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Fabrication of semiconductor nano-scale structures and control of its electrical characteristics by means of quantum doping

Research Project

Project/Area Number 09555102
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Electronic materials/Electric materials
Research InstitutionWaseda University

Principal Investigator

OHDOMARI Iwao  Waseda Univ, Sch. Of Sci. and Eng., Professor, 理工学部, 教授 (30063720)

Co-Investigator(Kenkyū-buntansha) HARA. Ken-ichi  Waseda Univ. Sch. Of Sci. and Eng., Research associate, 理工学部, 助手 (40298162)
TOYOSHIMA Yoshiaki  Toshiba, マイクロエレクトロニクス研究所, 主査
松川 貴  早稲田大学, 理工学部, 助手 (70287986)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥12,900,000 (Direct Cost: ¥12,900,000)
Fiscal Year 1999: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1998: ¥4,800,000 (Direct Cost: ¥4,800,000)
Fiscal Year 1997: ¥7,200,000 (Direct Cost: ¥7,200,000)
KeywordsQuantum doping / Single ion implantation / Impurity atom / Dopant / Semiconductor / Focused ion beam / Surface modification / Nano structure / 単一イオン抽出 / 2次電子検出 / 不純物揺らぎ / ドーパント個数制御 / SIMOX基板 / 異方性エッチング / ゆらぎ / 活性化 / MOS界面準位
Research Abstract

Trimming of the inherent fluctuation in electrical properties of a fine resistor which corresponds to an active region in semiconductor devices has been tried for the tirst time by implanting a small number of dopant atoms by means of single ion implantation (SII) which enables us to implant dopant ions one by one into a fine semiconductor region until the necessary number is reached. Firstly the conductance increase per one dopant atom in a sub-μm scale Si resistor was measured to be 18 nS/atom. Secondly very fine test resistors with a size of sub-μm were made by conventional device fabrication technology and the statistical distribution of conductance in the test devices was obtained. The initial conductance deviated considerably from the mean value, evaluated to be 63%. Finally based on the experimental increment of conductance per an ion, the number of single ions necessary to trim the conductance value into a certain value in the higher side of the initial conductance distribution … More was implanted to each test resistor. It was foud that the initial conductance fluctuation of 63% has been successfully reduced to only 13%. This result leads to the conclusion that the electrical properties in a fine semiconductor region can be controlled by implanting a necessary number of dopant atoms by SII in one-by-one manner. It was discovered that the value based on the analysis of various factors of fluctuation was larger than the experimental one, 13%. The reason for the large discrepancy was believed to be due to the overstimation of impurity position fluctuation in the specimens in which single ions were implanted at an interval of 0.3μm and the impurity position was not random in reality. We expect that a better correlation between impurity positions to be achieved by higher aiming precision of single ion incidence with SII would cause a smaller position fluctuation. This study clarifies an essential issue of controlling not only the impurity atom number but also their positions experimentally for the first time. Less

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (74 results)

All Other

All Publications (74 results)

