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SYNTHETIC OBSERVATIONAL STUDY ON OH AND OTHER REACTIVE TRACE GASES TO TEST THE THEORY OF ATMOSPHERIC PHOTOCHEMISTRY

Research Project

Project/Area Number 09480115
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental dynamic analysis
Research InstitutionTHE UNIVERSITY OF TOKYO

Principal Investigator

KAJII Yoshizumi  RCAST, THE UNIV. OF TOKYO, ASSOCIATE, 先端科学技術研究センター, 助教授 (40211156)

Co-Investigator(Kenkyū-buntansha) BANDOW Hiroshi  OSAKA-PREFECT. UNIV. PROFESSOR, 工学部, 教授 (80124353)
HIROKAWA Jun  RCAST, THE UNIV. OF TOKYO, RES. ASSOCIATE, 先端科学技術研究センター, 助手 (20262115)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 1999: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1998: ¥1,800,000 (Direct Cost: ¥1,800,000)
Fiscal Year 1997: ¥11,100,000 (Direct Cost: ¥11,100,000)
KeywordsOH RADICAL / HOィイD22ィエD2 RADIAL / NOx / ISOPRENE / SOLAR ULTRA-VIOLET / OZONE PRODUCTION / NOx / ボックスモデル計算 / 光化学オゾン生成 / HO2ラジカル / NOX / 反応性炭化水素 / RO2ラジカル / レーザー誘起蛍光 / 光分解 / 多重反射系 / 波長可変色素パルスレーザー / 非メタン炭化水素 / 大気光化学反応理論
Research Abstract

DEVELOPMENT OF INSTRUMENT TO MEASURE THE CONCENTRATION OF HOX RADICALS IN AMBIENT AIR BY USING LASER INDUCED FLUORESCENCE TECHNIQUE WAS PERFORMED. TO GET ADVANCED KNOWLEDGE OF ATMOSPHERIC CHEMISTRY SYNTHETIC OBSERVATIONAL STUDIES OF OH AND OTHER REACTIVE TRACE GASES IN REMOTE ATMOSPHERE WERE CARRIED OUT IN 1998 AT OKI ISLAND AND IN 1999 AT OKINAWA ISLAND. IN OKI OBSERVATION WE FOUND NEW HOX RADICAL SOURCE IN NIGHTTIME AS OZONOLYSIS REACTION WITH BIOGENIC OLEFINS. IN OKINAWA WE SUCCEEDED TO MEASURE OH RADICAL AND AVERAGE CONCENTRATION IN NOON TIME WAS DETERMINED TO BE CA. 3 X 10ィイD16ィエD1 RADICALS CMィイD1-3ィエD1. OZONE PRODUCTION POTENTIAL IS FOUND To BE QUITE HIGH EVEN IN THE CLEAN REMOTE ISLAND LIKE OKINAWA. THERE ARE CONSIDERABLE AMOUNTS OF OZONE PRECOURSORS LIKE BIOGENIC OLEFINS AND ALSO BIGENIC NOx. OZONE PRODUCITON RATE IN NOON TIME WAS ESTIMATED TO BE 4 PPPB DAYィイD1-1ィエD1.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (6 results)

All Other

All Publications (6 results)

  • [Publications] 金谷有剛、定永靖宗、松本淳、Sharma,U.廣川淳、梶井克純、秋元肇: "Nighttime observation of the HO_2 radical by an LIF instrument at Oki island Japan and its possible origins"Geophysical Research Letters. 26. 2179-2182 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 梶井克純、金谷有剛、定永靖宗、廣川淳、秋元肇: "Measurements of HO_X Radicals and Their Chemistry in the Troposphere""Recent Research Developments in Geoophysical Research II" Research Signpost(in press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] YUGO KANAYA, ET AL.: "NIGHTTIME OBSERVATION OF THE HOィイD22ィエD2 RADICAL BY AN LIF INSTRUMENT AT OKI ISLAND, JAPAN, AND ITS POSSIBLE ORIGINS"GEOPHYSICAL RESEARCH LET-TERS. 26. 2179-2182 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] YOSHIZUMI KAJII, ET AL.: "MEASUREMENTS OF HOX RADICALS AND THEIR CHEMISTRY IN THE TROPO-SPHERE"RECENT RESEARCH DEVELOP-MENTS IN GEOPHYSYCAL RE-SEARCH II, RESEARCH SIGN-POST, (IN PRESS). (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 金谷有剛、定永靖宗、松本淳、Sharma,U.廣川淳、梶井克純、秋元肇: "Nighttime observation of the HO_2 radical by an LIF instrument at Oki island, Japan, and its possible origins"Geophysical Research Letters. 26. 2179-2182 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 梶井克純、金谷有剛、定永靖宗、廣川淳、秋元肇: "Measurements of HOx Radicals and Their Chemistry in the Troposphere""Recent Research Developments in Geophysical Research II" Research Signpost(in Press). (2000)

    • Related Report
      1999 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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