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The precise determination of the concentrations of defects at thermal equilibrium in Si and Ge by means of simultaneous measurements of positron annihilation and positron diffusion characteristics

Research Project

Project/Area Number 09450005
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionUniversity of Tsukuba

Principal Investigator

TANIGAWA Shoichiro  University of Tsukuba, Institute of Materials Science, Professor, 物質工学系, 教授 (90011080)

Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥12,200,000 (Direct Cost: ¥12,200,000)
Fiscal Year 1998: ¥3,900,000 (Direct Cost: ¥3,900,000)
Fiscal Year 1997: ¥8,300,000 (Direct Cost: ¥8,300,000)
Keywordssilicon / germanium / thermal equilibrium defects / positron annihilation / diffusion of positrons / FZ-silicon / Cz-silicon / 陽電子消減
Research Abstract

Fort the purpose of precise determination of the concentrations of defects at thermal equilibrium in Si and Ge, the positron annihilation and positron diffusion characteristics were measured as a function of temperature. After constructing the ultra short pulse monoenergetic positron beam in FY1997 and installation of a heating system based on ultra-red light in FY1998, the measurements of positron annihilation characteristics were measured between 300K and 1200K in Ge, and between 300K and 1600K in Si, respectively. In Ge, although the positron annihilation characteristics showed a nearly constant behavior between 300K and 600K and started a slight change above 600K, the diffusion length of positrons showed a big decrease between 300K and 600K and kept a constant value above 600K.In Si, the overall temperature dependence was found to be nearly the same as that in Ge except for the shift to the higher temperature. region as compared with Ge. On the defects at high temperatures at therm … More al equilibrium in Si, two observations reported contradictory results ; one is based on the internal ^<22>Na source produced by proton irradiation, the other is based on the beta gamma coincidence technique using the Pelletron accelerator. The present result is in good agreement with the latter investigation. From the precise result of the present work, it was concluded that the observed results in the former experiment should be due to the growth of vacancy clusters at high temperatures. From the precise analyses of the present results, the observed small change in positron annihilation characteristics in intermediate temperature region was attributed to the presence of self-trapping effect due to positron-lattice coupling.
In order to obtain the information on the thermal equilibrium defects, the slow cooling of FZ-, Cz- and Hydrogen-annealed- Si wafers from the high temperature near the melting was examined by the 2D-ACAR measurements. As a result, in the order of contained concentration of oxygen atoms, small oxide precipitates, oxygen substitutional atoms, vacancy-oxygen complexes, and divacancies were observed in the concentration of the order of 10^<15>-10^<16>cm^<-3>. Less

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] T.Kitano: "Annealing properties in BF^+_2-implanted Si" MRS symp.proc.438. 137-142 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Watanabe: "Effect of vacancy-type defects on electrical activation of Pt.implantation into Si" MRS symp.proc.438. 131-136 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] A.Uedono: "Annealing properties of defects in B^+ -and F^+ -implanted Si studied using monoenergetic positron beams" Jpn.J.Appl.Phys.36. 2571-2580 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] A.Uedono: "Florine-related defects in BF^+_2 -implanted Si probed by monoenergetic positron beams" Jpn.J.Appl.Phys.36. 969-974 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Tanigawa: "Creation and annealing out mechanism of defects in ion-implanted Si crystals investigated by positron anihilation" MRS symp.proc.470. 287-297 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 森 照明: "対向型陽電子消滅γ線ドップラー拡がり測定装置の製作" Radioisotopes. 47. 623-627 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 谷川庄一郎(分担): "人工結晶と先端デバイス技術第4章1節" 三共出版, 210 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kitano et al.: ""Annealing properties in BF^+-implanted Si"" MRS Symp.Proc.438. 137-142 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Watanabe et al.: ""Effect of vacancy-type defects on electron activation of P^+ implantation into Si"" MRS Symp.Proc.438. 131-136 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] A.Uedono et al.: ""Annealing properties of defects in B^+- and F^+-implanted Si studied using monoenergetic positron beams"" Jpn.J.Appl.Phys.36. 2571-2580 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] A.Uedono et al.: ""Florine-related defects in BF_2^+-implanted Si probed by monoenergetic positron beams"" Jpn.J.Appl.Phys.36. 969-974

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Tanigawa: ""Creation and annealing out mechanism of defects in ion-implanted Si crystals investigated by positron annihilation"" MRS Symp.Proc.470. 287-297 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Mori et al.: ""Two detector positron annihilation Doppler broadening measurement system"" Radioisotopes. 47. 623-627 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Tanigawa: "Synthesized crystals and advanced device technology" Chapter 4.1. Sankyo Shuppan, 210 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kitano: "Annealing properties in BF^+_2-implanted Si" MRS symp.proc.438. 137-142 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Watanabe: "Effect of vacancy-type defects on electrical activation of Pt implantation into Si" MRS Symp.proc.438. 131-136 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] A.Uedono: "Annealing properties of defects in B^+-and F^+-implanted Si studied using monoenergetic positron beams" Jpn.J.Appl.Phys.36. 2571-2580 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] A.Uedono: "Florine-related defects in BF^+_2-implanted Si probed by monoenergetic positron beams" Jpn.J.Appl.Phys.36. 969-974 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Tanigawa: "Creation and annealing out mechanism of defects in ion-implanted Si crystals investigated by positron annihilation" MRS symp.proc.470. 287-297 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] 森 照明: "対向型陽電子消滅γ線ドップラー拡がり測定装置の製作" Radioisotopes. 47. 623-627 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 谷川 庄一郎(分担): "人工結晶と先端デバイス技術 第4章1節" 三共出版, 210 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Kitano: "Annealing properties of defects in BF_2^+ implanted Si" MRS Symp.Proc.438. 137-142 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Watanabe: "Effect of vacancy-type defects on electrical activation of P^+ implantation into silicon" MRS Symp.Proc.438. 131-136 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Itoh: "Intrinsic defects in cubic silicon carbide" phys.stat.sol.(a). 162. 173-198 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Itoh: "Positron annihilation studies of defects in 3C-SiC hot-implanted with nitrogen and aluminum ions" Appl.Phys.A. 65. 315-323 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] J.L.Lee: "Evidence for the formation of N^+-GaAs layer in Pd/Ge ohmic contact to N-type GaAs" J.Appl.Phys.82. 5460-5464 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Characterization of residual defects in cubic silicon carbide after hot-implantation and subsequent annealing: "J.Appl.Phys." 82. 1997. (5339-5347)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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