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Field Emission of Electrons from Carbon Nanotubes with Extremely Sharp Tips and Its Application to Electron Sources

Research Project

Project/Area Number 09555003
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Applied materials science/Crystal engineering
Research InstitutionMIE UNIVERSITY

Principal Investigator

SAITO Yahachi  MIE UNIVERSITY, DEPARTMENT OF ELECTRICAL AND ELECTRIC ENGINEERING, ASSOCIATE PROFESSOR, 工学部, 助教授 (90144203)

Co-Investigator(Kenkyū-buntansha) KURODA Katsuhiro  HITACHI MEDICO, TECHNOLOGY RESEARCH LABORATORY, VICE-HEAD OF THE LABORATORY, 技術研究所, 副所長
HATA Koichi  MIE UNIVERSITY, DEPARTMENT OF ELECTRICAL AND ELECTRIC ENGINEERING, ASSISTANT PROFESSOR, 工学部, 助手 (30228465)
OHSHITA Akinori  MIE UNIVERSITY, DEPARTMENT OF ELECTRICAL AND ELECTRIC ENGINEERING, PROFESSOR, 工学部, 教授 (80023240)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥5,400,000 (Direct Cost: ¥5,400,000)
Fiscal Year 1999: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1998: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1997: ¥2,900,000 (Direct Cost: ¥2,900,000)
KeywordsCarbon nanotude / Field emission / Electron source / Field emission microscopy / Multiwall nanotube / Single-wall nanotube / Display device / カーボンファイバー / 蛍光表示管 / アーク放電
Research Abstract

Carbon nanotubes possess physical and chemical properties favorable for field emitters. In this study, fundamental properties of field emission from carbon nanotubes are elucidated, and nanotube-based field-emission display devices are experimentally manufactured and their performance is examined.
1. Electron Emission from Carbon Nanotubes Studied by Field Emission Microscopy (FEM)
Field Emission from a variety, of carbon nanotubes, e.g., multiwall nanotube (MWNT), nanografiber (NGF), and single-wall nanotube (SWNT), was investigated by using an FEM apparatus constructed newly. Among the nanotubes studied, oxidized MWNTs with open tips exhibited the most excellent emission properties, and purified SWNTs and NGF were the next good emitters.
2. Electron Emission from Films of Carbon Nanotubes Spread on Cathode Plates
When the gap between the nanotube cathode and the grid was 1 mm and the grid voltage was 750 V, current density of 2.5 mA/cmィイD12ィエD1 as obtained for NGF, and approximately 0.1 mA/cmィイD12ィエD1 for MWNT and SWNTs.
3. Effects of Ambient Gases on Lifetimes of Nanotube Emitters
Life tests of MWNT emitters performed under ambient gases of oxygen, water, nitrogen and argon revealed that oxygen was the most hazardous gas for nanotube emitters.
4. Fabrication of Nanotube-Base Field Emission Display Elements and Their Performance
Cathode ray tube (CRT) lighting-elements were manufactured by replacing conventional thermionic cathodes with nanotube field emitters. Stable electron emission, high emission current with low electric field (〜10 mA/cmィイD12ィエD1 at 1.5 V/μm), and long life of the emitters were demonstrated.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (75 results)

All Other

All Publications (75 results)

