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RESEARCH ON RECOMBINATION REACTIONS BETWEEN POSITIVE AND NEGATIVE IONS BY USING A CROSSED ION-BEAM METHOD

Research Project

Project/Area Number 09440201
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

TSUJI Masaharu  Inst.Advanced Material Study, KYUSHU UNIVERSITY, Ass.Prof., 機能物質科学研究所, 助教授 (30038608)

Co-Investigator(Kenkyū-buntansha) OBASE Hiroshi  Tohwa Univ.Faculty of Eng., Ass.Prof., 工学部, 助教授 (00221169)
Project Period (FY) 1997 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥14,000,000 (Direct Cost: ¥14,000,000)
Fiscal Year 2000: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1999: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1998: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1997: ¥9,300,000 (Direct Cost: ¥9,300,000)
KeywordsION BEAM / POSITIVE ION / NEGATIVE ION / EXCIMER / SPIN-ORBIT STATE / RARE GAS ION / EMISSION SPECTRUM / NEUTRALIZATION REACTION / 放電フロー法 / 再結合反応 / クラスタリング
Research Abstract

A crossed ion-beam apparatus of positive and negative ions was constructed, and applied to the following neutralization reactions leading to rare gas halide excimers :
Ar^+(^2P_<1/2,3/2>) + SF_6^-→ArF(B,C,D) + SF_5, (1)
Kr^+(^2P_<1/2>) + C_6F_5Cl^- →KrCl(B,D) + C_6F_5, (2a)
Kr^+(^2P_<3/2>) + C_6F_5Cl^- →KrCl(B,C) + C_6F_5. (2b)
ArF(B-X,C-A) and KrCl(B-X,C-A,D-X) excimers are observed in reactions (1) and (2), respectively. No significant change in ArF((B-X,C-A) excimers was found, when the Ar^+(^2P_<1/2>) spin-orbit component was removed by the addition of N_2 to Ar. This suggests that the Ar^+(^2P_<1/2>)/SF_6^- does not provide ArF^* excimer or it gives the same excimer band. The relative formation rates of KrCl(B : C : D) in reaction (2a) were 0.05 : 0.00 : 0.95, while those in reaction (2b) were 0.71 : 0.29 : 0.00. The formation rate of KrCl(C) was small in both reactions at low operating pressures below 10^<-3> Torr. It was therefore concluded that the small formation rate of KrCl(C) is not due to its relatively long radiative lifetime, but due to its intrinsic feature.
In order to obtain detailed information on the reaction dynamics of recombination reactions, theoretical ab initio calculations have been carried out for the He_2^+/C_6F_6^- reaction leading to low lying He_2^* states.
In a preliminary experiment of this research project, we discovered a number of new emissions from rare gas heterodimers and heterotrimers.

Report

(5 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (103 results)

All Other

All Publications (103 results)

  • [Publications] M.Tsuji et al.: "The B1/2→X1/2 and C_21/2→A_21/2 Transitions of ArKr^+ Produced from Argon Afterglow Reactions of Kr"Chemical Physics Letters. 266・1,2. 246-252 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Formation of the He(3s,3p,3d) States by Ion-Ion Neutralization Reaction of He^+ with C_6F_6^- in the Helium Flowing Afterglow"Chemistry Letters. 3号. 259-260 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Dissociative Excitation of CH_4 via Triplet Superexcited State by Collisions with the Metastable Ne(^3P_<0.2>) Atoms in a Ne Flowing Afterglow"Chemistry Letters. 4号. 359-360 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Formation of the He_2(c,d,e,f,C,D,E,F) States by Ion-Ion Neutralization Reaction of He_2^+ with C_6F_6^- in the Helium Flowing Afterglow"Chemistry Letters. 5号. 465-466 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Mass-Spectrometric Study on Ion-Molecule Reactions of CF_3^+ with PhX(X=F,Cl,Br,I) at Near-Thermal Energies"Bulletin of the Chemical Society of Japan. 70・5. 