12>MnO_3, the metallic state shows weak ferromagnetism in the temperature (T) region of 145<T<171K.However, below 145K, the state changes to the insulating one with strong ferromagnetism. It was shown that the occurrences of two ferromagnetic states and metal-insulator transition are caused by the orbital degree : At high temperatures, the orbital fluctuation induces entropy and stabilizes the metallic state. However, at low temperatures, the orbital ordering occurs and the energy decreases. The orbital ordering brings about the superexchange interaction, which induces the strong ferromagnetism. The orbital ordering in this compound was detected in RXS and analyzed by using the theory mentioned above.
In this research project, the theory of the internal degrees of freedom of electron, spin charge orbital, in transition metal oxides was developed and the basis of the material design was constructed. Less

Report

(5 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (69 results)

All Other

All Publications (69 results)

  • [Publications] W.Koshibae: "Interplay of Spin and Orbital orderings in perovskite Manganites"J.Phys.Soc.Jpn.. 66・4. 957-960 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Kim: "Separation of Spin and Charge Excitations in One-Dimensional SrCuO_2"Phys.Rev.B. 56・24. 15589-15595 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "Effects of Orbitals on Magnetization Process in Manganites"J.Phys.Soc.Jpn.. 66・10. 2985-2988 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Pressure Effects in Manganites with Perovskite Structure"J.Phys.Soc.Jpn.. 66・10. 2965-2968 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 前川禎通: "遷移金属酸化物の物理(その1)-銅酸化物とマンガン酸化物-"固体物理. 32・1. 21-26 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 前川禎通: "遷移金属酸化物の物理(その2)-結晶構造と物性-"固体物理. 85・18. 870-876 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Maekawa: "Electronic Structure in Manganites"J.Mag.Mag.Matr.. 177・181. 850-853 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Kim: "Systematics of the APRES Spectral Function of Cuprates : Insulator, Hole and Electron-doped Superconducotrs"Phys.Rev.Lett. 80・19. 4245-4248 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Maekawa: "Spin and Charge Excitations and Photoemission Spectra in 1D and 2D Cuprates"J.Phys.Chem.Solids. 29・10-12. 1897-1901 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takahashi: "Effect of Coulomb Blockade on Magnetoresistance in Ferromagnetic Tunnel Junctions"Phys.Rev.Lett.. 80・8. 1758-1761 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Mizuno: "Electronic States and Magnetic Properties of Edge-Sharing CuO Chains"Phys.Rev.B. 57・9. 5326-5335 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Theory of Anomalous X-ray Scattering in Orbital Ordered Manganites"Phys.Rev.Lett.. 80・17. 3799-3862 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "Incommensurate State and Spin-induced Peierls Instability"Phys.Rev.Lett.. 82・10. 1811-1814 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takahashi: "Spin-Imbalance and Magnetoresistance in Ferromagnet/Superconductor/Ferro magnet Double Tunnel Junctions"Phys.Rev.Lett.. 82・19. 3911-3914 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tohyama: "Incommensurate State and Spin-induced Peierls Instability"J.Phys.Soc.Jpn.. 69・1. 9-12 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tohyama: "Effect of Stripe on Electronic Stripe on Electronic States in Underdoped La_<2-x>Sr_xCuO_4"Phys.Rev.Lett.. 82・24. 4910-4913 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tsutsui: "Momentum Dpendence of resonant Inelastic X-Ray Scatering Spectrum in Insulating Cuprates"Phys.Rev.Lett.. 83・18. 3705-3708 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Z.Hasan: "Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering"Science. 288. 1811-1814 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Mizuno: "Nonlinear Optical Response and Spin-Charge Separation in One-Dimensional Mott Insulators"Phys.Rev.B. 62. R4769-R4772 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Theory of Orbital Ordering, Fluctuation and Resonant X-ray Scattering in Manganites"Phys.Rev.B. 62・14. R9252-R9255 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Orbital Ordering and Resonant X-Ray Scattering in Layered Manganites"Phys.Rev.B. 62・9. 5690-2695 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "Thermopower in Cobalt Oxides"Phys.Rev.B. 62・10. 6869-6872 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Khaliullin: "Orbital Liquid in Three-Dimensional Mott Insulator.LaTiO_3"Phys.Rev.Lett.. 85・18. 3950-3953 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 前川禎通: "巨大磁気伝導の新展開"アグネ技術センター. 7 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "Interplay of Spin and Orbital orderings in perovskite Manganites"J.Phys.Soc.Jpn.. 66-4. 957-960 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.kim: "Separation of Spin and Charge Excitations in One-Dimensional SrCuO_2"Phys.Rev.B. 56-24. 15589-15595 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "Effects of Orbitals on Magnetization Process in Manganites"J.Phys.Soc.Jpn.. 66-10. 2985-2988 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Pressure Effects in Manganites with Perovskite Structure"J.Phys.Soc.Jpn.. 66-10. 2965-2968 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Maekawa: "Electronic Structure in Manganites"J.Mag.Mag.Matr.. 177-181. 850-853 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] C.Kim: "Systematics of the APRES Spectral Function of Cuprates : Insulator, Hole and Electron-doped Superconducotrs"Phys.Rev.Lett. 80-19. 4245-4248 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Maekawa: "Spin and Charge Excitations and Photoemission Spectra in 1D and 2D Cuprates"J.Phys.Chem.Solids. 29-10-12. 1897-1901 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takahashi: "Effect of Coulomb Blockade on Magnetoresistance in Ferromagnetic Tunnel Junctions"Phys.Rev.Lett.. 80-8. 