  • [Publications] Y. Saito: "Conical Beams from Open Nanotubes"Nature. 389. 554-555 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission Patterns from Single-Walled Carbon Nanotubes"Jpn. J. Appl. Phys.. 36. L1340-L1342 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Cathode Ray Tube Lightning-Elements with Carbon Nanotube Field Emitters"Jpn. J. Appl. Phys.. 37. L346-L348 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes ; Purified Single-Walled and Multi-Walled Tubes"Ultramicroscopy. 73(1-4). 1-6 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Multi-Wall Carbon Nanotubes and Its Application to Electron Tubes"Appl. Phys. A.. 67(1). 95-100 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "High Yield of Single-Wall Carbon Nanotubes by Arc Discharge Using Rh-Pt Mixed Catalysts"Chem. Phys. Lett.. 294. 593-598 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to FED Elements"Workshop Digest of Technical Papers of Asia Display '98. 173-181 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to Cathode Ray Tube Lighting Elements"Appl. Surface Sci.. 146. 305-311 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Synthesis, Structure and Field Emission of Carbon Nanotubes"Fullerene Sci.l Tech.. 7(4). 653-664 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Hata: "Selective Formation of C20 Cluster Ions by Field Evaporation from Carbon Nanotubes"Chem. Phys. Lett.. 308(3/4). 343-346 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Carbon Nanotubes Produced by Arc Discharge"New Diamond and Frontier Carbon Tech.. 9(1). 1-30 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Applications to Electron Sources"AIP Conference Proc.. 486. 439-443 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to Electron Sources"Carbon. 38(2). 169-182 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Diameter of Single-Wall Carbon Nanotubes Dependingon Helium Gas Pressure in Arc Discharge"J. Phys. Chem. B.. (in press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブの合成と物性"エレクトロニクス・コミュニケーション. 12. 2-9 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "ストラティファイド評価技術-ナノプローブ法-超高分解能電子顕微鏡による組織の観察と分析"金属. 68(4). 315-322 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブからの電界電子放出と電子源への応用"セラミックス誌. 33(6). 434-437 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "新しい形態の炭素-フラーレンとナノチューブ-"日本エネルギー学会誌. 77(9). 858-867 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブからの電界電子放出"表面科学. 19(10). 680-686 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブ電界放出電子源の試作に成功(発光表示デバイスへの応用)"季刊フラーレン. 6(2). 22-26 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "アーク放電によるナノチューブ,ナノカプセルの合成と応用"プラズマ・核融合学会誌. 75(8). 908-913 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノカプセルと単層ナノチューブ"電子顕微鏡. 34(2). 115-116 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブの作製と電子放出特性"真空. 42(8). 717-721 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブからの電界放出"ディスプレイアンドイメージング. 8(1). 69-75 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "新展開を迎えるカーボンナノチューブ"パリティ. 14(12). 101-103 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブの応用-電界放出型電子源-"むきざいNOW. No.179. 6-6 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブからの電界放出とディスプレイデバイスへの応用"応用物理学会誌. 69(3). 314-317 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "炭素ナノ繊維を用いた電子源および炭素イオン源"材料技術. 18(1). 5-11 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 篠原 久典: "フラーレンの化学と物理"名古屋大学出版会. 302 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 齋藤 弥八: "カーボンナノチューブの基礎"コロナ社. 206 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Conical Beams from Open Nanotubes"Nature. 389. 554-555 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission Patterns from Single-Walled Carbon Nanotubes"Jpn. J. Appl. Phys.. 36. L1340-L1342 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Cathode Ray Tube Lighting-Elements with Carbon Nanotube Field Emitters"Jpn. J. Appl. Phys.. 37 (3B). L346-L348 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes ; Purified Single-Walled and Multi-Walled Tubes"Ultramicroscopy. 73 (1-4). 1-6 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Multi-Walled Carbon Nanotubes and Its Application to Electron Tubes"Appl. Phys.. A 67 (1). 95-100 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "High Yield of Single-Wall Carbon Nanotubes by Arc Discharge Using Rh-Pt Mixed Catalysts"Chem. Phys. Lett.. 294. 593-598 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to FED Elements"Workshop Digest of Asia Display '98. 1998. 173-181 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to Cathode Ray Tube Lighting Elements"Appl. Surface Sci.. 146. 305-311 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Synthesis Structure and Field Emission of Carbon Nanotubes"Fullerene Sci. Tech.. 7 (4). 653-664 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Hata: "Selective Formation of CィイD220ィエD2 Cluster Ions by Field Evaporation from Carbon Nanotubes"Chem. Phys. Lett.. 308 (3/4). 343-346 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Carbon Nanotubes Produced by Arc Discharge"New Diamond and Frontier Carbon Tech.. 9 (1). 1-30 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to Electron Sources"AIP Conference Proc.. 486. 439-443 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to Electron Sources"Carbon. 