1179-1183 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Chemical Ionization Mass Spectra of Benzene and Toluene at Low CH_4 Pressures"Chemistry Letters. 8号. 781-782 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Mass-Spectrometric Study on Ion-Molecule Reactions of CF_3^+ with propyne, Allene, and 1-Butyne at Near-Thermal Energies"Journal of Mass Spectrometric Society of Japan. 45・4. 493-503 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Emission Spectra of NeRg_2^+(Rg=Ar,Kr,Xe), ArRg_2^+(Rg=Kr,Xe), and KrXe_2^+ Heterotrimer Ions Produced in Rare Gas Flowing Afterglows at High Stagnation Pressures"Journal of Chemical Physics. 107・13. 4852-4863 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 辻正治,西村幸雄: "熱エネルギーイオンビーム法によるプラズマプロセスガスのイオン化・分解素過程に関する研究"九州大学機能物質科学研究所報告. 11・2. 159-168 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+,C_2H_5^+, and C_3H_5^+ with Monosubstituted Benzenes Carrying a Carbonyl Group"Bulletin of the Chemical Society of Japan. 71・1. 273-283 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Nascent Rovibrational Distributions of CO(d^3Δ_i,e^3Σ^-,a′^3Σ^+) Produced in the Dissociative Recombination of CO_2^+ with Electrons"Journal of Chemical Physics. 108・19. 8031-8038 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Formation of CO(d^3Δ_i,a′^3Σ^+) by Dissociative Ion-Ion Neutralization Reaction of CO_2^+ with C_6F_6^- in the Helium Flowing Afterglow"Chemistry Letters. 5号. 413-414 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Emission Spectra of HeAr_2^+ and HeKr_2^+ Heterotrimer Ions Produced in a Helium Flowing Afterglow"Chemical Physics. 236・1-3. 319-329 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Formation of XeBr^*, Xe^*, and Br^* by the Xe^+(^2P_<1/2>)/Br^-/He and Xe^+(^2P_<3/2>)/Br^-/He Three-Body Ionic-Recombination Reactions in a Helium Flowing Afterglow"Journal of Chemical Physics. 109・9. 3374-3385 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Electronic State Distributions of He(ns,np,nd) Rydberg States Produced from Three-Body Collisional Radiative Recombination of He^+ in a Helium Flowing Afterglow"Japanese Journal of Applied Physics. 37・10. 5775-5780 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Photoelectrons Ejected from a Zirconium Surface by One-Photon or Two-Photon Laser Ionization in Air"九州大学機能物質科学研究所報告. 12・2. 141-143 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Formation of He^* by Ion-Ion Neutralization Reactions of He^+ with C_6F_5X^-(X=F,Cl,Br,CF_3) in a Helium Flowing Afterglow"Journal of Chemical Physics. 110・6. 2903-2910 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "The Influence of Vibrational Excited States of NO^+(X^1Σ^+ : v") on the Formation of NO^* by the NO^+(X)+C_6F_6^- Ion-Ion Neutralization Reaction at Thermal Energy"Bulletin of the Chemical Society of Japan. 72・2. 227-233 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+,C_2H_5^+, and C_3H_5^+ with Anilines, Benzonitrile, and Nitrobenzene"Bulletin of the Chemical Society of Japan. 72・2. 293-301 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Nascent Rovibrational Distributions of NO^+(A^1 TT) Produced from the Charge-Transfer Reaction of He_2^+ with NO at Thermal Energy"Journal of Chemical Physics. 110・18. 9064-9070 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 辻正治: "希ガスへテロクラスターイオンの電子構造と生成素過程"分光研究. 48・2. 57-67 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "A New Technique for a Selective Observation of Charge-Transfer Reactions by He^+ in a Helium Afterglow"九州大学機能物質科学研究所報告. 13・1. 37-39 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Vibrational Distributions of SO^+(A^2TT_i) Produced from Dissociative Ionization of SO-Containing Molecules in a Helium Flowing Afterglow"九州大学総合理工学研究科報告. 