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Control of Mg-Based Hydrogen Storage Alloy Nanocrystallites and Their Surface Modification

Research Project

Project/Area Number 09555273
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 工業物理化学
Research InstitutionOsaka Prefecture University

Principal Investigator

IWAKURA Chiaki  Osaka Prefecture University, College of Engineering, Professor, 工学部, 教授 (00029183)

Co-Investigator(Kenkyū-buntansha) ZHANG Shu guo  Osaka Prefecture University, College of Engineering, Research Associate, 工学部, 助手 (10295719)
FURUKAWA Naoji  Osaka Prefecture University, College of Engineering, Assistant Professor, 工学部, 講師 (70081338)
INOUE Hiroshi  Osaka Prefecture University, College of Engineering, Associate Professor, 工学部, 助教授 (00213174)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥13,900,000 (Direct Cost: ¥13,900,000)
Fiscal Year 1999: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1998: ¥4,800,000 (Direct Cost: ¥4,800,000)
Fiscal Year 1997: ¥5,600,000 (Direct Cost: ¥5,600,000)
KeywordsNickel-hydrogen battery / Mg-based hydrogen storage alloy / Ball-milling / Surface modification / Graphite / Mechanical alloying / Charge-discharge characteristics / X-ray photoelectron spectroscopy / MgNi / 非晶質構造 / ボールミル / 多成分化 / サイクル特性 / Mg_2Ni-Ni複合体 / 改質 / 水素吸蔵特性 / ナノ結晶 / 構造制御 / ラマン分光 / 光電子分光
Research Abstract

The results obtained in this study for three years are summarized as follows.
1. XPS and Raman spectroscopy showed that electron transfer from graphite with π electrons to the oxidized surface Mg by ball-milling weakened the Mg-O bond strength, leading to the formation of the Ni-O bonding. The ratio of metallic Ni to Mg on the MgNi surface was increased by the ball-milling.
2. The rate of hydrogen absorption for MgィイD22ィエD2Ni-70 wt.% Ni composite at 30℃ markedly increased in comparison with MgィイD22ィエD2Ni and MgィイD22ィエD2Ni-70 wt.% mixture and the amount of absorbed hydrogen reached H/M of about one within 1 h. In the charge-discharg test, the MgィイD22ィエD2Ni-70 wt.% Ni composite showed markedly high discharge capacity of about 870 mAh g(MgィイD22ィエD2Ni)ィイD1-1ィエD1. The discharge capacity, moreover, increased up to 1080 mAh g(MgィイD22ィエD2Ni)ィイD1-1ィエD1by using Ni powder with the weight ratio of Ni to alloy of 10 instead of Cu powder. The charge-discharge cycle performance was improved by increasing the amount of added Ni powder.
3. The charge-discharge cycle performance for MgィイD20.9ィエD2MィイD20.1ィエD2Ni (M=Ti, V) alloys was greatly improved in comparison with MgNi though the initial discharge capacity decreased. This was ascribed to the preference dissolution of V component in alkaline solution for the MgィイD20.9ィエD2VィイD20.1ィエD2Ni alloy and the formation of Ti oxides on the alloys surface for the MgィイD20.9ィエD2TiィイD20.1ィエD2Ni alloy. In addition, MgィイD20.9ィエD2TiィイD2xィエD2VィイD20.1-xィエD2Ni alloy showed cycle performance superior to the MgィイD20.9ィエD2MィイD20.1ィエD2Ni (M=ti, v) alloys due to the synegret effect of V and Ti components.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (42 results)

All Other

All Publications (42 results)

