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Design and development of compact, high-performance NOx sensors for preservation of environment

Research Project

Project/Area Number 09450320
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業物理化学
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

MIURA Norio  Kyushu Univ., Adv. Sci. & Tec. Center for Cooperative Research, Professor, 先端科学技術共同研究センター, 教授 (70128099)

Co-Investigator(Kenkyū-buntansha) SAKAI Go  Kyushu Univ., Graduate School of Engineering Science, Research Associate, 大学院・総合理工学研究科, 助手 (40284567)
SHIMANOE Kengou  Kyushu Univ., Graduate School of Engineering Science, Associate Professor, 大学院・総合理工学研究科, 助教授 (10274531)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥14,200,000 (Direct Cost: ¥14,200,000)
Fiscal Year 1999: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1998: ¥4,700,000 (Direct Cost: ¥4,700,000)
Fiscal Year 1997: ¥7,700,000 (Direct Cost: ¥7,700,000)
KeywordsNOx sensor / Preservation of environment / Solid electrolyte / Stabilized zirconia / NASICON / Oxide Semiconductor / Amperometric detection / Mixed potential / NOxセンサ / 団体電解質 / 酸化ビスマス / スピネル型酸化物 / 電線検出方式 / 安定性ジルコニア / スピネル酸化物 / 限界電流
Research Abstract

The purpose of the present study is the development of new type high-performance NOx sensors with the aim of preservation of environment. Four types of solid-state NOx sensors based on ionic conductors or oxide semiconductors were proposed here and their sensing properties were examined. (1) The stabilized zirconia-based electrochemical devices using the oxide sensing electrodes were tested for NOx sensing properties at high temperature. Among the many metal oxides examined, CdCr2O4 or WO3 was found to give the best sensing properties to NO and NO2 at 500-700℃. The EMF response of the device was linear to the logarithm of NOx concentration. (2) The stabilized zirconia-based devices using oxide electrode for selective amperometric detection of NO at high temperature. The CdCr2O4-attached tubular device showed quick and selective response to NO over NO2 at 500 and 550℃, if the potential of sensing electrode was polarized properly at + 100 mV vs. the reference Pt electrode. The 90% respon … More se time of the divide to 100 ppm NO was as short as ca. 20 s at 500℃. The current response was well correlated to the NO concentration in the range of 0 - 200 ppm. (3) A new solid-state amperometric sensor for NO2 was fabricated by combining an NaィイD1+ィエD1 conductor (NASICON) based device with an NaNO2 layer deposited on the counter electrode. With the sensing electrode polarized at - 150 mV relative to the reference Au electrode at 150℃, the electric current flowing through the device under exposure to NO2 was linear to the NO2 concentration in the range from 10 ppb to 1 ppm. (4) A search for semiconducting oxides was carried out to design a sensor selective to NO over NO2. Bi2O3 was very selective to NO through not very sensitive among the various oxides examined, and NiO was proved to be the most effective promoter to Bi2O3 for enhancing NO sensitivity. The sensor element using 5wt%NiO-Bi2O3 showed fairly good sensing properties to NO in the range of 0 - 400 ppm in sensitivity, selectivity over NO2, and response rate, at 300℃. Less

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (64 results)

All Other

All Publications (64 results)