21・1. 1-8 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Chemical Ionization of n-Paraffins (C_<14>-C_<18>) by CH_5^+,C_2H_5^+, and C_3H_5^+ in an Ion-Trap Type of Mass Spectrometer"Chemistry Letters. 12号. 1281-1282 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Vibrational Distribution of N_2(B^3TT_g) Produced from Dissociative Recombination of N_2O^+ in a Helium Flowing Afterglow"Chemistry Letters. 6号. 592-593 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+,C_2H_5^+, and C_3H_5^+ with Benzoic Acid and Benzoates"Bulletin of the Chemical Society of Japan. 73・7. 1673-1684 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Chemical Ionization of 1-Olefins (C_<15>-C_<18>) by CH_5^+, C_2H_5^+, and C_3H_5^+ in an Ion-Trap Type of Mass Spectrometer"Chemistry Letters. 8号. 892-893 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Electronic-State Distributions of Ne^* Formed by Energy Transfer from He(2^1S,2^3S) to Ne at Thermal Energy"Japanese Journal of Applied Physics. 39・8. 4970-4977 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "An Efficient Decomposition of NO into N_2 and O_2 in a Fast Discharge Flow of NO/He Mixtures"Japanese Journal of Applied Physics. 39・9A/B. L933-L935 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Superior Decomposition of N_2O into N_2 and O_2 in a Fast Discharge Flow of N_2O/He or N_2O/Ar Mixtures"Japanese Journal of Applied Physics. 39・12B. L1330-L1333 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Tanaka,M.Tsuji,and Y.Nishimura: "Mass-Spectormetric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with C_8-C_<18> n-Paraffins in an Ion Trap"Bulletin of the Chemical Society of Japan. 73・12. 2703-2712 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji et al.: "Decomposition of CO_2 into CO and O by a Microwave-Excited Discharge Flow of CO_2/He and CO_2/Ar Mixtures"Chemistry Letters. 1号. 22-23 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Tanaka and M.Tsuji: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with C_8-C_<18> 1-Olefins in an Ion Trap"Bulletin of the Chemical Society of Japan. 74・5(印刷中). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 辻正治: "熱エネルギー電荷移動反応における試料分子の振動励起効果"放射線化学. (印刷中). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji: "Advanced in Gas Phase Ion Chemistry,Vol.4,Edited by N.G.Adams and L.Babcock,JAI Press,Inc,Connecticut,USA"Flowing Afterglow Optical Studies of Electronic Stuctures and Reactions of Small Rare Gas Cluster Ions(印刷中). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Tanaka, and Y.Nishimura: "The B 1/2 → X 1/2 and C_21/2 → A_21/2 Transitions of ArKr^+ Produced from Argon Afterglow Reactions of Kr"Chem.Phys.Lett.. 266-1,2. 246-252 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Nakamura, and Y.Nishimura: "Formation of the He (3s, 3p, 3d) States by Ion-Ion Neutralization Reaction of He^+ with C_6F_6^-in the Helium Flowing"Chem.Lett.. 3. 259-260 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Komatsu, M.Tanaka, M.Nakamura, Y.Nishimura, and H.Obase: "Dissociative Excitation of CH_4 via Triplet Superexcited State by Collisions with the Metastable Ne (^3P_<0,2>) Atoms in a Ne Flowing Afterglow"Chem.Lett.. 4. 359-360 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, E.Oda, M.Tanaka, M.Nakamura, and Y.Nishimura: "Formation of the He_2(c, d, e, f, C,D,E,F) States by Ion-Ion Neutralization Reaction of He_2^+ with C_6F_6^- in the Helium Flowing Afterglow"Chem. Lett.. 5. 465-466 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Aizawa, E.Oda, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CF_3^+ with PhX(X=F, Cl, Br, I) at Near-Thermal Energies"Bull.Chem.Soc.Jpn.. 70-5. 