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ELECTRONIC STATES OF DENSITY WAVES IN ORGANIC CONDUCTORS

Research Project

Project/Area Number 09440131
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅱ(磁性・金属・低温)
Research InstitutionHOKKAIDO UNIVERSITY (1998-1999)
The University of Tokyo (1997)

Principal Investigator

HASEGAWA Tatsuo (1998-1999)  Hokkaido Univ., Research Institute for Electronic Science, 電子科学研究所, 助教授 (00242016)

鹿児島 誠一 (1997)  東京大学, 大学院・総合文化研究科, 教授 (30114432)

Co-Investigator(Kenkyū-buntansha) MAEDA Atsutaka  Univ. of Tokyo, Grad. School of Arts and Sciences, 大学院・総合文化研究科, 助教授 (70183605)
長谷川 達生  北海道大学, 電子科学研究所, 助教授 (00242016)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥13,000,000 (Direct Cost: ¥13,000,000)
Fiscal Year 1999: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1998: ¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 1997: ¥6,100,000 (Direct Cost: ¥6,100,000)
KeywordsOrganic Conductors / Spin-Density Waves / Charge-Density Waves / Thermal Hysterisis / X-ray Diffuse Scattering / X線散漫錯乱
Research Abstract

The nesting instability of the Fermi surfaces in low-dimensional conductors cause the formation of density waves accompanied by a metal-to-insulator transition. An on-site electron-electron Coulomb interaction leads to spin- density waves (SDWs), while an electron-phonon interaction leads to charge-density waves (CDWs). These collective states are characteristic of low-dimensional electronic systems. It is yet unclear whether these two density-wave states can coexist or exclude each other in real materials.
In this research, we have studied the behaviors of 2kィイD2FィエD2 and 4kィイD2FィエD2 charge-density waves (CDWs) coexisting with spin-density waves (SDWs) in (TMTSF)ィイD26ィエD2PFィイD26ィエD2 and (TMTSF)ィイD22ィエD2AsFィイD26ィエD2 by diffuse X-ray scattering down to 1.6K. It was found in the PFィイD26ィエD2 compound that CDWs disappear below 3-4K while they are present in the temperature range between 4 and 12K, the SDW onset temperature. This behavior is possibly related to the subphase structure of SDW. In the AsFィイD26ィエD2 compound, the amplitude of CDW is very small, which is related to the difference between the heat capacities of these two compounds.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (25 results)

All Other

All Publications (25 results)