  • [Publications] M.Koh: "Quantitative characterization of Si/SiO2 interface traps induced by energetic ions by means of single ion microprobe and single ion beam induced charge imaging"Appl.Surf.Sci.. 117/118. 171-175 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Development of single-ion implantation-controllability on implanted ion number"Appl.Surf.Sci.. 117/118. 677-683 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Damage and contamination free fabrication of thin Si wires with highly controlled feature size"Appl.Surf.Sci.. 117/118. 684-689 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koyama: "Estimation of spatial extent of a defect cluster in Si induced by single ion irradiation"Jpn.J.Appl.Phys.. 36. L708-710 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 松川貴: "シングルイオン照射とその応用"放射線. 23. 25-34 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koyama: "Influence of near-surface defects in Si induced by reactive ion etching on the electrical properties of the Pt/n-Si interface"Jpn.J.Appl.Phys.. 36. 6682-6686 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 原謙一: "シングルイオン注入と電気化学反応を用いたウェハースケールテクノロジー"電子情報通信学会信学技報. ED-97-07. 35-40 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Three-dimensinal site dependence of single-ion-induced charge collection at a p-n junction - role of funneling and diffusion processes under different ion energy"J.Appl.Phys.. 83. 3413-3418 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Key technologies of FIB system for single ion implantation"J.Vac.Sci.Technol.B. 16. 2479-2483 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "The current status of single ion implantation"J.Vac.Sci.Technol.B. 16. 2489-2493 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 原謙一: "シングルイオン注入と電気化学反応を用いたウェーハスケールテンクノロジー"電子情報通信学会論文誌. J81-C-2. 675-679 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Sumita: "Nano-fabricated CDW by ion-beam irradiation"Synthetic Metals. 103. 2234-2237 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Lateral migration of point defects in Si induced by localized ion implantation"Appl.Phys.Lett.. 74. 2663-2665 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kubota: "Nano-fabrication of CDW and its negative resistance phenomenon"J.Phys.IV France. 9. 175-197 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Influence of secondary electron detection efficiency on controllability of dopant ion number in single ion implantation"J.Appl.Phys.. 38. 3419-3421 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "Quantitative characterization of ion-induced SiO2/Si interface traps by means of MeV He single-ion irradiation"J.Appl.Phys.. 85. 1714-1718 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "Simple fabrication of nanopyramid array (NPA) on Si surface by means of focused ion beam patterning wet etching"Ext.Abst.SSDM. 184-185 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Hara: "Single-ion detection using nuclear track detector CR-39 plastic"Rev.Sci.Instrum.. 70. 4536-4538 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Reduction of fluctuation in semiconductor conductivity by one-by-one ion implantation of dopant atoms"J.Appl.Phys.. 39. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "New process for Si nanopyramid array (NPA) fabrication by means of ion beam irradiation and wet etching"J.Appl.Phys.. 39. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Flat-band voltage control of a back-gate MOSFET by single ion implantation"Appl,Surf.Sci., in press.. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "Simple nanostructuring of Si surfaces by means of focused beam patterning and wet etching"Appl,Surf.Sci., in press.. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.Sawara: "Simple fabrication of high density concave nanopyramid array(NPA) on Si surface"Appl,Surf.Sci., in press.. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "New process for Si nanopyramid array (NPA) fabrication by means of ion beam irradiation and wet etching"Appl,Surf.Sci., in press.. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Koh: "Quantitative characterization of Si/SiO2 interface traps induced by energetic ions by means of single ion microprobe and single ion beam induced charge imaging"Appl. Surf. Sci.. Vol. 117/118. 171-175 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Development of single-ion implantation controllability of implanted ion number"Appl. Surf. Sci.. Vol.117/118. 677-683 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Damage and contamination free fabrication of thin Si wires with highly controlled feature size"Appl. Surf. Sci.. Vol.117/118. 684-689 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koyama: "Estimation of spatial extent of a defect clluster in Si induced by single ion irradiation"Jpn. J. Appl. Phys.. Vol.36. L708-710 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Single ion irradiation and its application"Houshasen. Vol.23 (in Japanese). 25-34 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koyama: "Influence of near-surface defects in Si induced by reactive ion etching on the electrical properties of the Pt/b-Si interface"Jpn. J. Appl. Phys.. Vol.36. 6682-6686 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Hara: "Wafer-scale nano-fabrication using single-ion-implantation and electrochemical process"Technical report of IEICE. ED-97-07 (in Japanese). 35-40 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Matsukawa: "Three-dimensinal site dependence of single-ion-induced charge collection at a p-n junction-role of funneling and diffusion processes under different ion energy"Jpn. J. Appl. Phys.. Vol.83. 3413-3418 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Key technologies of FIB system for single ion implantation"J. Vac. Sci. Technol. B. Vol.16. 2479-2483 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "The current status of single ion implantation"J. Vac. Sci. Technol. B. Vol.16. 2489-2493 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Hara: "Wafer-scale nano-fabrication using single-ion-implantation and electrochemical process"Trans. of IEICE. Vol. J81-C-2. 675-679 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Sumita: "Nano-fabricated CDW by ion-beam irradiation"Synthetic Metals. 103. 2234-2237 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Matsukawa: "Lateral migration of point defects in Si induced by localized ion implantation"Appl. Phys. Lett.. Vol.74. 2663-2665 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.kubota: "Nano-fabrication of CDW and its negativeresistance phenomenon"J. Phys. IV France. Vol.9. 175-177 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Influence of secondary electron detection efficiency on controllability of dopant ion number in single ion implantation"Jpn. J. Appl. Phys.. Vol.38. 3419-3421 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "Quantitative characterization of ion-induced SiO2/Si interface traps by means of MeV He single-ion irradiation"J. Appl. Phys.. Vol.85. 7814-7818 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "Simple fabrication of nanopyramid array (NPA) on Si surface by means of focused ion beam patterning wet etching"Ext. Abst. SSDM, 1999 (Tokyo). 184-185