1179-1183 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, E.Oda, and Y.Nishimura: "Chemical Ionization Mass Spectra of Benzene and Toluene at Low CH_4 Pressures"Chem.Lett.. 8. 781-782 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Aizawa, E.Oda, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CF_3^+ with Propyne, Allene, and 1-Butyne at Near-Thermal Energies"J.Mass Spectrom.Soc.Jpn.. 45-4. 493-503 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Tanaka, and Y.Nishimura: "Emission Spectra of NeRg_2^+ (Rg=Ar, Kr, Xe), ArRg_2^+ (Rg=Kr, Xe), and KrXe_2^+ Heterotrimer Ions Produced in Rare Gas Flowing Afterglowsat High Stagnation Pressures"J.Chem.Phys.. 107-13. 4852-4863 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji and Y.Nishimura: "Studies of Ionization and Dissociation Processes of Plasma Processing Gases Using a Thermal-Energy Beam Method"Rep.Inst.Adv.Mater.Study, Kyushu Univ.. 11-2. 159-168 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Arikawa, Y.Tanaka, and Y.Nishimura Tsuji: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with Monosubstituted Benzenes Carrying a Carbonyl Group"Bull.Chem.Soc.Jpn.. 71-1. 273-283 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Nakamura, Y.Nishimura, and H.Obase: "Nascent Rovibrational Distributions of CO(d^3Δ_i, e^3Σ^-, a'^3Σ^+) Produced in the Dissociative Recombination of CO_2^+ with Electrons"J.Chem.Phys.. 108-19. 8031-8038 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, E.Oda, M.Nakamura, and Y.Nishimura: "Formation of CO (d^3Δ_i, a'^3Σ^+) by Dissociative Ion-Ion Neutralization Reaction of CO_2^+ with C_6F_6^- in the Helium Flowing AfterglowChem. Lett., No.5, 413-414 (1998)."Chem.Lett.. 5. 413-414 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Tanaka, E.Oda, H.Ishimi, and Y.Nishimura: "Emission Spectra of HeAr_2^+ and HeKr_2^+ Heterotrimer Ions Produced in a Helium Flowing Afterglow"Chem.Phys.. 236-1-3. 319-329 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Ide, E.Oda, and Y.Nishimura: "Formation of XeBr^*, Xe^*, and Br^* by the Xe^+(^2P_<1/2>/)Br^-/He and Xe^+(^2P_<3/2>)/Br^-/He Three-Body Ionic-Recombination Reactions in a Helium Flowing Afterglow"J.Chem.Phys.. 109-9. 3374-3385 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Nakamura, E.Oda, M.Hisano, and Y.Nishimura: "Electronic State Distributions of He(ns, np, nd) Rydberg States Produced from Three-Body collisional Radiative Recombination of He^+ in a Helium Flowing Afterglow"Jpn.J.Appl.Phys.. 37-10. 5775-5780 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, H.Oota, and Y.Nishimura: "Photoelectrons Ejected from a Zirconium Surface by One-Photon or Two-Photon Laser Ionization in Air"Rep.Inst.Adv.Mater.Study, Kyushu Univ.. 12-2. 141-143 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Nakamura, Y.Nishimura, E.Oda, H.Oota, and M.Hisano: "Formation of He^* by Ion-Ion Neutralization Reactions of He^+ with C_6F_5X^- (X=F, Cl, Br, CF_3) in a Helium Flowing Afterglow"J.Chem.Phys.. 110-6. 2903-2910 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, H.Ishimi, H.Oota, M.Hisano, and Y.Nishimura: "The Influence of Vibrational Excited States of NO^+(X^1Σ^+ : v^n) on the Formation of NO^* by the NO^+(X)+C_6F_6^- Ion-Ion Neutralization Reaction at Thermal Energy"Bull.Chem.Soc.Jpn.. 72-2. 227-233 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, K.Arikawa, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with Anilines, Benzonitrile, and Nitrobenzene"Bull.Chem.Soc.Jpn.. 72-2. 293-301 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, H.Ishimi, M.Hisano, H.Oota, and Y.Nishimura: "Nascent Rovibrational Distributions of NO^+(A^1Π) Produced from the Charge-Transfer Reaction of He_2^+ with NO at Thermal Energy"J.Chem.Phys.. 110-18. 