  • [Publications] 鹿児島誠一: "Organic Superconductors-Conducting and Superconducting Characteristics"Journal of Korean Physical Society. 31-1. 86-90 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 山口智弘: "Transport Properties of the Spin-Density-Wave Multiphase in (TMTSF)_2X"Synthetic Metals. 86. 2085-2086 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] V.A.ボンダレンコ: "A thermopower study of the SDW state of quasi one-dimensional conductor (TMTSF)_2AsF_6"Solid State Communications. 107. 477-481 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 鹿児島誠一: "Low-Temperature Diffuse X-ray Studies of Charge-Density Waves Coexisting with Spin-Density Waves in the Organic Conductors (TMTSF)_2PF_6 and (TMTSF)_2AsF_6"Solid State Communications. 110. 479-483 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 長谷川達生: "Electronic Phase Transition of BEDT-TTF-based mixed-stack CT complexes"Synthetic Metals. 103. 1804-1805 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 近藤隆祐: "Donor-Acceptor-type superconductor, (BETS)_2(CI_2TCNQ)"Chemistry Letters. 1999. 333-334 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S .Kagoshima, Y. Soso, M. Maesato, R. Kondo and T Hasegawa: "Low-Temperature Diffuse X-ray Studies of Charge-Density Waves Coexisting with Spin-Density Waves in the Organic Conductors (TMTSF)ィイD22ィエD2PFィイD26ィエD2 and (TMTSF)ィイD22ィエD2AsFィイD26ィエD2"Solid State Communications. vol.110. 479-483 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Hasegawa, T. Akutagawa, T. Nakamura, Y. Sasou, R. Kondo, S. Kagoshina, T. Mochida, G. Saito, and Y. Iwasa: "Electronic phase transition of BEDT-TTF based mixed-stack charge-transfer complexes"Synthetic Metals. vol.103. 1804-1805 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Mochida, T. Hasegawa, R. Kondo, S. Kagoshima, and Y. Iwasa: "Organic Metals Involving Double Chain Donor Arrangements"Synthetic Metals. vol.102. 1680 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Mochida, H. Moriyama, T. Hasegawa, R. Kondo, S. Kagoshinra, and Y. Iwasa: "Structure and Properties of (BEDSe-TTF)(FィイD2nィエD2TCNQ) Charge Transfer Complexes (n=1,2,4)"Synthetic Metals. vol.102. 1678-1679 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] R. Kondo, S. Kagoshima, T. Hasegawa, T. Mcchida, and Y. Iwasa: "Structure and Properties of ail organic conductor (BEDT-TseF)ィイD22ィエD2(XィイD21ィエD2XィイD22ィエD2TCNQ) (X1,X=Cl,Br)"Synthetic Metals. vol.102. 1628-1629 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] R. Kondo, T. Hasegawa, T. Mochida, S. Kagoshima, and Y. Iwasa: "Donor-Acceptor Type Superconductor, (BETS)ィイD22ィエD2(ClィイD22ィエD2TCNQ)"Chemistry Letters. vol.1999. 333-334 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] V.A. Bondarenko, S. Kagdshima, M. Maesato, T. Hasegawa, N. Miura, and T. Yamaguchi: "A thermopower study of the SDW state of quasi one-dimensional conductor (TMTSF)ィイD22ィエD2AsFィイD26ィエD2"Solid State Communications. vol.107. 477-481 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Hanasaki, S. Kagoshima, T. Hasegawa, T. Osada, and N. Miura: "Contribution of small closed orbits to magnetoresistance in quasi-two-dimensional conductors"Physical Review. vol.57. 1336-1339 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Hasegawa, K. Inukai, S. Kagoshima, T. Sugawara T. Mochida, S. Sugiura and Y. Iwasa: "(BEDT-TTF)(FィイD21ィエD2TCNQ) and (BEDT-TTF)(FィイD22ィエD2TCNQ)ィイD2xィエD2(FィイD22ィエD2TCNQ)ィイD21-xィエD2(x ca.0.5) : all-organic metals down to 2K"Chemical Communications. vol.1999. 1377-1378 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Hasegawa, S. Kagoshima, T. Mochida, S. Sugiura, and Y. Iwasa: "Electronic states and anti-ferromagnetic order in mixed-stack charge-transfer compound (BEDT-TTF)(FィイD22ィエD2TCNQ)"Solid State Communications. vol.103. 489-493 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kagoshima: ""Low-temperature diffuse X-ray studies of Charge-density Waves Coexisting with Spin-density waves in the Organic Conductors (IMTSF)_2P"Solid State Communications. 110. 479-483 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Hasegawa: ""Electronic phase transition of BEDT-TTF-based mixed-stack charge-transfer complexes"Synthetic Metals. 103. 1804-1805 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] R. Kondo: ""Donor-acceptor type superconductor, (BETS)_2(Cl_2TCNQ)"Chemistry Letters. 1999. 333-334 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Mochida: ""Organic Metals involving double chain donor arrangements"Synthetic Metals. 102. 1680 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Mochida: ""Structure and Properties of (BEDSe-TTF)(FnTCNQ) charge transfer complexes"Synthetic Metals. 102. 1678-1679 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] V.A.Bondarenko 他: "A Thermopower Study of the SDW State of Quasi-one dimensioral Conductor (TMTSF)_2AsF_6" Solid State Communication. 107. 477-481 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kagoshima 他: "Low-Temperature Diffuse X-ray Studies of Charge-Density Waves Coexisting with" Solid State Communication. (印刷中).

    • Related Report
      1998 Annual Research Report
  • [Publications] 鹿児島誠一: "Organic Superconductors-Conducting and Superconducting Charateristics" J.Korean Phys.Soc.31-1. 86-90 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山口智弘: "Transport Properties of the Spin-Density-Wave Multiphase in (TMTSF)_2X" Synthetic Metals. 86. 2085-2086 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2020-05-15  

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