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Development of New Photo-, Electric-, and Molecular-Devised Materials Using High Pressure Technology

Research Project

Project/Area Number 09554047
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 物質変換
Research InstitutionKochi University

Principal Investigator

KOTSUKI Hiyoshizo  Kochi University, Faculty of Science, Department of Chemistry, Professor, 理学部, 教授 (80093954)

Co-Investigator(Kenkyū-buntansha) SUENAGA Hitoshi  Teikoku Chemical Industries, Fine Chemicals Development, Chief Investigator, 化成品部門, 研究部長
GAMOH Keiji  Kochi University, Faculty of Education, Department of Chemistry, Associate Professor, 教育学部, 助教授 (90204817)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥12,100,000 (Direct Cost: ¥12,100,000)
Fiscal Year 1999: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1998: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1997: ¥6,100,000 (Direct Cost: ¥6,100,000)
KeywordsMichael Addition Reaction / Nitrogen Heterocycles / Quinazoline Derivatives / Silica Gel Supports / Natural Products Synthesis / Chiral Columns / Epoxide Opening Reaction / High Pressure Condensation / ホモ共役付加反応 / AI-77-B / キラルピリジン / キナゾリン / シリカゲル / キラルカラム / 高圧反応 / 脱Boc化反応 / 複素環化合物 / 還元的Boc化 / キナゾリン誘導率 / テンプレート / クロマト材料
Research Abstract

(a) Michael Addition Reactions of β-Ketoesters : Michael addition reactions of β-ketoesters with a variety of α, β-unsaturated carbonyl compounds using Yb(OTf)ィイD23ィエD2 / SiOィイD22ィエD2 or TfOH under solvent-free conditions have been established. In addition, homo-Michael addition reaction using activated cyclopropane derivatives has been achieved at high pressure.
(b) Asymmetric Catalysis Using Novel Nitrogen Heterocycles : Several chiral dipyridine and dithiophene derived ligands for the use in the catalytic enantioselective alkylation have been developed.
(c) Synthesis of Quinazoline Compounds : A variety of quinazoline derivatives have been prepared by condensation of cyano- and nitro-activated o-fluorobenzaldehydes with amidines in good yields.
(d) Supported Reactions on Silica Gel : Solvent-free organic reactions on silica gel supports have been developed: transformation of epoxides to halohydrins using LiX / SiOィイD22ィエD2 and chemoselective deprotection of N-Boc carboxamides using Yb(OTf)ィイD23ィエD2/ SiOィイD22ィエD2.
(e) Natural Product Synthesis : An enantioselective total synthesis of AI-77-B, a gastroprotective substance isolated from a culture broth of Bacillus pumilus AI-77, has been performed in high overall yield.
(f) Molecular Template Formation Using High Pressure Technique : Molecular template formation of bovine serum albumin-silica gels under high pressure conditions and its use for chiral HPLC analysis have been performed.
(g) Functional Group Transfonnations : Chemoselective reductive transformation of azides to N-Boc protected amines , Sc(OTf)ィイD23ィエD2- or TfOH-catalyzed Baeyer-Villiger oxidation and high-pressure-promoted LiClO)ィイD24ィエD2 -catalyzed reaction of epoxides with furans or thiophenes .

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (75 results)

All Other

All Publications (75 results)