  • [Publications] Shinji Nohara: "Electrochemical Characteristics of a Homogeneous Amorphous Alloy Prepared by Ball-Milling Mg_2Ni with Ni"J. Alloys Comp.. 267. 76-78 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiroshi Inoue: "Effect of Ball-Milling on Electrochemical and Physicochemical Characteristics of Crystalline Mg_2Ni Alloy"Electrochem. Acta. 43・14-15. 2215-2219 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiroshi Inoue: "Preparation and Electrochemical Characterization of Mg_2Ni Alloys with Different"Electrochem. Acta. 43・14-15. 2221-2224 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu Guo Zhang: "Surface Analysis of an Amorphous MgNi Alloy Prepared by Mechanical Alloying for Use in Nickel-Metal Hydride Batteries"J. Alloys Comp.. 270. 123-126 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Hydriding and Eledtrochemical Characteristics of Homogeneous Amorphous Mg_2Ni-Ni Composite"J. Alloys Comp.. 270. 142-144 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shinji Nohara: "Electrochemical Characterisitics of Amorphous Mg_<0.9>V_<0.1>Ni Alloy Prepared by Mechanical Alloying"J. Alloys Comp.. 280. 104-106 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Hydriding and Dehydriding Characteristics of an Amorphous Mg_2Ni-Ni Composite"J. Alloys. Comp.. 285. 246-249 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Roman and X-Ray Photoelectron Spectroscopic Investigations on a New electrode Material for Nicker-Metal Hydride Batteries : MhNi-Graphite Comosites Prepared by Ballmiling"J. Electrochem. Soc.. 146・5. 1659-1663 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu G. Zhang: "Electrochemical and Structural Characteristics of Amorphous MgNi_x(X21)alloys"J. Alloys Comp.. 293-295. 552-555 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "A New Electrode Material for Nickel-Metal Hydride Batteries : MgNi-Graphite Composites Prepared by Ball-Milling"J. Alloys Comp.. 293-295. 653-657 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu G. Zhang: "Physicochemical and Electrochemical Hydriding-Dehydriding Charcteristics of Amorphous MgNi_x(x=1.0,1.5,2.0)Alloys Preparedby Mechanical Alloying"J. Solid Stat Electrochem.. (in press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 岩倉 千秋: "電池技術第9巻"社団法人 電気化学会電池技術委員会. 100 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 岩倉 千秋: "電池技術第11巻"社団法人 電気化学会電池技術委員会. 140 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shinji Nohara: "Electrochemical Characteristics of a Homogeneous Amorphous Alloy Prepared by Ball-Milling MgィイD22ィエD2Ni with Ni"J.Alloys Comp.. 267. 76-78 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiroshi Inoue: "Effect of Ball-Milling on Electrochemical and Physicochemical Characteristics of Crystalline MgィイD22ィエD2Ni Alloy"Electrochim.Acta. 43・14-15. 2215-2219 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiroshi Inoue: "Preparation and Electrochemical Characterization of MgィイD22ィエD2Ni Alloys with Different Crystallinities"Electrochem.Acta. 43・14-15. 2221-2224 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu Guo Zhang: "Surface Analysis of an Amorphous MgNi Alloy Prepared by Mechanical Alloying for Use in Nickel-Metal Hydride Batteries"J.Alloys Comp.. 270. 123-126 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Hydriding and Electrochemical Characteristics of a Homogeneous Amorphous MgィイD22ィエD2Ni-Ni Composite"J.Alloys Comp.. 270. 142-144 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shinji Nohara: "Electrochemical Characteristics of an Amorphous MgィイD20.9ィエD2VィイD20.1ィエD2Ni Alloy Prepared by Mechanical Alloying"J.Alloys Comp.. 280. 104-106 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Hydriding and Dehydriding Characteristics of an Amorphous MgィイD22ィエD2Ni-Ni Composite"J.Alloys Comp.. 285. 246-249 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Roman and X-Ray Photoelectron Spectroscopic Investigations on a New Electrode Material for Nickel-Metal Hydride Batteries : MgNi-Graphite Composites Prepared by Ballmilling"J.Electrochem.Soc.. 146・5. 1659-1663 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu G.Zhang: "Electrochemical and Structural Characteristics of Amorphous MgNィイD2ixィエD2 (xz1) alloys prepared by mechanical alloying"J.Alloys Comp.. 293-295. 