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Research and development on the pulsed slow positron beam to analyze surface of polymer

Research Project

Project/Area Number 09555298
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 高分子構造・物性(含繊維)
Research InstitutionHigh Energy Accelerator Research Organization

Principal Investigator

SUZUKI Takenori  Applied Research Laboratory, High Energy Accelerator Research Organization, Professor, 放射線科学センター, 教授 (40162961)

Co-Investigator(Kenkyū-buntansha) OKI Yuichi  Applied Research Laboratory, High Energy Accelerator Research Organization, Research Associate, 放射線科学センター, 助手 (40204094)
MIURA Taichi  Applied Research Laboratory, High Energy Accelerator Research Organization, Research Associate, 放射線科学センター, 助手 (80209717)
KONDO Kenjiro  Applied Research Laboratory, High Energy Accelerator Research Organization, Professor, 共通研究施設, 教授 (20004434)
NUMAJIRI Masaharu  Applied Research Laboratory, High Energy Accelerator Research Organization, Research Associate, 放射線科学センター, 助手 (20189385)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥5,600,000 (Direct Cost: ¥5,600,000)
Fiscal Year 1999: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1998: ¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 1997: ¥3,000,000 (Direct Cost: ¥3,000,000)
Keywordspositron annihilation / pulsed beam / radio isotopes / slow positron / polymer / surface / thin film / free volume / 低速陽電子ビーム / 陽電子の寿命 / 短パルス化 / 高分子表面 / 自由体積 / ドップラー幅 / パルス化効率 / 陽電子の寿命測定
Research Abstract

In order to study the surface of polymers a pulsed show positron beam (PSPB) is necessary to determine the injection time in the investigated polymer. In this project, a small apparatus desk-top size has been built using radio isotopes. The bunched and pulsing beam was obtained by the hybrid method : (1) pre-buncher, t-2 ideal electrical potential bunching, (2) main buncher, RF buncher using 1/4 cavity. The first buncher could make a pulsed beam with 2ns full width at half maximum (FWHM). The beam was focused on the gap of the acceleration gap of the RF cavity, the main buncher could bunch the pulsed beam with 0.5ns FWHM. This resolution is good enough to analyze polymer, in which positronium has 2 to 3 ns lifetime. However this is still wider to analyze the lifetime in metals.
In this project, the apparatus to obtain a pulsed and bunched beam was successfully built and was applied to measure lifetime of polymers : polyethylene, epoxy resin, epoxy composite, and multi-layer of Fe metal and polyethylene. In this application, the heat expansion coefficient of the surface and the bulk of epoxy resin was obtained. The increase in the positronium formation with increasing the depth was observed in polyethylene. The skin layer of the composite materials was observed by a non destructive method.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (48 results)

All Other

All Publications (48 results)

