| Project/Area Number |
09555201
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
Composite materials/Physical properties
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| Research Institution | Shizuoka University |
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Principal Investigator |
INAGAKI Norihiro Shizuoka University Fac. Eng. Professor, 工学部, 教授 (30022015)
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| Co-Investigator(Kenkyū-buntansha) |
SUZUKI Takanori Tomoegawa Paper Co. Senior Researcher, 技術研究所, 首席研究員
YAMASHITA Mitsuji Shizuoka University Fac. Eng. Professor, 工学部, 教授 (60110748)
TASAKA Shigeru Shizuoka University Fac. Eng. Professor, 工学部, 教授 (10134793)
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| Project Period (FY) |
1997 – 1999
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| Project Status |
Completed (Fiscal Year 1999)
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| Budget Amount *help |
¥12,700,000 (Direct Cost: ¥12,700,000)
Fiscal Year 1999: ¥4,200,000 (Direct Cost: ¥4,200,000)
Fiscal Year 1998: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1997: ¥6,300,000 (Direct Cost: ¥6,300,000)
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| Keywords | Copper metallization / Teflon / Polyimide / Plasma treatment / Silane coupling / Electroless plating / Electro plating / Imidazole / 表面金属化 / メタライジング / フッ素ポリマー / 同軸ケーブル / プリント配線基板 / シランカップリング反応 / ポリテトラフルオロエチレン / リモートプラズマ |
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| Research Abstract |
The concept of this project is based on the preliminary results, which have been published by the head investigator in the Journal (Macromolecules). These are (1) Improved Adhesion between Kapton Film and Copper Metal by Plasma Graftpolymerization of Vinylimidazole (Macromolecules, vol. 29, pp. 1642-1648 (1996)), and (2) Surface Modification of Poly(tetrafluoroethylene) by remote Hydrogen Plasma (Macromolecules, vol. 29, pp. 4331-4339 (1996)). Introduction of some residues which can strongly interact with metal surface are introduced into the polymer surfaces is an essential factor in order to metallize polymer surfaces. Following procedures were designed:
For copper metallization of polyimide which is superior to electrical resistance, mechanical and thermal properties, the imidazole group was used as a residue to interact strongly with copper metal surface. 3'(Trimethoxysilyl)propoxy-2-hydroxypropyl-1,3-diazole was coupled with Kapton film surfaces which had been treated with argon plasma (plasma treatment). For copper metallization of fluoropolymers which are excellent electrical resistance in the high frequency current, the carbonyl group which was formed by hydrogen plasma treatment was used as a residue to interact wit metal surface.
The copper metallization of these polymer surfaces succeeded. The adhesion between the copper metal and polymer surface was good for practice usage.
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