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Unequilibrium Effect in Reaction Diffusion Couples with Very Different Diffusional Properties

Research Project

Project/Area Number 09450230
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

IIJIMA Yoshiaki  Graduate School of Engineering, Tohoku University, Professor, 大学院・工学研究科, 教授 (70005411)

Co-Investigator(Kenkyū-buntansha) FUJIKAWA Shin-itiroh  Graduate School of Engineering, Tohoku University, Research Associate, 大学院・工学研究科, 助手 (50005344)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥7,300,000 (Direct Cost: ¥7,300,000)
Fiscal Year 1999: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1998: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1997: ¥5,800,000 (Direct Cost: ¥5,800,000)
KeywordsKirkendall effect / Darken's relation / interdiffusion / interface between different phases / intrinsic diffusion / Au-Fe / Au-Ni / tracer diffusion / 非平衡空孔 / カ-ケンドール効果 / ダ-ケンの関係式 / マルチプルマーカー法 / 多相拡散 / 自己拡散
Research Abstract

Interdiffusion behavior and Kirkendall effect in a binary single-phase couple have been sufficiently connected by Darken's relations. However, in some cases the values of interdiffusion coefficients determined with a multiple-phase couple are found to be smaller than those determined with a single-phase couple. These results contradict the conventional theory of interdiffusion. To elucidate the interdiffusion behavior in binary multi-phase couples, experiments on interdiffusion, intrinsic diffusion and tracer diffusion in Au-Fe and Au-Ni systems which consist of metals with very different diffusional properties were performed. The experimental results are summarized as follows :
(1) The value of interdiffusion coefficient in the Au/γ-Fe multi-phase couple was compared with that in the Au/α-Fe multi-phase couple. It was found that Darken's relation did not apply to the Au/γ-Fe multi-phase couple.
(2) The values of intrinsic diffusion coefficients in the Au/γ-Fe multi-phase couple were com … More pared with those in the Au/α-Fe multi-phase couple. It was found that the vacancy flux from the γ-Fe phase towards the Au-rich phase was insufficient to balance in the atom fluxes, resulting in the retardation of the interdiffusion in the Au/γ-Fe couple.
(3) The self-diffusion coefficients of Au and Fe in gold-iron alloys (0 to 36at%Fe) were determined. The values of the interdiffusion coefficients experimentally determined with the Au/γ-Fe couple were smaller than those calculated by Darken's relation using the values of the self-diffusion coefficients and the thermodynamic factor in the whole composition in the Au-rich alloys.
(4) Darken's relation does not apply to the Au-Ni single-phase couple which consists of metals with very different diffusional properties.
Consequently, it is found that Darken's relation in which it is assumed that the equilibrium concentration of vacancies would be maintained does not apply to the diffusion couple which consists of metals with very different diffusional properties. Less

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] Y.Iijima: "Shift of Multiple Markers and Intrinsic Diffusion in Gold-Iron Alloys"Phil.Mag.Lett.. 74. 423-428 (1996)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Iijima: "Interdiffusion and Multiple Markers Shift in Au-Fe Alloys"Defect and Diffusion Forum. 143-147. 499-504 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Yamazaki: "Interdiffusion coefficients in Fe/Au-Fe diffusion couples"The Eighteenth Japan Symposium on Thermophysical Properties. 18. 193-196 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Sugiyama: "Interdiffusion and Kirkendall effect in Au/Ni diffusion couples"The Nineteenth Japan Symposium on Thermophysical Properties. 19. 175-178 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Yamazaki: "Deviation from Darken's Relation in Au/Fe Diffusion Couples"Proceedings of the International Conference on Solid-Solid Phase Transformations'99(JIMIC-3). 493-496 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Sugiyama: "Interdiffusion in Au/Ni Diffusion Couples"Proceedings of the International Conference on Solid-Solid Phase Transformations'99(JIMIC-3). 513-516 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Iijima: "Shift of Multiple Markers and Intrinsic Diffusion in Gold-Iron Alloys"Phil. Mag. Lett.. 74. 423-428 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Iijima: "Interdiffusion and Multiple Markers Shift in Au-Fe Alloys"Defect and Diffusion Forum. 143-147. 499-504 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yamazaki: "Interdiffusion coefficients in Fe/Au-Fe diffusion couples"Japan Symposium on Thermophysical Properties. 18. 193-196 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Sugiyama: "Interdiffusion and Kirkendall effect in Au/Ni diffusion couples"Japan Symposium on Thermophysical Properties. 19. 175-178 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Yamazaki: "Deviation from Darken's Relation in Au/Fe Diffusion Couples"Proceedings of the International Conference on Solid-Solid Phase Transformations '99(JIMIC-3). 493-496 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Sugiyama: "Interdiffusion in Au/Ni Diffusion Couples"Proceedings of the International Conference on Solid-Solid Phase Transformations '99(JIMIC-3). 513-516 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Iijima: "Shift of Multiple Markers and Intrinsic Diffusion in Gold-Iron Alloys"Phil. Mag. Lett.. 74. 423-428 (1996)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Iijima: "Interdiffusion and Multiple Markers Shift in Au-Fe Alloys"Defect and Diffusion Forum. 143-147. 499-504 (1997)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Yamazaki: "Interdiffusion coefficients in Fe/Au-Fe diffusion couples"The Eighteenth Japan Symposium on Thermophysical Properties. 18. 193-196 (1997)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Sugiyama: "Interdiffusion and kirkendall effect in Au/Ni diffusion couples"The Nineteenth Japan Symposium on Thermophysical Properties. 19. 175-178 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Yamazaki: "Deviation from Darken's Relation in Au/Fe Diffusion Couples"Proceedings of the International Conference on Solid-Solid Phase Transformations '99 (JIMIC-3). 493-496 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Sugiyama: "Interdiffusion in Au/Ni Diffusion Couples"Proceedings of the International Conference on Solid-Solid Phase Transformations '99 (JIMIC-3). 513-516 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Iijima: "Shift of Multiple Markers and Intrinsic Diffusion in Gold-Iron Alloys" Phil.Mag.Lett.74. 423-428 (1996)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Iijima: "Interdiffusion and Multiple Markers Shift in Au-Fe Alloys" Defect and Diffusion Forum. 143-147. 499-504 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Yamazaki: "Interdiffusion coefficients in Fe/Au-Fe diffusion couples" The Eighteenth Japan Symposium on Thermophysical Properties. 18. 193-196 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Sugiyama: "Interdiffusion and kirkendall effect in Au/Ni diffusion couples" The Nineteenth Japan Symposium on Thermophysical Properties. 19. 175-178 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 飯島嘉明: "Interdiffusion and Multiple Markers Shift in Au-Fe Alloys" Defect and Diffusion Forum. 143-147. 499-504 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山崎仁丈: "Fe/Au-Fe拡散対における相互拡散係数" 第18回日本熱物性シンポジウム講演論文集. 193-196 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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