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Mechanisms for the formetion of HCN and HNC on the intersteellar dust grains

Research Project

Project/Area Number 09640316
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Astronomy
Research InstitutionYamanashi University

Principal Investigator

HIRAOKA Kenzo  Yamanashi Univ.Fac.Eng., Professor, 工学部, 教授 (80107218)

Co-Investigator(Kenkyū-buntansha) SATO Tetsuya  Yamanashi Univ.Fac.Eng., Assistant, 工学部, 助手 (60252011)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 1998: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1997: ¥2,100,000 (Direct Cost: ¥2,100,000)
Keywordsdust grain / HCN / HNC / tanneling reaction / シアン化水素 / イソシアン化水素
Research Abstract

Experimental simulation was made for the elucidation of solid-phase reactions taking place on the interstellar dust grains. The cryocooler and a quadrupole mass spectrometer were housed in a vacuum chamber. Infrared spectra of products formed by the reaction of H atoms with deposited samples on the silicon substrate were measured using a FT-IR spectrometer. The hydrogen atoms were produced by the dc glow discharge using the bottle-neck discharge tube having two optical traps. The UV light from the H_2 plasma was completely absorbed by the graphite coated on the optical traps. When the grounded Mo wire included in the optical trap wasused, electrons effusing from the discharge tube were completely annihilated, The CN radicals formed by the discharge of N_2/CO mixed gas were deposited on the silicon substrate and reacted with H atoms. The HNC/HCN products were measured by means of FT-IR.In addition, ON radicals were also formed by the UV irradiation of (CN)_2. The reaction of C_2 hydrocarbons with H and D atoms were also investigated, It was found that acetylene was much less reactive than ethylene toward H atoms at cryogenic temperature.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] K.Hiraoka: "Reactions of hydrogen atoms With solid thin films of acetone and 2-prepanol at 13K" Astrophys.J.508. 423-430 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Gas-phase ion-molucule reactions in tetrahydrothiophene" J.Mass Spectrom.Soc.Jpn.46. 442-447 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "A new liquid chromatography / mass spectrometry interface : laser spray" Rapid Commun.Mass spectrom. 12. 1170-1174 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "How is the fluside ion found to O_2, N_2, and CO molecules ?" J.Phys.Chem.A. 102. 6916-6920 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Formation of the trimer ion core in heterogeneous rare gas cluster ions" J.Chem.Phys.108. 6689-6697 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Gas-grain processes for the formation of CH_4 and H_2O : reactions of Hatoms with C, O, and CO in the solid phase at 12K" Astrophys.J.498. 710-715 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Reactions of hydrogen atoms with solid thin films of autone and 2-propanol at 13K" Astrophys.J.508. 423-430 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Gas-phssc ion-moleale reactions in totrahydro thiophene" J.Mars Spectrom.foc.Jpn.46. 442-497 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "A newliguid chromatography/mass speotrsmetry intarface : laser spray" Rapid Comman Mass Speotrim. 12. 1170-1174 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "How is the Fluoride ion bound to O_2, N_2, and CO molecules?" J.Phys.Chem.A. 102. 6916-6920 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Formation of the trimer in core in the heterogeneous chusler ions." J.Chem.Phys.108. 6689-6697 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Gas-grain proasses for the formation of CA_4 and H_2O : reactions of H atoms with C,O,and CO in the solid phase at 12K" Astrophys.J.498. 710-715 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Hiraoka: "Reactions of hydrogen atons with suhid thin fibno of aceton and 2-propanot as βK" Astrophya. J.508. 423-430 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hiraoka: "Gas-phase ion-moleale reactions in totrahydrothiophene" J.Mass Seecron Sol.Jpn.46. 442-447 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hiraoka: "A new bigid chromatography/mass spectiomety interface : laser spiry" Rapid Commun. Mass Spedron. 12. 1170-1174 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hiraoka: "How is the flusidr ion bound to O_2, N_2, and CO molecnles?" J.phys.Chim.A. 102. 6916-6920 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hiraoka: "Formation of the triner ion core in the heterogeneous rare gas cbualn ins" J.Chim.phys.108. 6689-6697 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hiraoka: "Gas-grain processes for the fermation H CH4 and H2O : reactions of Hatons with C, O and CO in the slid phree of 12K" Astrophys.J.498. 710-715 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Hiraoka, S.Fujimaki: "Gas-phase thermochemical staibities of cluster ions [(N_2)m(Ar)n]^+" Journal of Chemical Physics. 107. 2550-2556 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Hiraoka, J.Katsuragawa: "Thermochemistry and structure of the cluster ions CH_3^+(CO)n and SiH_3^+(CO)n" Chemical Physis Letters. 271. 302-310 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Hiraoka, F.Matsushita: "Enhancemint of ion evaporation by the CO_2 laser irradiatioro on the electropprey" International Journel of Mass Speetrometry and Ion Proesson. 162. 35-44 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Sato, A.Shimiza, K.Hiraokal: "Secondary Ion Produced by low energy impact of He^+ ions" Rapid Communicatuins in Mrss spectrometry. 11. 1139-1143 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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