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Hara: "Single-ion detection using nuclear track detector CR-39 plastic"Rev. Sci. Instrum. Vol.70. 4536-4538 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Reduction of fluctuation in semiconductor conductivity by one-by-one ion implantation of dopant atoms"Jph. J. Appl. Phys.. Vol.39. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "New process for Si nanopyramid array (NPA) fabrication by means of ion beam irradiation and wet etching"Jph. J. Appl. Phys.. Vol.39 (in press). (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Flat-band voltage control of a back-gate MOSFET by single ion implantation"Appl. Surf. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "Simple nanostructuring of Si surfaces by means of focused beam patterning and wet etching"Appl. Surf. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Sawara: "Simple fabrication of high density concave nanopyramid array (NPA) on Si surface"Appl. Surf. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Koh: "New process for Si nanopyramid array (NPA) fabrication by means of ion beam irradiation and wet etching"Appl. Surf. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Shinada: "Influence of secondary electron detection effciency controllability of dopant ion number in single ion implantation"Jpn.J.Appl.Phys.. 38. 3419-3421 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Koh: "Quantiative characterization of ion-induced SiO2/Si interface traps by means of MeV He single-ion irradiation"J.Appl.Phys.. 85. 7814-7818 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kubota: "Nano-fabrication of CDW and its negative resistance phenomenon"J.Phys.IV France. 9. 175-177 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Hara: "Single-ion detection using nuclear track detector CR-39 plastic"Rev.Sci.Instrum. 70. 4536-4538 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Shinada: "Control of electrical characteristics in fine semiconductor by pinpoint doping of impurity atoms"Proc.of 18^<th> symp.on mat.sci.and Eng.,Tokyo (Hosei univ.,1999). 101-106 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Shinada: "Flat-band voltage control of a back-gate MOSFET by single ion implantation"Appl.Surf.Sci.. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Matsukawa, et al.: "Three-dimensinal site dependence of single-ion-induced charge collection at a p-n junction-role of funneling and diffusion process under different ion energy" J.Appl.Phys.Vol.83. 3413-3418 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Matsukawa, et al.: "Key technologies of FIB system for single ion implantation" J.Vac.Sci.Technol.B. Vol.16. 2479-2483 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Shinada, et al.: "The current status of single ion implantation" J.Vac.Sci.Technol.B. Vol.16. 2489-2493 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Matsukawa, et al.: "Three-dimensinal site dependence of single-ion-induced charge collection at a p-n junction-role of funneling and diffusion processes under differention energy," Journal of Applied Physics(to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Matsukawa, et al.: "Key technologies of FIB system for single ion implantation" Journal of Vacuum Science and Technology B(to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Koh, et al.: "Quantitative characterization of Si/SiO_2 interface traps induced byenergetic ions by means of single ion microprobe and single ion beam induced charnge imaging," Applied Surface Science. 117/118. 171-175 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Koyama, et al.: "Estimation of Spatial Extent of a Defect Cluster in Si Induced by SingleIon Irradiation," Japanese Journal of Applied Physics. 36. L708-710 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Koyama, et al.: "Influence of Near-Surface Defects in Si Induced by Reactive Ion Etching on the Electrical Properties of the Pt/n-Si Interface," Japanese Journal of Applied Physics. 36. 6682-6686 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Shimada, et al.: "Reactivity of O_2 with Si(111)surfaces with different surface structures" Applied Surface Science. (to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Ishimaru, et al.: "Role of corner holes in the formation of SF half unit of DAS structures" Applied Surface Science. (to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Watanabe, et al.: "Mechanism of H_2 desorption from H-terminated Si(001)surfaces" Applied Surface Science. 117/118. 67-71 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] I.Ohdomari, et al.: "Consideration of atom movement during Si surface reconstruction" Phase Transitions. 62. 245-258 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Watanabe, et al.: "Monte Carlo study on formation of periodic structures on Si(111)surfaces," Surface Science. 389. 357-381 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Hoshino, et al.: "Theoretical investigation on the formation process of the stacking-fault triangle in the Si(111)-7x7 structure" Surface Science. 394. 119-128 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Watanabe, et al.: "Effects of fixed particles on periodic adatom arrangements on Si(111)unreconstructed surfaces" Applied Surface Science. (to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Shimada, et al.: "Damage and contamination free fabrication of thin Si wires with highly controlled feature size" Applied Surface Science. 117/118. (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Shimada, et al.: "The current status of sigle ion implantation" Journal of Vacuum Science and Technology B. (to be published).

    • Related Report
      1997 Annual Research Report
  • [Publications] 原謙一、他: "シングルイオン注入と電気化学反応を用いたウェハ-スケールテクノロジー" 電子情報通信学会信学技報. ED-97-07. 35-40 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 松川 貴、他: "シングルイオン照射とその応用" 放射線. 23. 25-34 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Matsukawa, et al.: "Development of single-ion implantation-controllability of implanted ion number" Applied Surface Science. 117/118. 677-683 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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