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Nano-Scale Structure Control of Organic/Metal Interface and photocurrent Multiplication Device

Research Project

Project/Area Number 09450012
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionOsaka University

Principal Investigator

HIRAMOTO Masahiro  Osaka University, Faculty of Engineering, Associate Professor, 大学院・工学研究科, 助教授 (20208854)

Co-Investigator(Kenkyū-buntansha) YOKOYAMA Masaki  Osaka University, Faculty of Engineering, Professor, 大学院・工学研究科, 教授 (90029281)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥13,400,000 (Direct Cost: ¥13,400,000)
Fiscal Year 1998: ¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1997: ¥10,500,000 (Direct Cost: ¥10,500,000)
Keywordsphotocurrent multiplication / organic / metal interface / multiplication-type photosensor / transient response / AFM / tunneling / 原子力間力顕微鏡 / トンネリング / 高速応答 / シリコン基板 / 原子間力顕微鏡 / 金超微粒子
Research Abstract

We have observed a large photocurrent multiplication reaching 105-fold in various organic films. Aim of research is the clarification of the multiplication mechanism and the application to the multiplication-type photo-sensing device. Following results were obtained.
1. The transient response of the photocurrent multiplication phenomenon was revealed to have two components, which were identified as the primary and the subsequent multiplied photocurrents. This clearly supports the proposed mechanism based on tunneling electron injection from a metal electrode to the organic layer triggered by the photo-accumulated space charges of trapped holes near the organic/metal interface. Based on this result, high speed response of multiplication device was successfully fabricated.
2. Metal film deposited on organic surface was revealed to be a gathering of particles of nanometer scale by atomic force microscopy (AFM), and moreover, the multiplication rate increased with the size of nano-particles. This result confirms that there are the spatially separated parts, I.e., the blind alleys acting as the structural traps at organic/metal interface, which causes the multiplication.
3. By using AEM probe, microscopic observation of surface potential of organic film capturing holes was accomplished. Relation between the structural trap sites and the surface molecular stacking was suggested.
4. Multiplication devices on silicon chip were successfully fabricated. Above results clearly show that the application of multiplication phenomenon to high sensitive photosensor is possible.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] M.Hiramoto: "Photocurrent Multiplication Phenomenon at Organic/Organic Heterojunction and Application to Optical Conputing Pevice Combining with Organic Electroluminescence"Synthetic Metals. 91. 77-79 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Hiramoto: "Photocarrent Multiplication Phenomena at Organic/Metal and Organic/Organic Interfaces"Thin Solid Films. 331. 71-75 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Hiramoto: "Photo current Multiplication at Organic/Metal Interface and Morphology of Metal Films"Japanese Journal of Applied Physics. 37. L1184-L1186 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Hiramoto: "Field-activated Structural Traps at Organic Pigment/Metal Interfaces cousing photocurrent Maltiplication Phenomena"Applied Physics Letters. 73. 2627-2629 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Nakayama: "Direct Tracing of the Photocurrent Multiplication Process in an Organic Pigment Films"Journal of Applied Physics. 84. 6154-6156 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Nakayama: "Photocurrent Multiplication at Organic/Metal Interface and Sorface Morphology of Organic Films"Journal of Applied Physics. (in press). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. Hiramoto, H. Kumaoka, and M. Yokoyama: "Photocurrent Multiplication Phenomenon at Organic/Organic Heterojunction and Application to Optical Computing Device Combining with Organic EL"Synthetic Metals. 91. 77-79 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. Hiramoto, K. Nakayama, I. Sato, H. Kumaoka, and M. Yokoyama: "Photocurrent Multiplication Phenomena at Organic/Metal and Organic/Organic Interface"Thin Solid Films. 331. 71-75 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. Hiramoto, I. Sato, K. Nakayama, and M. Yokoyama: "Photocurrent Multiplication at Organic/Metal Interface and Morphology of Metal Films"Japanese Journal of Applied Physics. 37. L1184-L1186 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M. Hiramoto, K. Nakayama, T. Katsume, and M. Yokoyama: "Field-activated Structural Traps at Organic Pigment/Metal Interfaces Causing Photocurrent Multiplication Phenomena"Applied Physics Letters. 73. 2627-2629 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Nakayama, M. Hiramoto, and M. Yokoyama: "Direct Tracing of the Photocurrent multiplication Process in an Organic Pigment Film"Journal of Applied Physics. 84. 6154-6156 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Nakayama, M. Hiramoto, and M. Yokoyama: "Photocurrent multiplication at organic/metal interface and surface morphology of organic films"Journal of Applied Physics. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Hiramoto: "Photocurrent Multiplication Phenomena at Organic/Metal and Organic/Organic Interfaces" Thin Solid Films. 331. 71-75 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Hiramoto: "Photocurrent Multiplication at Organic/Metal Interface and Morphology of Metal Films" Japaneses Journal of Applied Physics. 37. L1184-L1186 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Nakayama: "Transient Response of Multiplied Photocurrent observed in Metal/Organic Pigment Film Interface" Proceedings of IS&T's NIP14. 490-493 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Hiramoto: "Field-activated Structural Traps at Organic Pigment/Metal Interfaces Causing Photocurrent Multiplication Phenomena" Applied Physics Letters. 73. 2627-2629 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Nakayama: "Direct Tracing of Photocurrent Multiplication Process in Organic Pigment Film" Journal of Applied Physics. 84. 6154-6156 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Hiramoto: "Photocurreut Multiplication Phenomenon at Organic/Organic Heterojunction and Application to Optical Computing Device Combining with Organic Electroluminescence" Synthetic Metals. 91. 77-79 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Hiramoto: "Photocurrent Multiplication Phenomenon at Organic/Organic Heterojunction" Proceedings of IS&T's NIP13. 248-251 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Hiramoto: "Photocurrent Multiplication Phenomenon at Organic/Metal and Organic/Organic Interfaces" Thin Solid Films. (in press). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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