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Technological Development for Neutralizing Contamination by Impurities in Recycled Aluminum Alloys by Control of Solidification Reaction

Research Project

Project/Area Number 09555210
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Structural/Functional materials
Research InstitutionNagaoka University of Technology

Principal Investigator

KOJIMA Yo  Nagaoka University of Technology, Faculty of Engineering, Professor, 工学部, 教授 (60016368)

Co-Investigator(Kenkyū-buntansha) KAMADO Shigeharu  Nagaoka University of Technology, Faculty of Engineering, Associate Professor, 工学部, 助教授 (30152846)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥11,500,000 (Direct Cost: ¥11,500,000)
Fiscal Year 1999: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1998: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 1997: ¥7,900,000 (Direct Cost: ¥7,900,000)
KeywordsWrought Aluminum Alloy / Recycling / Impurity / Mechanical Property / Microstructure / Formability / Electromagnetic Casting / Microalloying / アルミニウム合金 / 無害化技術 / 金属間化合物 / 時効析出 / 耐食性 / 凝固反応 / 熱分析 / 引張特性
Research Abstract

Effects of impurities, which contaminate the melts during recycling, and useful elements for removal of the impurities on mechanical properties of the recycled aluminum alloys were investigated. Furthermore, shapes and sizes of the crystallized compounds, and grain size were altered by an application of electromagnetic casting and micro alloying, and their influences on mechanical properties were also evaluated.
(1) When Mn and Zr, which are effective for removal of iron from the melt, are added to the 6061 AI-Mg-Si alloy, a compound containing Si increases with an increase in Mn content and, therefore, age hardenability is lowered and proof stress and tensile strength decrease. The manganese content in the alloy with 0.3% Zr should be less than 0.4mass% to guarantee the tensile properties specified by JIS.
(2) When Si, which contaminate 3003 A1-Mn alloy from a cladding material, and Ca, which is an effective element for the removal of Si from the melt, are added to the alloy, the amount … More of a A1-Fe-Si compound increases as Si content increases, resulting in increases in proof stress and tensile strength, but a decrease in elongation. An addition of Ca above 0.3% gives rise to the disappearance of the A1-Fe-Si compound and the crystallization of a large amount of coarse A1ィイD26ィエD2(Fe,Mn) compound, and consequently, to remarkable degradation of elongation.
(3) Application of electromagnetic casting to the fabrication of a thin 5052 A1-Mg slab makes the crystallized compounds to be very fine and uniformly distributed. Therefore, even when the amount of crystallized compounds increases with an increase in Fe content, the compounds are useful for the dispersion strengthening and refining of the recrystallized grains. As a result, it is possible to increase proof stress and tensile strength while maintaining enough elongation with Fe content of up to 0.81%.
(4) As a result of adding small amount of Mn, Sr and Ca to 6N01 Al-Mg-Si alloy containing 0.7% Fe, it is found that Sr addition of 0.005% refines A1-Fe-Si compound and improves proof strength and tensile strength of T4-treated specimens and elongation of T6-treated specimens, resulting in satisfying JIS requirement on tensile properties Less

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (29 results)

All Other

All Publications (29 results)