  • [Publications] H.Kotsuki,他2名: "A Facil New Method for the Chemoselective Reductive Transformation of Azides to N-(test-Butoxycarboryl)amires"Tetrahedron Letters. 39. 2129-2132 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,K.Arimura: "Yb(OTf)_3-Catalyzed Michel Addition Roactions of β-Ketoestors on Silica Gel Supports and at Hish Pressure"Tetrahedron Letters. 38. 7583-7586 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Mtauoka,他5名: "Localization Blepharismin Photosensors and Identification of a Photoreceptor Complex Mediating the Step up Photopic spose of the...."Photochemistry of Photobiology. 65. 915-921 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Maeda,他6名: "Blepharsimin 1-5,Novel Photoreceptor from the Unicellular Organism Blepharisma japonicum"Tetrahedron Letters. 38. 7411-7414 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotuki,他2名: "Scandium(III) Trifluoromethanesultorate-Catalzed Friedel-Crabts Alkylasion of Aromatic Compounds with Secondary Alcohol Methaneselfonates"Synlett. 255-256 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Gomoh,H.Kotsuki: "Molecular Template Formation on Serun Albumin ender High Dressure Conditions"Chromatogrophy. 19. 100-101 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki: "Organic Synthesis at High Pressure Efficient Ring Opening Reaction of Epoxides with Heterocycles"Review of High Presure Science & Technology. 7. 1250-1252 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "Solvent Free Organic Reactions on Silica Ceel Supports Facihe Transformation of Epoxides to β-Halehydrins with Lithium Malides"Tetrahedron. 54. 2709-2722 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "A Facile New Method For Selective Deprofection of N-(test-butoxycarbonyl)-Protected Carboxamides with Yb(OTf)_3 on Slica Ceel"Tetrahedron Letters. 39. 4869-4870 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他4名: "Synthesis of Novel Chital Oligopyridine Derivative Ligands For the Enantioselective Addition of Diethylzine to Benzaldehyde"Tetrahedron:Asymmetry. 9. 3203-3212 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "A New Convenient Frieldel-Crabts Alkylation of Aromasic Compounds with Secndary Alcohol Methanesulterates in the Presence of Scandium(III)....."Synthesis. 603-606 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotuski,他3名: "Sc(OTf)_3-and Tfort-Catalyzed Baeyer-Velliger Oxidetion of Carbonyl Compounds with m-Chloroperbenzoic Acid"Synlett. 462-464 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "Trifluoromethanesulfenic Acid,an Unusually Powerful Catalyst for the Michael Addition Roaction of β Kieriesters under Solvont-Free Condetions"Journal of Organic Chemistry. 64. 3770-3773 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 小槻 日吉三: "キラルトリフラート法-光学活性天然物合成の新手法"有機合成化学協会誌. 57. 334-345 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "Ytherbium(III) Trifluoromethanesulforate-Catalyzed Homoconjugate Addition Reaction of βーKcetoesters with Activated Cyclopropane Dericatuvesat High Presure"Synlett. 650-652 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他4名: "A New Enantioselective Total Syntheais of AI-77-B"Organic Letters. 1. 499-502 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 蒲生啓司、坂田知栄子、小槻日吉三: "ODS-ショ糖エステルに固定化したリパーゼの有機溶媒中での酵素活性およびエナニチオ選択性"分析化学. 48. 1149-1155 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "A New Faule Method for the symthesis of 4-Dialkylasiropyridine Derivatied by High Pressure-Promoted Anirationa of 4-Chloropyridine"Synlett. 116-118 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kotsuki,他3名: "A Novel Synthesis of a Highly Sterically Hirdcered C_2-Symmetric Chiral Pyridine Derivative"Heterocycles. 52. 661-666 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsuoka,他5名: "Immunochemical Analysis of a Photoreceptor Protein Using Anti-IP3 Receptor Antibody in the Uniiicallular Organism,Blopharisma"Journal of Photo Chemistry & Phtobiology. (印刷中). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Hayashi,他編: "Asymmeric Synthesis:Graphical Abstracts and Experimental Methods"Kodansha. 396 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 松本澄、井畑敏一編: "超高圧有機合成"ナカニシヤ出版. 466 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "A New Facile Method for the Chemoselective Reductive Transformation of Azides to N- (tert-Butoxycarbonyl) amines"Tetrahedron Lett.. 38. 2129-2132 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "High-Pressure Organic Chemistry. Part 21. Yb(OTf)ィイD23ィエD2-Catalyzed Michael Addition Reactions of β-Ketoesters on Silica Gel Supports and at High Pressure"Tetrahedron Lett.. 38. 7583-7586 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Matsuoka: "Localization of Blepharismin Photosensors and Identification of a Photoreceptor Complex Mediating the Step-up Photophobic Response of the Unicellular Organism, Blepharisma"Photochem. Photobiol.. 65. 915-921 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Maeda: "Blepharismin 1-5, Novel Photoreceptor from the Unicellular Organism Blepharisma japonicum"Tetrahedron Lett.. 38. 7411-7414 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Scandium(III) Trifluoromethanesulfonate-Catalyzed Friedel-Crafts Alkylation of Aromatic Compounds with Secondary Alcohol Methanesulfonates"Synlett. 1998. 255-256