9064-9070 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji: "Electronic Structure and Formation Mechanism of Rare Gas Heterocluster Ions"J.Spectrosc.Soc.Jpn.. 48-2. 57-67 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Hamagami, T.Tanoue, and Y.Nishimura: "A New Technique for a Selective Observation of Charge-Transfer Reactions by He^+ in a Helium Afterglow"Rep.Inst.Adv.Mater.Study, Kyushu Univ.. 13-1. 37-39 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, I.Murakami, S.Okano, and Y.Nishimura: "Vibrational Distributions of SO^+(A^2Π_i) Produced from Dissociative Ionization of SO-Containing Molecules in a Helium Flowing Afterglow"Rep.Grad.School Eng.Sci., Kyushu Univ.. 21-1. 1-8 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, Y.Tanaka, T.Arikawa, and Y.Nishimura: "Chemical Ionization of n-Paraffins (C_<14>-C_<18>) by CH_5^+, C_2H_5^+, and C_3H_5^+ in an Ion-Trap Type of Mass Spectrometer"Bull.Chem.Soc.Jpn.. 73-7. 131-145 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Arikawa, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with Monosubstituted Benzenes Carrying a Hydroxy Group"Chem.Lett.. 12. 1281-1282 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Tanoue, Y.Tanaka, and Y.Nishimura: "Vibrational Distribution of N_2(B^2Π_g) Produced from Dissociative Recombination of N_2O^+ in a Helium Flowing Afterglow"Chem.Lett.. 6. 592-593 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Arikawa, Y.Tanaka, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with Benzoic Acid and Benzoates"Bull.Chem.Soc.Jpn.. 73-7. 1673-1684 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, Y.Tanaka, T.Arikawa, and Y.Nishimura: "Chemical Ionization of 1-Olefins (C_<15>-C_<18>) by CH_5^+, C_2H_5^+, and C_3H_5^+ in an Ion-Trap Type of Mass Spectrometer"Chem.Lett.. 8. 892-893 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, M.Hisano, T.Tanoue, and Y.Nishimura: "Electronic-State Distributions of Ne^* Formed by Energy Transfer from He(2^1S,2^3S) to Ne at Thermal Energy"Jpn.J.Appl.Phys.. 39-8. 4970-4977 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, A.Tanaka, T.Hamagami, K.Nakano, and Y.Nishimura: "An Efficient Decomposition of NO into N_2 and O_2 in a Fast Discharge Flow of He/NO Mixtures"Jpn.J.Appl.Phys.. 39-9A/B. L933-L935 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Tanaka, M.Tsuji, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with C_8-C_<18> n-Paraffins in an Ion Trap"Bull.Chem.Soc.Jpn.. 73-12. 2703-2712 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Tanoue, K.Nakano, A.Tanaka, and Y.Nishimura: "Superior Decomposition of N_<>O into N_2 and O_2 in a Fast Discharge Flow of N_2O/He or N_2O/Ar Mixtures"Jpn.J.Appl.Phys.. 39-12B. L1330-L1333

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Tanoue, K.Nakano, and Y.Nishimura: "Decomposition of CO_2 into CO and O by a Microwave-Excited Discharge Flow of CO_2/He and CO_2/Ar Mixtures"Chem.Lett.. 1. 22-23 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji: "Effects of Vibrational Excitation of Reagent Molecules in Thermal-Energy Charge-Transfer Reactions"Radiation Chemistry. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji: "Flowing Afterglow Optical Studies of Electronic Structures and Reactions of Rare Gas Cluster Ions"Advanced in Gas Phase Ion Chemistry, Academic Press. (in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Tanaka and M.Tsuji: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with C_8-_<18> 1-Olefins in an Ion Trap"Bull.Chem.Soc.Jpn.. 74-5 (in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tsuji, T.Tanoue, Y.Tanaka, and Y.Nishimura: "Vibrational Distribution of N_2(B^3П_g) Produced from Dissociative Recombination of N_2O^+ in a Helium Flowing Afterglow"Chemistry Letters. 