  • [Publications] 伊藤泰男、鈴木健訓: "An application of the coincidence Doppler spectroscopy for substances of chemical interest"Radiation Physics and Chemistry. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 濱田栄作、鈴木健訓、他: "Application of pulsed slow positron beam to polymer"Radiation Physics and Chemistry. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kansy J. 、鈴木健訓、他: "study of poly(methylphenylsilylenemethylene) by elastic thermalization lifetime analythis"Radiation Physics and Chemistry. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 鈴木健訓、他: "Radiation effect on positronium formation in low temperature polyethylenes"Radiation Physics and Chemistry. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊藤寛、鈴木健訓、他: "The effect of visible light irradiation on positronium on formation in polyethylene at low temperature"ACTA PHYSICA POLONICA A,, pp. 533-538(1999). 95. 533-538 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 鈴木健訓、他: "Polymerization of Epoxy Resins Studies by Positron Annihilation"ACTA PHYSICA POLONICA A. 95. 671-678 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 濱田栄作、鈴木健訓、他: "Development of a Pulsed Slow-Positron Beam Using Time-Varying Pulsing-Bias"Applied Surface Science. 149. 40-43 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 林利明、鈴木健訓、他: "Characterization of curing behavior of cyanic ester by a positron-annihilation"Polymer. 40. 1053-1056 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 大島永康、鈴木健訓、他: "Application of pulsed slow positron Beam to polymer"Journal of Radioanalytical and Nuclear Chemistry. 239. 329-333 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 鈴木健訓: "Free Volumes in Polymers and Positron Annihilation"Journal of Network Polymer, 19, No. 3, 156-166(1998). 19. 156-166 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 小川 琢哉、鈴木健訓、et al.: "Characterization of Poly(silylenemethylene)s by positron Annihilation lifetime spectroscopy"J. Polym. Sci., Part B. Polym. Phys.. 36. 755-761 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] W. Zheng, T. Suzuki, et al.: "Mobility of positrons in gamma-irradiated polypropylene and polyethylene"Radiation Physics and Chemistry. 51. 269-272 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 小林慶規、鈴木健訓、et al.: "Electric field effect on positronium formation in gamma-irradiated polypropylene and polyethylen"Radiation Physics and Chemistry. 50. 589-593 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 小林慶規、鈴木健訓、et al.: "Positronium Formation in Polypropylene and Polyethylene-Effects of Gamma-irradiation and Electric field-"Materials Science Forum. 255-257. 67-71 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 鈴木健訓: "Application of Positron Annihilation Lifetime Spectroscopy to Network Polymers"Journal of Network Polymer. 18. 121-132 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Ohshima, T. Suzuki, et al.: "Performance report of a newly Developed slow positron pulsing apparatus"Materials Science Forum. 255-257. 629-631 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Ohshima, T. Suzuki, et al.: "Design of a high-efficiency Short-pulsed positron beam system"Applied Surface Science. 116. 82-86 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ito Y. and Suzuki T.: "An application of the coincidence Doppler spectros copy for substances of chemical interest"Rad. Phys. Chem.. (in Pring, 2000).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hamada E., Ohshima N., Suzuki T., Kobayashi H., Kondo K., Kanazawa I., and Ito Y.: "Application of pulsed slow positron beam to polymer"Rad. Phys. Chem.. (in Print, 2000).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kansy J., Suzuki T., Ogawa T., and Murakami M.: "Study of poly(methylphenylsilylenemethlene) by elastic thermalization lifetime analythis"Rad. Phys. Chem.. (in Print, 2000).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Suzuki T., Kondo K., Ito Y., Hamada E., and Ito Y.: "Radiation effect on positronium formation in low temperature polyethylenes"Rad. Phys. Chem.. (in Print, 2000).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ito Y., Hirade T., Hamada E., Suzuki T. and Ito Y.: "The effect of visible light irradiation on positronium formation in polyethylene at low temperature"ACTA PHYSICA POLONICA A. 95. 533-538 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Suzuki T., Hayashi T., and Ito Y.: "Polymerization of Epoxy Resins Studied by Positron Annihilation"ACTA PHYSICA POLONICA A. 95. 671-676 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hamada E., Oshima N., Suzuki T., Kobayashi H., Kondo K., Kanazawa I. And Ito Y.: "Development of a Pulsed Slow-Positron Beam Using Time-Varying Pulsing-Bias"Applied Surface Science. 149. 40-43 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hayashi T., Nakamura H., and Suzuki T.: "Characterization of curing behavior of cyanic ester by a positron-annihilation lifetime technique"Polymer. 40. 1053-1056 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Oshima N., Hamada E., Suzuki T., Kanazawa I. And Ito Y.: "Application of Pulsed Slow-Positron Beam to Polymer"Journal of Radioanalytical and Nuclear Chemistry. 239. 329-333 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Suzuki: "Free Volumes in Polymers and Positron Annihilation"Journal of Network Polymer. 19. 156-166 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ogawa, T.Suzuki and M.Murakami: "Characterization of Poly(silylenenmethylene)s by positron annihilation lifetime spectroscopy"J. Polym. Sci., Part B. Polym. Phys.. 36. 755-761 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] W.Zheng, Y.Kobayashi, K.Hirata and T.Suzuki: "Mobility of positrons in gamma-irradiated polypropylene and polyethylene"Radiation Physics and Chemistry. 51. 269-272 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Kobayashi, W.Zheng, K.Hirata and T.Suzuki: "Electric field effect on positronium formation in gamma-irradiated polypropylene and polyethylene"Radiation Physics and Chemistry. 50. 589-593 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Kobayashi, W.Zheng, K.Hirata and T.Suzuki: "Positronium Formation in Polypropylene and Polyethylene -Effects of Gamma-irradiation and Electric field-"Materials Science Forum. 255-257. 67-71 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Takenori Suzuki: "Application of Positron Annihilation Lifetime Spectroscopy to Network Polymers"Journal of Network Polymer. 18. 121-132 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.Oshima, E.Hamada, T.Suzuki, I.Kanazawa and Y.Ito: "Performance report of a newly developed slow positron pulsing apparatus"Materials Science Forum. 255-257. 629-631 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Suzuki, N.Oshima, E.Hamada, T.Ogawa, M.Murakami and Y.Ito: "Relaxational behavior of Polymers at Low emperature Studied by Positron Annihilation"Materials Science Forum. 255-257. 351-353 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 伊藤寛、鈴木健訓、他: "The effect of visible light irradiation on positronium formation in polyethylene at low temperature"ACTA PHYSICA POLONICA A, pp. 533-538(1999). 95. 533-538 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 鈴木健訓、他: "Polymerization of Epoxy Resins Studied by Positron Annihilation"ACTA PHYSICA POLONICA A. 95. 671-678 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 濱田栄作、鈴木健訓、他: "Development of Pulsed Slow-Positron Beam Using Time-Varying Pulsing-Bias"Applied Surface Science. 149. 40-43 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 林利明、鈴木健訓、他: "Characterization of curing behavior of cyanic ester by a positron-annihilation lifetime technique"Polymer, vol. 40, pp1053-1056 (1999). 40. 1053-1056 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大島永康、鈴木健訓、他: "Application of Pulsed Slow-Positron Beam to Polymer"Journal of Radioanalytical and Nuclear Chemistry. 239. 329-333 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 鈴木健訓、他: "Radiation effect on positronium formation in low temperature polyethylenes"Radiation Physics and Chemistry. (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 鈴木健訓: "高分子材料の自由体積と陽電子消滅" ネットワークポリマー. 19. 156-166 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Oshima,et al.: "Application of pulsed Slow-Positron Beam to Polymer" J.Radioanalytical and Nuclear Chemistry. 239. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ogawa,et al.: "Characterization of Poly(silylenemethylene)s by Positron Annihilation Lifetime Spectroscopy" J.Polym,Sci.,Part B,Polym.Phys.36. 755-761 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] W.Zheng.et al.: "Mobility of Positronsin δ-irradiated Polypropylene and Polyethylene" Radiation Physics and Chemistry. 55. 269-272 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Hayashi,et al.: "Characterization of Curing Behavior of Cyanic Ester by a positron Annihilation Lifetime Technique" Polymer. 40(in press). 1053-1056 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Oshima, T.Suzuki, et al.: "Application of Pulsed Slow-Positron Beam to Polymer" J.of Radioanalytical and Nuclear Chemistry. (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Oshima, T.Suzuki, et al.: "Design of a high-efficiency short-pulsed positron beam system" Applied Surface Science. 116. 82-86 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Suzuki, 鈴木健訓: "陽電子消滅法のネットワークポリマーへの応用" ネットワークポリマー. 18. 121-132 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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