  • [Publications] 大野 猛: "6061アルミニウム合金の組織および諸特性に及ぼすマンガンおよびジルコニウムの影響"軽金属. 48・2. 67-72 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kamado: "Fabrication of 5052 Aluminum Alloy Thin Slab by Electromagnetic Casting and Mechanical Properties of Its Cold-Rolled Sheet"Solidification & Gravity 2000, Materials Science Forum, (Proc. of The 3rd Intern. Conf. on Solidification and Gravity). 329-330. 473-478 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 石川 幸伯: "6N01アルミニウム合金の諸性質に及ぼすMn,Ca,Sr添加の影響"第96回軽金属学会春期大会講演概要集. 153-154 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Kojima: "Present Status of alminum Recycling and Recycling Technology Under Development in Japan"Proc. of The Rewas'99 Global Symp. on Recycling, Waste Treatment and Clean Technology. 2. 1083-1091 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 椛山 陽一: "電磁鋳造法により製造したアルミニウム合金薄板スラブの組織および引張特性"第95回軽金属学会秋期大会講演概要集. 293-294 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kamado: "Fabrication of Thin Aluminum Alloy Slabs by Electromagnetic Casting"Aluminum Alloys - Their Physical and Mechanical Properties - (Proc. of The 6^<th> Intern. Conf. on Aluminum Alloys). 1. 195-200 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 原 昌宏: "6N01アルミニウム合金の諸性質に及ぼすFeの影響"第95回軽金属学会秋期大会講演概要集. 201-202 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 原 昌宏: "3003アルミニウム合金の諸性質に及ぼすSi、CaおよびZnの影響"第94回軽金属学会春期大会講演概要集. 319-320 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 椛山 陽一: "電子鋳造法により製造したアルミニウム合金薄板スラブの組織および冷間圧延材の引張特性"第94回軽金属学会春期大会講演概要集. 193-194 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 高坂 忠洋: "電磁鋳造法によるアルミニウム合金薄板スラブの製造"日本鋳造工学会第130回全国講演大会講演概要集. 95 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kamado, T. Kosaka, Y. Kabayama, Y. Kojima, T. Muramatsu and M. Matsuo: "Fabrication of 5020 Aluminum Alloy Thin Slab by Electromagnetic Casting and Mechanical Properties of Its Cold-Rolled Sheet"Solidification & Gravity 2000, Materials Science Forum, 329-330 (Proc. of The 3rd Intern. Conf. on Solidification and Gravity), Trans Tech Publications. 473-478 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Kojima, S. Kamado and T. Ohzono: "Present Status of Aluminum Recycling and Recycling Technology Under Development in Japan"Proc. of The "Rewas'99 Global Symp. on Recycling, Waste Treatment and Clean Technology", Vol. 2, TMS & iNASMET. 1083-1091 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kamado, T. Kosaka, Y. Kabayama, Y. Kojima, T. Muramatsu and M. Matsuo: "Fabrication of Thin Aluminum Alloy Slabs by Electromagnetic Casting"Aluminum Alloys -Their Physical and Mechanical Properties- Vol. 1 (Proc. of ICAA6), The Japan Institute of Light Metals. 195-200 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohno, K. Miyazawa, S. Kamado, Y. Kojima, R. Masuda and K. Ohsumi: "Effect of Mn and Zr on Microstructure and Various Properties of 6061 Aluminum Alloys"Journal of Japan Institute of Light Metals. Vol. 42, No. 2. 67-72 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Ishikawa, M. Hara, S. Kamado, Y. Kojima, S. Nishi and H. Matsuzaki: "Effect of Mn, Ca and Sr Addition on Various Properties of 6N01 Aluminum Alloy"Abstracts of the 96th Conf. of Japan Institute of Light Metals. 153-154 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Kabayama, I. Fujisaki, S. Kamado, Y. Kojima and T. Muramatsu: "Microstructure and Tensile Properties of Thin Aluminum Alloy Slabs fabricated by Electromagnetic Casting"Abstracts of the 95th Conf. of Japan Institute of Light Metals. 293-294 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Hara, Y. Ishikawa, S. Kamado, Y. Kojima, S. Nishi and H. Matsuzaki: "Effect of Fe on Various Properties of 6N01 Aluminum Alloy"Abstracts of the 95ィイD1thィエD1 Conf. of Japan Institute of Light Metals. 201-202 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Hara, S. Kamado, Y. Kojima, R. Masuda and S. Nishi: "Effect of Si, Ca and Zn on Various Properties of 3003 Aluminum Alloy"Abstracts of the 94ィイD1thィエD1 Conf. of Japan Institute of Light Metals. 319-320 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Kabayama, T. Kosaka, S. Kamado, Y. Kojima and T. Muramatsu: "Microstructure of Thin Aluminum Alloy Slabs fabricated by Electromagnetic Casting and Tensile Properties of Their Cold-Rolled Sheets"Abstracts of the 94ィイD1thィエD1 Conf. of Japan Institute of Light Metals. 193-194 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Kosaka, Y. Kanouya, S. Kamado, Y. Kojima and M. Matsuo: "Fabrication of Thin Aluminum Alloy Slab by Electromagnetic Casting"Abstracts of the 103ィイD1rdィエD1 Conf. of Japan Foundrymens Society. 95 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 石川 幸伯: "6N01アルミニウム合金の諸性質に及ぼすMn、Ca、Sr添加の影響"第96回軽金属学会春季大会講演概要. 153-154 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 椛山陽一: "電磁鋳造法により製造したアルミニウム合金薄板スラブの組織および冷間圧延材の引張特性" 第94回軽金属学会春期大会講演概要集. 193-194 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 原昌宏: "3003アルミニウム合金の諸性質に及ぼすSi,CaおよびZnの影響" 第94回軽金属学会春期大会講演概要集. 319-320 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 原昌宏: "6N01アルミニウム合金の諸性質に及ぼすFeの影響" 第95回軽金属学会秋期大会講演概要集. 201-202 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 椛山陽一: "電磁鋳造法により製造したアルミニウム合金薄板スラブの組織および引張特性" 第95回軽金属学会秋期大会講演概要集. 293-294 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 石川幸伯: "6N01アルミニウム合金の諸性質に及ぼすMn,Ca,Srの影響" 第96回軽金属学会春期大会. (発表予定). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Shigeharu Kamado: "Fabrication of 5052 Aluminum Allay Thin Slab by Electromagnetic Casting and Mechanical Properties of Its Cold-Rolled Sheets" The Third International Conference on Solidification and Gravity. (発表予定). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 原 昌宏: "3003合金の諸性質に及ぼすSiおよびCaの影響" 日本金属学会北陸信越支部・日本鉄鋼協会北陸支部平成9年度連合講演会概要集. 96 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 大野 猛: "6001アルミニウム合金のミクロ組織および機械的性質に及ぼすMn,Zrの影響" 軽金属. 第48巻 2号. 67-72 (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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