| Project/Area Number |
09554031
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
Physical chemistry
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| Research Institution | Hokkaido University |
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Principal Investigator |
NAKAMURA Takayoshi Research Institute for Electronic Science, Hokkaido Univ., Pro., 電子科学研究所, 教授 (60270790)
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| Co-Investigator(Kenkyū-buntansha) |
KIGUCHI Masashi Advanced Research Laboratory, Hitachi, Ltd., Senior Researcher, 基礎研究所, 主任研究員
AKUTAGAWA Tomoyuki Research Institute for Electronic Science, Inst., 電子科学研究所, 助手 (60271631)
HASEGAWA Research Institute for Electronic Science, Asso.Pro., 電子科学研究所, 助教授 (00242016)
KAWAMATA Jun Research Institute for Electronic Science, Hokkaido Univ., Inst., 電子科学研究所, 助手 (40214689)
INOUE Kuon Research Institute for Electronic Science, Hokkaido Univ., Pro., 電子科学研究所, 教授 (30021934)
斎藤 軍治 京都大学理学研究科, 教授 (40132724)
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| Project Period (FY) |
1997 – 1998
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| Project Status |
Completed (Fiscal Year 1998)
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| Budget Amount *help |
¥12,200,000 (Direct Cost: ¥12,200,000)
Fiscal Year 1998: ¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 1997: ¥9,500,000 (Direct Cost: ¥9,500,000)
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| Keywords | the third optical non-linear effect / four wave mixing / evanescent wave / 電荷移動錯体 |
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| Research Abstract |
In this work, we developed the equipment based on FWMEW to determine the third optical non-linearity precisely of the powder samples having a large absorption band in the visible range. We measured the chi^<(3)> values of the powder or thin-film samples using this equipment and confirmed the effectiveness of the method. At present, due to the large reflection from the prism surface and the diffraction at the prism-sample interface, the application of FWMEW method is limited to the large chi^<(3)> samples such as VO-Pc or Pt-dimethylglyoxim. Although the THEW method has much higher sensitivity, the FWMEW method has the merit that the measurements under non-resonant conditions are easy. Now, we are improving the SIN on the measurements of FWMEW.
In the mean time, we developed the charge-trensfer-complex LB films having optical non-linearity. The preliminary studies on the second order effect by the field modulating spectroscopy were performed. The evaluation of the optical non-linearlity on the power samples of charge transfer compleses such as (TBA)(EtO-C[C(CN)_2]_2and (EtO-TCA) is also started.
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