38 (2). 169-182 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Diameters of Single-Wall Carbon Nanotubes Depending on Helium Gas Pressure in Arc Discharge"J. Phys. Chem. B. (in press). (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Synthesis and Physical Properties of Carbon Nanotubes (in Japanese)"Electronics Commun.. 12. 2-9 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Characterization Technique for Stratified Materials - Observation and Analysis of textures by High Resolution Electron Microscopy - (in Japanese)"Kinzoku. 68(4). 315-322 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Electron Field Emission from Carbon Nanotubes and Its Application to Electron Sources (in Japanese)"Bulletin of the Ceramic Society of Japan. 33(6). 434-437 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "New Forms of Carbon - Fullerenes and Nanotubes (in Japanese)"J. Jpn. Institute of Energy. 77 (9). 858-867 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Electron Field Emission from Carbon Nanotubes (in Japanese)"J. Surface Sci. Soc. of Jpn.. 19 (10). 680-686 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Success in Experimental Manufacturing of Carbon Nanotube-Based Electron Sources (Application as Light-Emitting Display Devices) (in Japanese)"Quarterly Fullerene. 6 (2). 22-26 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Synthesis and Application of Nanotubes and Nanocapsules (in Japanese)"J. Plasma and Fusion Research. 75 (8). 908-913 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Carbon Nanocapsules and Single-Wall Nanotubes (in Japanese)"Electron Microscopy. 34 (2). 115-116 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Production of Carbon Nanotubes and Electron Emission Properties (in Japanese)"J. Vacuum Soc. Jpn.. 42 (8). 717-721 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes (in Japanese)"Display and Imaging. 8 (1). 69-75 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Carbon Nanotube Studies Developing to a New Phase (in Japanese)"Parity. 14 (12). 101-103 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Application of Carbon Nanotubes - Field Emission Electron Sources -"Mukizai NOW. No.179. 6 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Field Emission from Carbon Nanotubes and Its Application to Display Devices (in Japanese)"Oyo Buturi. 69 (3). 314-317 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Electron and Carbon Ion Sources Utilizing Carbon Nanofibers (in Japanese)"Material Technology. 18 (1). 5-11 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Shinohara: "Chemistry and Physics of Fullerenes (in Japanese)"Nagoya University Press. 302 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Saito: "Introduction to Carbon Nanotubes (in Japanese)"Corona-sha. 206 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Yahachi Saito: "Field Emission from Carbon Nanotubes and Its Application to Cathode Ray Tube Lighting Elements"Appl.Surface Sci.. 146. 305-311 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yahachi Saito: "Synthesis,Structure and Field Emission of Carbon Nanotubes"Fullerene Sci.Tech.. 7・4. 653-664 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Koichi Hata: "Selective Formation of C_<20> Cluster Ions by Field Evaporation from Carbon Nanotubes"Chem.Phys.Lett.. 308・3/4. 343-346 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yahachi Saito: "Carbon Nanotubes Produced by Arc Discharge"New Diamond and Frontier Carbon Tech.. 9・1. 1-30 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yahachi Saito: "Field Emission from Carbon Nanotubes and Its Application to Electron Sources"AIP Conference Proceedings. 486. 439-443 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yahachi Saito: "Field Emission from Carbon Nanotubes and Its Application to Electron Sources"Carbon. 38・2. 169-182 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Yahachi Saito: "Cathode Ray Tube Lighting Elements with Carbon Nanotube Field Emitters" Japanese Journal of Applied Physics. 37・3B. L346-L348 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Saito: "Field Emission from Multi-walled Carbon Nanotubes and its Application to Electron Tubes" Applied Physics A. 67・1. 95-100 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 齋藤弥八: "カーボンナノチューブからの電界放出と電子源への応用" セラミックス. 33・6. 434-437 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 齋藤弥八: "カーボンナノチューブからの電界電子放出" 表面科学. 19・10. 680-686 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 齋藤弥八: "新しい形態の炭素(フラーレンとナノチューブ)" 日本エネルギー学会誌. 77・9. 858-867 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 齋藤弥八: "カーボンナノチューブの基礎" コロナ社, 206 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Yahachi Saito: "Conical Beams from Open Nanotubes" Nature. 389. 554-555 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yahachi Saito: "Field Emission Patterns from Single-Walled Carbon Nanotubes" Japanese Journal of Applied Physics. 36. L1340-L1342 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] Yahachi Saito: "Field Emission from Carbon Nanotubes;Puried Single-Walled and Multi-Walled Tubes" Ultramicroscopy. (印刷中).

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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