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Mechanisms of Ultra-low NOx and High Efficiency De-SOx in CO_2 Recycled Coal Combustion

Research Project

Project/Area Number 09450089
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

OKAZAKI Ken  Tokyo Institute of Technology Department of Mechanical Engineering and Science, Professor, 工学部, 教授 (20124729)

Co-Investigator(Kenkyū-buntansha) OGAWA Kuniyasu  Tokyo Institute of Technology Department of Mechanical Engineering and Science,, 工学部, 助手 (50272703)
HIRAI Shuichiro  Tokyo Institute of Technology Research Center for Carbon Recycling and Utilizati, 炭素循環素材研究センター, 教授 (10173204)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥9,900,000 (Direct Cost: ¥9,900,000)
Fiscal Year 1998: ¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1997: ¥6,700,000 (Direct Cost: ¥6,700,000)
KeywordsCoal Combustion / Global Environment / Carbon Deoxide / NOx / Low NOx Combustion / In-Furnace Desulfurization / CO_2 Recycling / 低NO_x燃焼
Research Abstract

CO_2 recycled coal combustion is promising because of its easy CO_2 recovery, extremely low NOx emission and high in-furnace desulfurization efficiency. The feasibility of simultaneous CO_2/NOx/SOx reduction in CO_2 recycled coal combustion was studied in order to develop a novel environmentally favorable coal combustion technology.
It was identified through experiments that the amount of NOx exhausted from the system is reduced to less than about one fourth of that exhausted with conventional air combustion. The contributions to the total NO decrease from coal combustion with air caused by the use of recycled CO_2 are as follows : 1. The effect of an increase of CO_2 concentration in the furnace is not significant below 10%. 2. The effect of interaction between fuel-N and recycled NO is 10-50 %. 3. The effect of a reduction of recycled NO in the furnace is dominant and amounts to 50-80%. Theoretical simulation also confirmed the validity of this result. The characteristics and mechanism of desulfurization were clarified through experiment and modeling. The desulfurization efficiency in CO_2 recycled coal combustion is about three times as high as that with coal combustion in air and does not suffer so much from CaSO_4 decomposition. The high desulfurization efficiency is mainly attributed to : 1. high concentration of SO_2 inside furnace owing to the recirculation of gases ; 2. decrease in CaSO_4 decomposition resulted from high SO_2 concentration. CO_2 recycled coal combustion was identified to be a promising system with which simultaneous reduction of CO_2/NOx/SOx can be realized.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (14 results)

All Other

All Publications (14 results)

  • [Publications] Bo Feng: "NO Destruction and Regeneration in Co_2 Enriched CH_4 Flame (A Fundamental Study on Co_2 Recycled Coal Combustion)" JSME International Journal, Series B. 41・3. 959-965 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 金子宇内: "O_2/CO_2微粉炭燃焼におけるNOx,SOxの同時大幅低減" 第36回燃焼シンポジウム論文集. 146-148 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Liu Hao: "O_2/CO_2石炭燃焼における高濃度CO_2雰囲気下での脱硫挙動" 第36回燃焼シンポジウム論文集. 752-754 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Hao Liu: "Sulfation Behavior under High CO_2 Concentration in O_2/CO_2 Coal Combustion" Fuel. 発表予定. (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Bo Feng, T.Ando, K.Okazaki: "NO Destruction and Regeneration in CO_2 Enriched CH_4 Flame (A Fundamental Study on CO_2 Recycled Coal Combustion)" JSME International Journal, Series B. Vol.41, No.3. 959-965 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] U.Kaneko, Hao Liu, S.Katagiri, K.Okazaki: "Efficient Simultaneous Removal of NOx and SOx in CO_2/O_2 Coal Combustion (in Japanese)" Proceedings of Combustion Symposium in Japan. 146-148 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Hao Liu, S.Katagiri, U.Kaneko, K.Okazaki: "Desulfurization Behavior under High CO_2 Concentration in CO_2/O_2 Coal Combustion (in Japanese)" Proceedings of Combustion Symposium in Japan. 752-754 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Hao Liu, S.Katagiri, U.Kaneko, K.Okazaki: "Sulfation Behavior under High CO_2 Concentration in O_2/CO_2 Coal Combustion" Fuel. (submitted). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Bo Feng,T.Ando,K.Okazaki: "NO Destruction and Regeneration in CO_2 Enriched CH_4 Flame(A Fundamental Study on CO_2 Recycled Coal Combustion)" JSME Intemational Journal,Series B. 41・3. 959-965 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 金子宇内,Liu Hao,片桐史郎,岡崎 健: "O_2/CO_2微粉炭燃焼におけるNOx,SOxの同時大幅低減" 第36回燃焼シンポジウム論文集. 146-148 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Liu Hao,片桐史郎,金子宇内,岡崎 健: "O_2/CO_2石炭燃焼における高濃度CO_2雰囲気下での脱硫挙動" 第36回燃焼シンポジウム論文集. 752-754 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hao Liu,S.Katagiri,U.Kaneko,K.Okazaki: "Sulfation Behavior under High CO_2 Concentration in O_2/CO_2 Coal Combustion" Fuel. (発売予定). (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Okazaki, T.Ando: "NOx Reduction Mechanism in Coal Combustion with Recycled CO_2" Energy,The International Journal. 22・2/3. 207-215 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 岡崎 健: "燃焼生成物の発生と抑制技術(分担:NOx発生機構)" テクノシステム, 600 (1977)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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