1758-1761 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Mizuno: "Electronic States and Magnetic Properties of Edge-Sharing CuO Chains"Phys.Rev.B. 57-9. 5326-5335 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Theory of Anomalous X-ray Scattering in Orbital Ordered Manganites"Phys.Rev.Lett.. 80-17. 3799-3862 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "ncommensurate State and Spin-induced Peierls Instability"Phys.Rev.Lett.. 82-10. 1811-1814 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takahashi: "Spin-Imbalance and Magnetoresistance in Ferromagnet/Superconductor/Ferr0magnet Double Tunnel Junctions"Phys.Rev.Lett.. 82-19. 3911-3914 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tohyama: "Incommensurate State and Spin-induced Peierls Instability"J.Phys.Soc.Jpn.. 69-1. 9-12 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tohyama: "Effect of Stripe on Electronic Stripe on Electronic States in Underdoped La_<2-x>Sr_xCuO_4"Phys.Rev.Lett.. 82-14. 4910-4913 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tsutsui: "Momentum Dpendence of resonant Inelastic X-Ray Scatering Spectrum in Insulating Cuprates"Phys.Rev.Lett.. 83-18. 3705-3808 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Z.Hasan: "Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering"Science. 288. 1811-1814 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Mizuno: "Nonlinear Optical Response and Spin-Charge Separation in One-Dimensional Mott Insulators"Phys.Rev.B. 62. R4769-R4772 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Theory of Orbital Ordering, Fluctuation and Resonant X-ray Scattering in Manganite"Phys.Rev.B. 62-10. R9252-R9255 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Ishihara: "Orbital Ordering and Resonant X-Ray Scattering in Layered Manganites"Phys.Rev.B. 62-9. 5690-5695 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Koshibae: "Thermopower in Cobalt Oxides"Phys.Rev.B. 62-10. 6859-6872 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Kahliullin: "Orbital Liquid in Three-Dimensional Mott Insulator : LaTiO_3"Phys.Rev.Lett.. 85-18. 3950-3953 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Z.Hasana: "Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering"Science. 288. 1811-1814 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Mizuno: "Nonlinear Optical Response and Spin-Charge Separation in One-Dimensional Mott Insulators"Phys.Rev.B. 62. R4769-R4772 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Ishihara: "Theory of Orbital Ordering, Fluctuation and Resonant X-ray Scattering in Manganites"Phys.Rev.B. 62・14. R9252-R9255 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Ishihara: "Orbital Ordering and Resonant X-Ray Scattering in Layered Manganites"Phys.Rev.B. 62・9. 5690-2695 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] W.Koshibae: "Thermopower in Cobalt Oxides"Phys.Rev.B. 62・10. 6869-6872 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] G.Khaliullin: "Orbital Liquid in Three-Dimensional Mott Insulator : LaTiO_3"Phys.Rev.Lett.. 85・18. 3950-3953 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Takahashi: "Spin-lmbalance and Magnetoresistance in Ferromagnet/Superconductor/Ferromagnet Double Tunnel Junctions"Phys. Rev. Lett.. 82・19. 3911-3914 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Tsutsui: "Momentum Dependence of Resonant Inelastic X-Ray Scattering Spectrum in Insulating Cuprates"Phys. Rev. Lett.. 83・18. 3705-3708 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Tohyama: "Effect of Stripe on Electronic States in Underdoped La_<2-x>Sr_xCuO_4"Phys. Rev. Lett.. 82・24. 4910-4913 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Tohyama: "Spin Liquid State around a Doped Hole in Insulating Cuprates"J. Phys. Soc. Jpn.. 69・1. 9-12 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] W.Koshibae: "Incommensurate state and spin-induced Peierls instability"Phys. Rev. Lett.. 82・10. 2119-2122 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Maekawa: "Electronic Structure in Manganites" J.Mag.Mag.Matr.177-181. 850-853 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] C.Kim: "Systematics of the ARPES Spectral Function of Cuprates:Insulator,Hole-and Electron-doped Superconductors" Phys.Rev.Lett.80・19. 4245-4248 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Maekawa: "Spin and Charge Excitations and Photoemission Spectra in 1D and 2D Cuprates" J.Phys.Chem.Solids. 59・10-12. 1897-1901 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Takahashi: "Effect of Coulmb blockade on magnetoresistence in ferromagnetic tunnel junctions" Phys.Rev.Lett.80・8. 1758-1761 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Mizuno: "Electronic states and magnetic properties of edge-sharing Cu-O chains" Phys.Rev.B. 57・9. 5326-5335 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Ishihara: "Theory of Anomalous X-ray Scattering in Orbital Ordered Mangnites" Phys.Rev.Lett.80・17. 3799-3862 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] W.Koshibae: "Interplay of Spin and Orbital Orderings in Perovskite manganites." J.Phys.Soc.Jpn.66,No.4. 957-960 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] C.Kim: "Separation of spin and charge excitations in one-dimensional SrCuO_2." Phys.Rev.B. 56,No.24. 15589-15595 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] W.Koshibae: "Effects of Orbitals on Magnetization Process in Manganites." J.Phys.Soc.Jpn.66,No.10. 2985-2988 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Isihara: "Pressure Effects in Manganites with Perovskite Structure." J.Phys.Soc.Jpn.66,No.10. 2965-2968 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 前川禎通: "遷移金属酸化物の物理(その1)-同酸化物とマンガン酸化物-" 固体物理. 32 1. 21-26 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 前川禎通: "遷移金属酸化物の物理(その2)-結晶構造と物性-" 固体物理. 3211. 870-876 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 前川禎通: "巨大磁気伝導の新展開" アグネ技術センター, 7 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2020-05-15  

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