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Gamoh: "Molecular Template Formation on Serum Albumin under High Pressure Conditions"Chromatography. 19. 100-101 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Solvent-Free Organic Reactions on Silica Gel Supports. Facile Transformation of Epoxides to β-Halohydrins with Lithium Halides"Tetrahedron. 54. 2709-2722 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Organic Synthesis at High Pressure. Efficient Ring Opening Reaction of Epoxides with Heterocycles (Invited Review)"Rev. High Pressure Sci. Technol.. 7. 1250-1252 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "A Facile New Method for Selective Deprotection of N- (tert-Butoxycarbonyl) -Protected Carboxamides with Yb(OTf)ィイD23ィエD2 Supported on Silica Gel"Tetrahedron Lett.. 39. 4869-4870 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Synthesis of Novel Chiral Oligopyridine Derivative Ligands for the Enantioselective Addition of Diethylzinc to Benzaldehyde"Tetrahedron : Asymmetry. 9. 3203-3212 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "A New Convenient Friedel-Crafts Alkylation of Aromatic Compounds with Secondary Alcohol Methanesulfonates in the Presence of Scandium (III) Trifluoromethanesulfonate or Trifluoromethane-sulfonic Acid as the Catalyst"Synthesis. 1999. 603-606

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Sc(OTf)ィイD23ィエD2- and TfOH-Catalyzed Baeyer-Villiger Oxidation of Carbonyl Compounds with m-Chloroperbenzoic Acid"Synlett. 1999. 462-464

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Chiral Triflate Technology : An Efficient Tool for the Construction of Biologically Interesting Natural Products in Optically Pure Forms"Yuki Gosei Kagaku Kyokai-Shi. 57. 334-345 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "Trifluoromethanesulfonic Acid, an Unusually Powerful Catalyst for the Michael Addition Reaction of p-Ketoesters under Solvent-Free Conditions"J. Org. Chem.. 64. 3770-3773 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "High-Pressure Organic Chemistry. Part 22. Ytterbium (III) Trifluoromethanesulfonate-Catalyzed Homoconjugate Addition Reactions of β-Ketoesters with Activated Cyclopropane Derivatives at High Pressure"Synlett. 1999. 650-652

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "A New Enantioselective Total Synthesis of AI-77-B"Organic Lett.. 1. 499-502 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "A New Quinazoline Synthesis"Synlett. 1999. 1993-1995

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Gamoh: "Catalyiic Activity and Enantioselectivity in Organic Solvent of Lipase Immobilized on ODS-sugar Ester"BUNSEKIKAGAKU. 48. 1149-1155 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "High-Pressure Organic Chemistry. Part 23 A New Facile Method for the Synthes is of 4-Dialkylaminopyridine Derivatives by High-Pressure-Promoted Amination of 4- Chloropyridine"Synlett. 2000. 116-118