6号. 592-593 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji, T.Arikawa, Y.Tanaka, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+with Benzoic Acid and Benzoates"Bulletin of the Chemical Society of Japan. 73・7. 1673-1684 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji, Y.Tanaka, T.Arikawa, and Y.Nishimura: "Chemical Ionization of 1-Olefins (C_<15>-C_<18>)by CH_5^+, C_2H_5^+, and C_3H_5^+in an Ion-Trap Type of Mass Spectrometer"Chemistry Letters. 8号. 892-893 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji, M.Hisano, T.Tanoue, and Y.Nishimura: "Electronic-State Distributions of Ne^* Formed by Energy Transfer from He(2^1S, 2^3S) to Ne at Thermal Energy"Japanese Journal of Applied Physics. 39・8. 4970-4977 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji, A.Tanaka, T.Hamagami, K.Nakano, and Y.Nishimura: "An Efficient Decomposition of NO into N_2 and O_2 in a Fast Discharge Flow of NO/He Mixtures"Japanese Journa1 of Applied Physics. 39・9A/B. L933-L935 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji, T.Tanoue, K.Nakano, A.Tanaka, and Y.Nishimura: "Superior Decomposition of N_2O into N_2 and O_2 in a Fast Discharge Flow of N_2O/He or N_2O/Ar Mixtures"Japanese Journal of Applied Physics. 39・12B. L1330-L1333 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Tanaka, M.Tsuji, and Y.Nishimura: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with C_8-C_<18> n-paraffins in an Ion Trap"Bulletin of the Chemical Society of Japan. 73・12. 2703-2712 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji, T.Tanoue, K.Nakano, and Y.Nishimura: "Decomposition of CO_2 into CO and O by a Microwave-Excited Discharge Flow of CO_2/He and CO_2/Ar Mixtures"Chemistry Letters. 1号. 22-23 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Y.Tanaka and M.Tsuji: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_5^+, C_2H_5^+, and C_3H_5^+ with C_8-C_<18> 1-Olefins in an Ion Trap"Bulletin or the Chemical Society of Japan. (印刷中). (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 辻正治: "熱エネルギー電荷移動反応における試料分子の振動励起効果"放射線化学. (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tsuji: "Advanced in Gas Phase Ion Chemistry, Vol. 4, Edited by N.G.Adams and L.Babcock, JAI Press, Inc, Connecticut, USA"Flowing Afterglow Optical Studies of Electronic Structures and Reactions of Small Rare Gas Cluster Ions (印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Masaharu Tsuji: "Mass-Spectrometric Study on Ion-Molecule Reactions of CH_s^+,C_3H_5^+ with Anilines,Benzonitrie,and Nitrobenzene"Buletin of the chemical Society of Japan. 72・2. 293-301 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaharu Tsuji: "Nascent Rovibrational Distributions of No^+(A^1II)Produced from the Charge-Transfer Reaction of He_2^+ with NO at Thermal Energy"Journal of Chemical Physics. 110・18. 9064-9070 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 辻 正治: "希ガスヘテロクラスターイオンの電子構造と生成素過程"分光研究. 48・2. 57-67 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaharu Tsuji: "A New Technique for a Selective Observation-Transfer Reactions by He'in a Helium Afterglow"九州大学機能物質科学研究所報告. 13・1. 37-39 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaharu Tsuji: "Vibrational Distrubutions of SO^+(A^2Π_1)Produced from Dissociative Ionization of S-Containing Molecules in a Helium Flowing Afterglow"九州大学総合理学研究科報告. 21・1. 1-8 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaharu Tsuji: "Chemical Ionization of n-paraffins (C_<14>-C_<18>)by CH_5_+,C_2H_5^+ in an Ion-Trap Type of Mass Spectrometer"Chemistry Letters. 