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Preparation of intercalation compounds and their support on porous filter by soft solution chemistry

Research Project

Project/Area Number 09555277
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 無機工業化学
Research InstitutionOsaka University

Principal Investigator

KIKKAWA Shinichi  (Associate professor, The Institute of Scientific and Industrial Research Osaka University), 産業科学研究所, 助教授 (10127219)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Masao  Research associate, The Institute of Scientific and Industrial Research Osaka University, 産業科学研究所, 助手 (00188054)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥13,000,000 (Direct Cost: ¥13,000,000)
Fiscal Year 1999: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1998: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1997: ¥8,900,000 (Direct Cost: ¥8,900,000)
Keywordssoft solution chemistry / functional ceramic / metastable phases / nano-or meso-porous materials / micro gravity / intercalation compound / porous filter / COィイD22ィエD2absorption / 凍結乾燥 / 微小重力 / 均一混合 / 均一核発生 / ハイドロタルサイト / 二酸化炭素分離 / 多孔体 / フィルター / タングステン酸 / メゾ複合体 / 均一液相法 / 無機合成 / 層状化合物
Research Abstract

Soft solution chemistry was applied for the preparation of functional ceramic materials including intercalation compounds. It led to the preparation of new metastable phases due to well-mixing of starting materials, the structural control to nano-or meso-porous materials and so on as follows:
(1) Citric acid was added to mixed aqueous Zn and In nitrate solution as a gelling agent. The solution was concentrated at 100℃ under stirring and then fired at 350℃. Solid solution range of InィイD13+ィエD1 in ZnO extended to 15%. The products showed a good transparent electrical conductivity.
(2) The citric acid method was also applied on ZrOClィイD22ィエD2-AlClィイD23ィエD2 system. Tetragonal zirconia fine powder was obtained in more homogeneously mixed state with alumina than product from the coprecipitation method.
(3) Mixed chloride or nitrate aqueous solution was frozen under micro gravity condition instead of an addition of gelling agent. The product crystallized much better than the salt obtained at ambient condition after its drying under vacuum. The homogeneously mixed state was preserved even after its oxidation.
(5) Nano- or meso-porous WOィイD23ィエD2 and VィイD22ィエD2O(5) were prepared using micelle of alkyl ammonium surfactant as a template or by leaching out fo BィイD22ィエD2OィイD23ィエD2 after its congruent melting with these oxides.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (28 results)

All Other

All Publications (28 results)

  • [Publications] K. Adhikary: "Preparation and electrochemical lithium intercalation of V_2O_5 porous lump with large surface area"Solid State Ionics. 99. 53-60 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Adhikary: "Some new aspects of low-temperature lithium cobalt oxides prepared through citric acid precursor route"Mater. Res. Bull. 33. 1845-1856 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa: "Formation of tungustic acid in alkyl ammonium aqueous solution"Solid State Ionics. 113-115. 403-406 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa: "Soft chemical preparation and electrochemical oxygen-doping of La_2Ca_<n-1>Cu_nO_<2n+2>"J. Mate. 13. 812-815 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 吉川: "ハイドロタルサイト担持フィルターによるCO_2の可逆分離"粉体および粉末冶金. 46. 300-304 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 吉川信一: "層状無機物質における新機能性"化学工業. 50. 514-517 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Adhikary and S. Kikkawa: "Preparation and electrochemical lithium intercalation of VィイD22ィエD2OィイD25ィエD2 porous lump with large surface area"Solid State Ionics. 99. 53-60 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Adhikary, M. Takahashi and S. Kikkawa: "Some new aspects of low-temperature lithium cobalt oxides prepared through citric acid precursor route"Mater. Res. Bull.. 33. 1845-1856 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa and Y. Teng: "Formation of tungustic acid in alkyl ammonium aqueous solution"Solid State Ionics. 113-115. 403-406 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa, N. Taya and F. Kanamaru: "Soft chemical preparation and electrochemical oxygen-doping of LaィイD22ィエD2CaィイD2n-1ィエD2CuィイD2nィエD2OィイD22n+2ィエD2"J. Mater. Res.. 13. 812-815 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa, Y. Kohno and Y Teng: "Recovery of COィイD22ィエD2 using hydrotalcite supported filter"J. Jpn. Soc. Powder & Powder Metallurgy. 46. 1128-1138 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa, H. Kanasaki, M. Takahashi, K. Adhikary, K. Hirota and O. Yamaguchi: "Low temperature preparation of transparent conducting material in ZnO-InィイD22ィエD2OィイD23ィエD2 system by homogeneous aqueous method"J. Jpn. Soc. Powder & Powder Metallurgy. 46. 189-193 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa: "Studies on inorganic layered materials"J. Jpn. Soc. Powder & Powder Metallurgy. 45. 13-19 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa: "Shaping of intercalation materials"New Ceramics. 11. 21-24 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kikkawa: "New functionality of layered inorganic materials"Chemical Industry. 50. 514-517 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 吉川信一: "ハイドロタルサイト担持フィルターによるCO_2の可逆分散"粉体および粉末冶金. 46. 300-304 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉川信一: "均一液相ほうによるZnO-In_2O_3系透明導電物質の低温合成"粉体および粉末冶金. 46. 189-193 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉川信一: "層状無機物質による新機能性"化学工業. 50. 514-517 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Adhikary et al.: "Some new aspects of LT-lithium cobalt oxides prepared through citric acid precursor ronie" Mater.Res.Bull.33. 1845-1856 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kikkawa et al.: "Formation of tangstic acid in alkyl-ammonium Aguiarius solution" Solid State Ionics. 113〜115. 403-406 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉川信一ら: "均一液相法によるZnO-In_2O_3系透明導電物質の低温合成" 粉体および粉末冶金. 46. 189-193 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉川信一ら: "インタカレーション材料の形態制御" ニューセラミックス. 11. 21-24 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉川信一ら: "ハイドロタルサイト担持フィルターによるCO_2の可逆分離" 粉体および粉末冶金. 46(印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Kikkawa: "Titanium disulfide thin film prepared by plasma CVD for lithium rechargeable battery" Ceramic Inter.23. 7-11 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Adhikary: "Preparation and electrochemical lithium intercalation of V_2O_5 porous lump with large surface area" Sclid State Ionics. 99. 53-60 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Kikkawa: "Soft chemical preparation and electrochemical oxygen-doping of La_2 Can-1 Cun C_<n+2>" J.Mater.Res. 13(印刷中). (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 吉川信一: "無機層状物質の創製に関する研究" 粉体および粉末冶金. 45. 13-19 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] 吉川信一: "インタカレーション材料の形態制御" ニューセラミックス. '98・4(印刷中). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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