  • [Publications] N. MIURA: "Compact Amperometeric Solid Electrolyte Sensor for Detection of NO_< 2> in ppb Range"Proc. of Transducer's 97. 2. 951-954 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. Lu: "High-Temperature Sensors for NO and NO2 Based on Stablized Zirconia and Sponel-Type Oxide Electrodes."J. Mater. Chem.. 7(8). 1445-1449 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "Solid-State Amperometric No Sensor Based on Stabilized Zirconia and Oxide Electrode"Proc. 11th Int. Conf. on Solid State Ionics. 150-151 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "A Compact Amperometric NO2 Sensor on Na^< +> Conductive Solid Electrolyte"J. Appl. Electrochem. 28(9). 863-865 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] X. WANG: "Spin-coated Thin Films of SiO_< 2I>-WO_< 3I> Composaites for Detection of Sub-ppm NO2"Sensors & Actuators B.. 45. 141-143 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N, MIURA: "Solid-State Amperometric NO Sensor Based on Stabilized Zirconia and Oxide Electrode"Tech. Digest. Of The 16th Sensor Symp.. 147-152 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N, MIURA: "High-temperature Potentiometric/Amperometric Nox Sensor Combling Stabilized Zirconia with Mixed-Metal Oxide Electrode"Sensors and Actuators B. 52巻. 169-178 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. LU: "High Temperature Amperometric NO Sensor Based on Stabilized Zirconia and CdCr_< 2>O_< 4> Electrode"J. Appl. Electrochem.. 28・9. 1009-1022 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "A Compact Solid-State Amperometric Sensor for Detection of NO_< 2> in ppb Range"Sensors and Actuators B. 49巻. 578-583 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 酒井剛: "酸化ビスマスを用いた半導体NOセンサ"電気学会論文誌E,. 118・12. 578-583 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "Selective Detection of NO by Using Amperometric Sensor Based on Stabilized Zirconia and Oxide Electrode"Solid State Ionics. 117. 283-290 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. LU: "High-Temperature NO_< 2> Sensor Using Stabilized Zirconia and Tungsten Oxide Electrode"Ionics. 4巻. 16-24 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "Selective Detection of NO by Using Amperometric Sensor Based on Stabilized Zirconia and Oxide Electrode"Solid State Ionics. 117. 283-290 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "Solid-State Amperometric Nox Sensor Using Proton Conductor Operative at Ordinary Temperature"2nd Int. MeetPacific Rim Ceramic Soc.. 2. 44-50 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. YAMAZOE: "Gas Sensors Using Solid Electrolytes"MRS Bulletin. 24. 37-43 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. S. KWAK: "Nox Sensing Properties of Ba_< 2> O_< 5> Element at Elevated Temperature"Sensors and Actuators B. 56. 59-64 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "Approach to High-Performance Electrochemical NOX Sensors Based on Solid Electrolytes"Sensor Update. 6. 191-210 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. MIURA: "Progress in Mixed-Potential Type Devices Based on Solid Electrolyte for Sensing Redox Gases"Solid State Ionics. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, M. Ono, K.Shimanoe, N. Yamazoe: "Compact Amperometric Solid-Electrolyte Sensor for Detection of NO2 in ppb Range"Proc. of Transducer' s 97, Chicago. 2. 951-954 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. Lu, N. Miura, N. Yamazoe: "High-Temperature Sensors for NO and NO2 Based on Stabilized Zirconia and Spinel-Type Oxide Electrodes"J. Mater. Chem.. 7(8). 1445-1449 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] X. Wang, G. Sakai, N. Miura, N. Yamazoe: "Sub-ppm NO2 Sensing Characteristics of WO3 Thin Film Prepared by Sol-Gel Method"Japanese Sensor Newsletter. 11(2). 1-7 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. Lu, N. Miura, N. Yamazoe: "Stabilized Zirconia-Based NOx Sensor Using Spinel-Type Oxide for Sensing Electrode"Proc. of Eurosensors XI. 379-382 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, G. Lu, N. Yamazoe: "Solid-State Amperometric NO Sensor Based on Stabilized Zirconia and Oxide Electrode"11th International Conference on Solid State Ionics, Honolulu. 150-151 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Yamazoe, M. Ono, K.Shimanoe, N. Miura: "Approach to Amperometric Sensor for Nitrogen Oxides"Proc. of The Third Korea-Japan Joint Seminar on Electrochemistry. 179-187 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] X. Wang, G. Sakai, K. Shimanoe, N. Miura, N. Yamazoe: "Spin-Coated Thin Films of SiO2-WO3 Composites for Detection of sub-ppm NO2"Sensors and Actuators B. 45. 141-143 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, M. Ono, K.Shimanoe, N. Yamazoe: "A Compact Solid-State Amperometric Sensor for Detection of NO2 in ppb Range"Sensors and Actuators B. 49. 101-109 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, G. Lu, N. Yamazoe: "Solid-State Amperometric NO Sensor Based on Stabilized Zirconia and Oxide Electrode"Tech. Digest of The 16th Sensor Symp.. 147-152 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] W. Xusheng, N. Miura, N. Yamazoe: "Study of WO3-based Sensing Materials for NH3 and NO Detection"Tech. Digest of 7-IMCS. 50-52 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. Lu, N. Miura, N. Yamazoe: "Stabilized Zirconia-Based Electrochemical Sensors Attached with Oxide Electrode for Detection of NO or NO2"Tech. Digest of 7-IMCS. 112-114 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, M. Ono, G. Lu, N. Yamazoe: "Design of Compact Amperometric NO2 Sensor Based on NaィイD1+ィエD1 Conductive Solid Electrolyte"J. Appl. Electrochem.. 28(9). 863-865 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, G. Lu, N. Yamazoe: "High-Temperature Potentiometric/Amperometric NOx Sensors Combining Stabilized Zirconia with Mixed-Metal Oxide Electrode"Sensors and Actuators B. 52. 169-178 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. Lu, N. Miura, N. Yamazoe: "High-Temperature Amperometric NO Sensor Based on Stabilized Zirconia CdCr2O4 Electrode"J. Appl. Electrochem.. 