12. 1281-1282 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaharu Tsuji: "Mass-Spectrometric study on Ion-Molecule Reactions of CH_2^+,C_2H_5^+,and C_2H_5^+ with Monosubstituted Benzenes Carrying a Hydroxy Group"Bulletin of the Chemical Society of Japan. 73・1. 131-145 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaharu Tsuji: "Nascent Rovibrational Distributions of CO(d^3△.,a^3Σ)Produced in the Dissociative Recombination of CO_2 with Electrons" Journal of Chemical Physics. 108・19. 8031-8038 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "Formation of CO(d^3△.,a^3)by Dissociative Ion-Ion Neutralization Reaction of CO_2 with C_6F_6 in the Helium Flowing Afterglow" Chemistry Letters. 1885・5. 413-414 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "Formation of XeBr,Xe,and Br by the Xe (^2P_<1/2>)/Br/He and Xe(^2P_<2/3>)/Br/He Three-Body Ionic-Recombination Reactions in a Helium Flowing Afterglow" Journal of Chemical Physics. 109・9. 3374-3385 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "Electronic State Distributions of He^※ Produced by Collisional Radiative Recombination of He in the Helium Flowing Afterglow" Japanese Journal of Applied Physics. 37・10. 5775-5780 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "Emission Spectra of HeAr^2 and HeKr_2 Heterotrimer Ions Produced in a Helium Flowing Afterglow" Chemical Physics. 236・1-3. 319-329 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "Photoelectrons Ejected from a Zirconium Surface by One-Photon or Two-Photon Lasea Ionization in Air" 九州大学機能物質科学研究所報告. 12・2. 43-45 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "Formation of He Ryberg Sates by Ion-Ion Neutralization Reactions of He with C_4F_5X(X=F,Cl,Br,CF_3) in a Helium Flowing Afterglow" Journal of Chemical Physics. 110・6. 2903-2910 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "The Influence of Vebrational Excited States of NO‘(X'Σ:v)on the Formation of NO by the NO(X) + C_4F_6 Ion-Ion Neutralization Reaction at Thermal Energy" Bulletin of the Chemical Society of Japan. 72・2. 293-301 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masaharu Tsuji: "The B 1/2→X 1/2 and C_2 1/2→A_2 1/2 Transitions of ArKr^+ Produced from Argon Afterglow Reactions of Kr" Chemical Physics Letters. 266・1/2. 246-252 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Masaharu Tsuji: "Formation of the He(3s,3p,3d)States by Ion-Ion Neutralization Reactions of He^+ with C_6F_6^- in the Helium Flowing Afterglow" Chemistry Letters. 1997・3. 259-260 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Masaharu Tsuji: "Formation of the He_2(c,d,e,f,C,D,E,F)States by Ion-Ion Neutralization Reaction of He_2^+ with C_6F_6^- in the Helium Flowing Afterglow" Chemistry Letters. 1997・5. 465-466 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Masaharu Tsuji: "Emission Spectra of NeRg_2^+(Rg=Ar,Kr,Xe),ArRg_2^+(Rg=Kr,Xe),and KrXe_2^+ Heterotrimer Ions Produced in Rare Gas Flowing Afterglows at High Stagnation Prossures" Journal of Chemical Physics. 107・13. 4852-4863 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Masaharu Tsuji: "Nascent Rovibrational Distributions of CO(d^3Δ_1,e^3Σ^-,a′^3Σ^+)Produced in the Dissociative Recombination of CO_2^+ with Electrons" Journal of Chemical Phsics. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] Masaharu Tsuji: "Formation of CO(d^3Δ_1,a′^3Σ^+)by Dissociative Produced Ion-Ion Neutralization Reaction CO_2^+ with C_6F_6^- in the Helium Flowing Afterglow" Chemistry Letters. (印刷中). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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