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Kotsuki: "A Novel Synthesis of a Highly Sterically Hindered CィイD22ィエD2 -Symmetric Chiral Pyridine Derivative"Heterocycles. 52. 661-666 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Matsuoka: "Immunochemical Analysis of a Photoreceptor Protein Using Anti-IP3 Receptor Antibody in the Unicellular Organism, Blepharisma"J. Photochem. Photobiol.. in press. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Hayashi: "Asymmetric Synthesis : Graphical Abstracts and Experimental Methods"Kodansha. 396 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Matsumoto: "High Pressure Organic Synthesis"Nakanishiya. 466 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Gamoh,K.Emi,H.Kotsuki: "Optical Resolution by Immobilized Lipase"Chromatography. 20. 26-27 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "A New Convenient Friedel-Crafts Alkylation of Aromatic Compounds with Secondary Alcohol Methane sulfornates in the Presence of Sc(OTf)3 or・・・"Synthesis. 603-606 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "Sc(OTf)3- and TfOH-Catalyzed Baeyer-Villiger Oxidation of Carbonyl Compounds with m-Chloooperbenzoic Acid"Synlett. 462-464 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 小槻 日吉三: "キラルトリフラート法-光学活性天然物合成の新手法"有機合成化学協会誌. 57. 334-345 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "Trifluoromethanesulfonic Acid,an Unusually Powerful Catalyst for the Michael Addition Reaction of β-Ketoesters under Soluom-Free Conditions"Journal of Organic Chemistry. 64. 3770-3773 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "Ytlerbium(III) Trifluoromethanesulfonate-Catalyzed Homoconjugate Addition of β-Ketoesters with Activated Cyclopropane Derivasioes at High Pressure"Synlett. 650-652 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "A New Enantioselective Total Synthesis of AI-77-B"Organic Letters. 1. 499-502 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "A New Quirazoline Synthesis"Synlett. 1993-1995 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 蒲生啓司,坂田知栄子,小槻日吉三: "ODS-ショ糖エステルに固定化したリパーゼの有機溶媒中での酵素活性およびエナスチオ選択性"分析化学. 48. 1149-1155 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "A New Facile Method for the Synthesis of 4-Dialkylaminopyridine Derivatives by High Pressure -Promoted Amination of 4-Chloropyridine"Synlett. 116-118 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki,他3名: "A Novel Synthesis of a Highly Sterically Hindered G-Symmetric Chiral Pyridine Denvatioe"Heterocycles. 52. 661-666 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Matsuoka,他5名: "Immonochemical Analysis of a Photoreceptor Protein Using Anti-IP3 Receptor Antibody in the Unicellular Organism,Blepharisma"Journal of Photochemistry of Photobiology. (印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 松本 澄、井畑敏一.編: "超高圧有機合成-高効率分子変換と反応制御を目指して-"ナカニシヤ書店. 466 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kotsuki: "Solvont-Free Organsc Reactions on Silica Gel Supports Fauile Transformasion of Epoxides to B-halohydrins with Lithium Halides" Tetrahodron. 54. 2709-2722 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "A Facile New Method for Solective Deprolecdion of N-(tert-Butoxycarboyl)-Protected Carboxamides with Yb(OTf)3 Supported on Silica Gel" Tetrahodron Letlers. 39. 4869-4870 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "Scandium(III)Trifluoromethane sulfonate-Catalyzed Friedol-Crofts Alkylation of Aromatic Conpounds with Secondary Alcohol Methanesfulfonates" Synlett. 255-256 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "Organic Synthesis at High Pressure.Efficient Ring Opening Reaction of Epoxides with Heterocyclos" Review of High Pressure Scionce & Technology. 7. 1250-1252 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "Soprthesis of Novel Chiral Oligopyridrie Derivative Ligands for the Enantioselective Addition of Dietlylzinc to Benzaldehyde." Tetrahodron:Asymmetry. 9. 3203-3212 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "A New Conveniont Friedel-Ceafts Alkylarion of Aromatic Cosypoinds with Secondary slcohol Methanesatforates in the Prescnce of Scandium(III)Taifluoronerhanesulfomte or" Sgnthesis. 印刷中. 印刷中 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "Sc(OTf)3-and TfOH-Caralyzed Baeyer-Valliger Oxidation of Carbonyl Compounds with m-Chloroperbenzoic Acid" Synlett. 印刷中. 印刷中 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "Trifheoromerhanesultonic Acid,an Unusually Poqerful Catalyst forthe Michael Addition Roacrion of B-Keroestcrs under Solvent-Free Conditions" Journal of Organic Chemuistry. 64 印刷中. 印刷中 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "Ytterbium(III) Trsfluoromerhanesuiforate Catolyced Homocoryusate Additim Rcactions of B-Ketoestcrs with Bctivased Cyclopropane Derivasies at lhigh Pressure" Synlett. 印刷中. 印刷中 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 小槻 日吉三: "キシルトリフラート法-光学活性天然物合成の新手法" 有機合成化学協会誌. 57 印刷中. 印刷中 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 林・富岡・米光 編: "Asymmedric Symrheais:Geaphical Absrocts and Expeaimenal Mefhals" 講談社, 396 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 松本 澄 編: "超高圧有機合成-高効率分子交換と反応制御を目指して-" ナカニミヤ出版 印刷中, 印刷中 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kotsuki: "A New Facile Method for the Chemoselective Roductive Transformation of Azides to N-(terl-Butoxycarbonyl)amines" Tetrahedron Letlers. 38. 2129-2132 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kotsuki: "Yb(OTf)_3-Catalyzed Michael Addision Rいactions of p-Ketoeskrs on Silica Gel supports and at High Pressure" Jetrahedron Letlers. 38. 7583-7586 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Kotsuki: "Organic Synthesis at High Pressure.Efficient Ring Opening Reactioo of Epoxides with Heterocycles" The Review of High Pressure Science and Technology. 7. (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Gamoh: "Moleculer Template Formation on Serum Albumin under High Pressare Conditions" Chaomatography. 18. 88-89 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Gamoh: "Precision Based Qptimization of HL LC-MS Analysisi Experimental and Theoretical Verification of Internal Standart Method" Chromatography. 18. 268-269 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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