| Project/Area Number |
09450320
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
工業物理化学
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| Research Institution | KYUSHU UNIVERSITY |
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Principal Investigator |
MIURA Norio Kyushu Univ., Adv. Sci. & Tec. Center for Cooperative Research, Professor, 先端科学技術共同研究センター, 教授 (70128099)
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| Co-Investigator(Kenkyū-buntansha) |
SAKAI Go Kyushu Univ., Graduate School of Engineering Science, Research Associate, 大学院・総合理工学研究科, 助手 (40284567)
SHIMANOE Kengou Kyushu Univ., Graduate School of Engineering Science, Associate Professor, 大学院・総合理工学研究科, 助教授 (10274531)
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| Project Period (FY) |
1997 – 1999
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| Project Status |
Completed (Fiscal Year 1999)
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| Budget Amount *help |
¥14,200,000 (Direct Cost: ¥14,200,000)
Fiscal Year 1999: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1998: ¥4,700,000 (Direct Cost: ¥4,700,000)
Fiscal Year 1997: ¥7,700,000 (Direct Cost: ¥7,700,000)
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| Keywords | NOx sensor / Preservation of environment / Solid electrolyte / Stabilized zirconia / NASICON / Oxide Semiconductor / Amperometric detection / Mixed potential / NOxセンサ / 団体電解質 / 酸化ビスマス / スピネル型酸化物 / 電線検出方式 / 安定性ジルコニア / スピネル酸化物 / 限界電流 |
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| Research Abstract |
The purpose of the present study is the development of new type high-performance NOx sensors with the aim of preservation of environment. Four types of solid-state NOx sensors based on ionic conductors or oxide semiconductors were proposed here and their sensing properties were examined. (1) The stabilized zirconia-based electrochemical devices using the oxide sensing electrodes were tested for NOx sensing properties at high temperature. Among the many metal oxides examined, CdCr2O4 or WO3 was found to give the best sensing properties to NO and NO2 at 500-700℃. The EMF response of the device was linear to the logarithm of NOx concentration. (2) The stabilized zirconia-based devices using oxide electrode for selective amperometric detection of NO at high temperature. The CdCr2O4-attached tubular device showed quick and selective response to NO over NO2 at 500 and 550℃, if the potential of sensing electrode was polarized properly at + 100 mV vs. the reference Pt electrode. The 90% respon
… More
se time of the divide to 100 ppm NO was as short as ca. 20 s at 500℃. The current response was well correlated to the NO concentration in the range of 0 - 200 ppm. (3) A new solid-state amperometric sensor for NO2 was fabricated by combining an NaィイD1+ィエD1 conductor (NASICON) based device with an NaNO2 layer deposited on the counter electrode. With the sensing electrode polarized at - 150 mV relative to the reference Au electrode at 150℃, the electric current flowing through the device under exposure to NO2 was linear to the NO2 concentration in the range from 10 ppb to 1 ppm. (4) A search for semiconducting oxides was carried out to design a sensor selective to NO over NO2. Bi2O3 was very selective to NO through not very sensitive among the various oxides examined, and NiO was proved to be the most effective promoter to Bi2O3 for enhancing NO sensitivity. The sensor element using 5wt%NiO-Bi2O3 showed fairly good sensing properties to NO in the range of 0 - 400 ppm in sensitivity, selectivity over NO2, and response rate, at 300℃. Less
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