28(9). 1009-1011 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura: "Development of High-Performance NOx Sensor Based on Solid Electrolytes"Poc. of the 9th Conf. On Sensor Tech.. 13-18 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] G. Lu, N. Miura, N. Yamazoe: "High-Temperature NO or NO2 Sensor Using Stabilized Zirconia and Tungsten Oxide Electrode"Ionics. 4(1/2). 16-24 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, G. Lu, M. Ono, N. Yamazoe: "Selective Detection of NO by Using Amperometric Sensor Based on Stabilized Zirconia and Oxide Electrode"Solid State Ionics. 117. 1-8 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Yamazoe, N. Miura: "Potenometric Gas Sensors for Oxide Gases"J. Electroceramics. 2(4). 243-255 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, G. Lu, M. Ono, N. Yamazoe: "Selective Detection of NO by Using Amperometric Sensor Based on Stabilized Zirconia and Oxide Electrode"Solid State Ionics. 117. 283-290 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, T. Harada, T. Raisen, N. Yamazoe: "Solid-State Amperometric NOx Sensor Using Proton Conductor Operative at Ordinary Temperature"The Second International Meeting of Pacific Rim Ceramic Societies. 2. 44-50 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Yamazoe, N. Miura: "Solid State Gas Sensor Design Using Foreign Receptors"Electrochemistry. 67(3). 224-231 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Yamazoe, K. Shimanoe, S. Yao, N. Miura: "Exploration of Auxiliary Phase Materials for High-Sensitivity Solid Electrolyte NO2 Sensor"Electrochemical Society Proceedings. Vol. 99-13. 335-341 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] W. Y. Chung, J. W. Lim, D. D. Lee, N. Miura, N. Yamazoe: "A New Planar-Type Micro Gas Sensor"Proc. of Transducers '99. Vol. 1. 672-675 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Yamazoe, N. Miura: "Gas Sensors Using Solid Electrolytes"MRS Bulletin. 26(6). 37-43 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. S. Kwak, J. S. Hwang, C. O. Park, N. Miura, N. Yamazoe: "NOx Sensing Properties of Ba2WO5 Element at Elevated Temperature"Sensors and Actuators B. 56. 59-64 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] W. Y. Chung, Y. S. Lee, J. W. Lim, D. D. Lee, N. Miura, N. Yamazoe: "NO2 Sensing Properties of WO3 Film Prepared by Hydrothermal Method and Dip Coating"Poc, of 4th East Asian Conf. On Chemical Sensors. 77-80 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, N. Yamazoe: "Approach to High-Performance Electrochemical NOx Sensors Based on Solid Electrolytes"Sensors Update. 6. 191-210 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Miura, G. Lu, N. Yamazoe: "Progress in Mixed-Potential Type Devices Based on Solid Electrolyte for Sensing Redox Gases"Solid State Ionics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.MUURA: "Selective Detection of NO by Using Amperometri Sensor Based on Stabilized Zirconia and Oxide Electrode"Solid State Ionics. 117. 283-290 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N.MUURA: "Solid-Satae Amperometric NOx Sensor Using Proton Conductor Operative at Ordinary Temperature"2nd Int,Meet,Pacific Rim Ceramic Soc,. 2. 44-50 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N.MUURA: "Gas Sensors Using Solid Electrolytes"MRS Bulletin. 24. 37-43 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.S.KWAK: "NOx Sensing Properties of Ba2WO5 Element at Elebated Temperature"Sensors and Actuators B. 56. 59-64 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N,MIURA: "Approach to High-Preformance Electrochemical Nox Sensors Based on Solid Electrolytes"Sensors Update. 6. 191-210 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] N,MIURA: "Progress in Mixed-Potential Type Devices Based on Solid Electrolyte for Sensing Rodox Gases"Solid State Ionics. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] M.MIURA: "High-temperature Potentiometric/Amperometric NOx Sensors Combining Stabilized Zircoma with Mixed-Metal Oxide Electrobe" Sensors and A ctuators B. 52巻. 169-178 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] G.LU: "High Temperature Amperometric NO Sensor Based on Stabilized Zircomia and CdCr_2O_4 Electrobe" J.Appl.Electrochem.28・9. 1009-1011 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.MIURA: "A Compact Solid-State Amperometric Sensor for Detection of NO_2 in ppb Range" Sensors and Actuators B. 49巻. 101-109 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 酒井,剛: "酸化ビスマスを用いた半導体NOセンサ" 電気学会論文誌E. 118・12. 578-583 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.MIURA: "Selective Detection of NO by Using Amperometric Sensor Based on Stabilized Zirconea and Oxide Electrode" Solid Stare Ionics. 117. 283-290 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] G.LU: "High-Temperature NO_2 Sensor Using Stabilized Zerconea and Tungsten Oxide Electrode" Ionics. 4巻. 16-24 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.MIURA: "Compact Amperometric Solid Electrolyte Sensor for Detection of NO2 in ppb Range" Proc.of Transducer's 97. 2. 951-954 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] G.Lu: "Stabilized Zirconia-Based NOx Sensor Using Spinel-Type Oxide for Sensing Electrode" Proc.of Eurosensors X1. 379-382 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.MIURA: "Solid-State Amperometric NO Sensor Based on Stabilized Zirconia and Oxide Electrode" Proc.11th Int.Conf.on Solid State Ionics. 150-151 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.MIURA: "A Compact Amperometric NO2 Sensor Based on Na^+ Conductive Solid Electrolyte" J.Appl.Electrochem.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] X.WANG: "Spin-coated Thin Films of SiO2-WO3 Composaites for Detection of Sub-ppm NO2" Sensors & Actuators B.(in press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.MIURA: "A Compact Solid State Amperometric Sensor for Detection of NO2 in ppb Range" Sensors & Actuators B.(in press). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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