552-555 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "A New Electrode Material for Nickel-Metal Hydride Batteries : MgNi-Graphite Composites Prepared by Ball-Milling"J.Alloys Comp.. 293-295. 653-657 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu G.Zhang: "Physicochemical and Electrochemical Hydriding-Dehydriding Characteristics of Amorphous MgNiィイD2xィエD2 (x=1.0, 1.5, 2.0) Alloys Prepared by Mechanical Alloying"J.Solid State Electrochem.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Chiaki Iwakura: "Roman and X-Ray Photoelectron Spectroscopic Investigations on a New Electrode Material for Nickel-Metal Hydride Batteries: MgNi-Graphite Composites Prepared by Ballmilling"J. Electrochem. Soc.. 146・5. 1659-1663 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shu G. Zhang: "Electrochemical and Structural Characteristics of Amorphous MgNi_x(x【greater than or equal】1) alloys prepared by mechanical alloying"J. Alloys Comp.. 293-295. 552-555 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Chiaki Iwakura: "A New Electrode Material for Nickel-Metal Hydride Batteries: MgNi-Graphite Composites Prepared by Ball-Milling"J. Alloys Comp.. 293-295. 653-657 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shu G. Zhang: "Physicochemical and Electrochemical Hydriding-Dehydriding Characteristics of Amorphous MgNi_x(x=1.0,1.5,2.0) Alloys Prepared by Mechanical Alloying"J. Solid State Electrochem.. (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 岩倉 千秋: "電池技術第11巻"(社)電気化学会電池技術委員会. 140 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shinji Nohara: "Electrochemical Characteristics of a Homogeneous Amorphous Alloy Prepared by Ball-Milling Mg_2Ni with Ni" J.Alloys Comp.267・1-2. 76-78 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiroshi Inoue: "Effect of Ball-Milling on Electrochemical and Physicochemical Characteristics of Crystalline Mg_2Ni Alloy" Electrochem.Acta. 43・14-15. 2215-2219 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiroshi Inoue: "Preparation and Electrochemical Characterization of Mg_2Ni Alloys with Different Crystallinities" Electrochem.Acta. 43・14-15. 2221-2224 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Shu Guo Zhang: "Surface Analysis of an Amorphous MgNi Alloy Prepared by Mechanical Alloying for Use in Nickel-Metal Hydride Batteries" J.Alloys Comp.270・1-2. 123-126 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Chiaki Iwakura: "Hydriding and Electrochemical Characteristics of a Homogeneous Amorphous Mg_2Ni-Ni Composite" J.Alloys Comp.270・1-2. 142-144 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Shinji Nohara: "Electrochemical Characteristics of an Amorphous Mg_<0.9>V_<0.1>Ni Alloy Prepared by Mechanical Alloying" J.Alloys Comp.280・1-2. 104-106 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Chiaki Iwakura: "Hydriding and Dehydriding Characteristics of an Amorphous Mg_2Ni-Ni Composite" J.Alloys.Comp.(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Chiaki Iwakura: "Raman and X-Ray Photoelectron Spectroscopic Investigations on a New Electrode Material for Nickel-Metal Hydride Batteries: MgNi-Graphite Composites Prepared by Ball-Milling" J.Electrochem.Soc.(in press). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Nohara et al.: "Effect of Surface Modification of a MgNi Alloy with Graphite by Ball-Milling on the Rate of Hydrogen Absorption" Journal of Alloys and Compounds. 252. L16-L18 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Nohara et al.: "Compositional and Structural Characteristics of MgNi Alloy Prepared by Mechanical Alloying for Use as Negative Electrodes in Nickel-Metal Hydride Batteries" Journal of Alloys and Compounds. 259. 183-185 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Nohare et al.: "Electrochemical Characteristics of a Homogeneous Amorphous Alloy Prepared by Ball-Milling Mg_2Ni with Ni" Journal of Alloys and Compounds. (In press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Inoue et al.: "Effect of Ball-Milling on Electrochemical and Physicochemical Characteristics of Crystalline Mg_2Ni Alloy" Electrochimica Acta. (In press). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Inoue et al.: "Preparation and Electrochemical Characterization of Mg_2Ni Alloys with Different Crystallinities" Electrochimica Acta. (In press). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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