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Development of a new respirator for organic vapors with a built-in breakthrough detector using semiconductor gas sensors.

Research Project

Project/Area Number 09557035
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field Public health/Health science
Research InstitutionUniversity of Occupational and Environmental Health

Principal Investigator

HORI Hajime  UOEH, School of Health Sciences, Professor, 産業保健学部, 教授 (70140902)

Co-Investigator(Kenkyū-buntansha) ICHIMATSU Sumiyo  UOEH, School of Health Sciences, Instructor, 産業保健学部, 助手 (40289591)
ARASHIDANI Keiichi  UOEH, School of Health Sciences, Professor, 産業保健学部, 教授 (10141748)
HIGASHI Toshieki  UOEH, IIES, Professor, 産業生態科学研究所, 教授 (10119000)
ISHIDAO Toru  UOEH, School of Health Sciences, Instructor, 産業保健学部, 助手 (90212901)
則武 祐二  (株)リコー, 品質管理部, グループリーダー
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥6,300,000 (Direct Cost: ¥6,300,000)
Fiscal Year 1999: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1998: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1997: ¥3,800,000 (Direct Cost: ¥3,800,000)
Keywordsorganic vapor / semiconductor sensor / breakthough time / gas mask / respirator cartrigde
Research Abstract

To predict the breakthrough of organic vapors in a respirator cartridge when a worker is wearing it is usually difficult because the service life of the cartridge for organic vapors depends on many factors, such as, the kinds of vapors, concentration, temperature, relative humidity and the respiratory rate. In this study, a method for determining the breakthrough of the vapors in the respirator cartridge was developed. Air containing organic vapors was introduced into the cartridge, and the breakthrough curve was obtained by measuring the vapor concentration at downstream of the respirator with a gas chromatograph (GC) equipped with a flame ionization detector. Simultaneously, an output signal from a semiconductor sensor that was inserted in the downstream of the cartridge was recorded in an IC card temporally. After the measurement, the data recorded in the card were transferred to a personal computer and the change in the output signal from the sensor was compared with the breakthrough curve obtained by the GC. More than eight kinds of solvents including aromatic hydrocarbons, chlorinated hydrocarbons, acetates, alcohols, ketones and aliphatic hydrocarbons were tested. The sensitivity of the sensor for chlorinated hydrocarbons was generally low, especially when the relative humidity was high, but the rising time of the signal from the sensor was almost the same as or earlier than the breakthrough time obtained by the GC. These results suggest that the sensor is applicable as a detector of the breakthrough in respirator cartridges for organic vapors. Based on the results, a respirator with a breakthrough detector was developed, and its availability was discussed.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (13 results)

All Other

All Publications (13 results)

  • [Publications] 保利 一, 他: "半導体ガスセンサーによる防毒マスク吸収缶の破過の検出法"呼吸保護. 14・1. 14-22 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H et al.: "Detection of breakthrough of organic vapors in a respirator cartridge using a semiconductor sensor"Journal of the International Society for Respiratory Protection. 17・3. 35-35 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H, Tanaka I: "Equilibrated vapor concentrations for bicomponent organic solvents"Journal of Occupational Health. 40. 132-136 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H et al.: "A method for detecting breakthrough of organic solvent vapors in a charcoal tube using semiconductor gas sensors"Applied Occupational and Environmental Hygiene. 14・8. 558-564 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H, Tanaka I: "equilibrated vapor concentrations for bicomponent organic solvents."Journal of Occupational Health. 40. 132-136 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H, Noritake Y, Murobusi H, Higashi T, Tanaka I: "A method for detecting breakthrough of organic solvent vapors in a charcoal tube using semiconductor gas sensors."Applied Occupational and Environmental Hygiene. 14(8). 558-564 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H, Ishidao T, Ishimatsu S, Arashidani K: "Detection of breakthrough organic vapors in a respirator cartridge using a semiconductor sensor."Journal of the International Society Respiratory Protection. 17(3). 35 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hori H, Ishidao T, Ishimatsu S, Arashidani K: "Detection of breakthrough organic vapors in a respirator artrigde"Journal of ISRP Japan Section Respiratory Protection. 14(1). 14-22 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 保利 一,他: "半導体ガスセンサーによる防毒マスク吸収缶の破過の検出法"呼吸保護. (印刷中). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hori H et al.: "Detection of breakthrough of organic vapors in a respirator cartridge using a semiconductor sensor"Journal of the International Society for Respiratory Protection. 17・3. 35-35 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 保利 一,他: "有機ガス用防毒マスク吸収缶の加熱再生法の検討"1999年度呼吸保護に関する研究発表会講演抄録集. 17-20 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 保利 一,他: "半導体センサーによる防毒マスク吸収缶の破過の検出法" 日本労働衛生工学会第38回学会抄録集. 94-95 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 保利 一,他: "センサーによる防毒マスク吸収缶の破過の検出" 1998年度呼吸保護に関する研究発表会講演抄録集. 12-15 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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