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High Resolution Analysis of Paleoenvironmental Change by the Simultaneous Methylation Method (TMAH Method)

Research Project

Project/Area Number 09640587
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 地球化学
Research InstitutionSoka University

Principal Investigator

YAMAMOTO Shuichi  Soka university, Faculty of Education, Professor, 教育学部, 教授 (20182628)

Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1998: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1997: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsTMAH method / Pyrolysis methylation method / Paleo-environment / Bio-marker / ODP Leg 167 / Sedimentary Organic matter / バイオマーカー / 推積物 / 環境指標有機化合物 / ODPLeg167
Research Abstract

In this study, we obtained the following results.
(1) Retrieval of bio-marker organic compounds on the analyses of oceanic sediments by the TMAH method
Land-derived organic compounds produced by TMAH method are C20-C32 fatty acids, lignins (8 compounds, vanillins, syringyls, cinnamyls), cutin acids (3 compounds), sterols (e.g. beta-sitosterol). On the other side, as marine-derived compounds, C12-C18 fatty acids, sterols (e.g. brassicasterol), phytol, marine cutin acids (6 compounds include new 3 compounds) and cyclohexyl-alkylalcohols (9 compounds) probably originated by bacteria are analyzed.
(2) The high resolution analysis of sediment core of California margin (ODP Leg 167, Site 1017)
Total organic carbon drastically decreased at the Younger Dryas period, and obviously increased at the last glacial period (12 - 15 kyrs). A clear increase of lignin was also seen at the last glacial period. As it is presumed that the river-system developed to the vicinity of California at this period, the result of lignin suggests the transportation of the land derived organic compounds to this area actively occurred. It is clarified that the contribution of angiosperm has increased gradually from 1 6ka toward the present, as the syringyls/vanillyls ratio of lignin (the contribution index of the angiosperm) increased.
(3) Analysis of the Morikita tumulus at Bange-cho in the Fukushima
In the analysis of the Morikita tumulus, we mentioned the position of buried person, the specification of the fiber-like material, the specification of the wood to be used as coffin tub, and differences of vegetation between the present and the Tumulus period.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] 吉川博康: "TMAH法による琵琶湖堆積物中の有機物の解析" 第15回有機地球化学シンポジウム 講演要旨集. 11 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 山本修一: "熱分解メチル化法による海洋堆積物(ODP Leg 167, Site1017)中有機物の解析" 1997年度日本地球化学会年会 講演要旨集. 172 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 吉川博康: "カリフォルニア沖堆積物(OPP Leg 167, site 1017)中の陸起源有機物 : 熱分解メチル化法による解析" 1997年度 日本地球化学会 講演要旨集. 54 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 吉川博康: "カリフォルニア沖堆積物(ODP Leg 167, site 1017)中の陸起源有機物 : 熱分解メチル化法による解析-2" 1998年度 日本地球化学会 講演要旨集. 65 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 吉川博康: "カリフォルニア沖堆積物コア中の有機物組成の変動 : TMAH メチル化法による解析" 第16回 有機地球化学シンポジウム 講演要旨集. 8 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 山本修一: "森北1号古墳の有機地球化学的手法による解析" 会津坂下町森北1号古墳. (報告書, 印刷中). (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Yamamoto: "Analysis of Morikita tumulus by the organic geochemical method" Morikita tumulus groups.Soka university and Education committee of Aizu Bange-cho. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Yoshikawa et al.: "Analysis of Organic matter from the sediment of Lake Biwa by the TMAH method." Abstract of the 15-th symposium of organic geochemistry. (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Yamamoto et al.: "Analysis of organic matter in marine sediments (ODP Leg 167, Site 1017) by Py-GC-MS with in situ methylation." Abstarct of 1997 Annual Meeting of the Geochemical Society of Japan. 172 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Yoshikawa et al.: "Land-derived organic matter in California margin sediments (ODP Leg 167, Site 1017) : analysis by GC-MS with in situ methylation." Abstract of 1997 Annual Meeting of the Geochemical Society of Japan. 54 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Yoshikawa et al.: "Change of composition of organic matter in the California margin sediment core : Analysis by the TMAH method." Abstract of the 16-th symposium of organic geochemistry. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Yoshikawa et al.: "Land-derived organic matter in California margin sediments (ODP Leg 167, Site 1017) : analysis by GC-MS with in situ methylation-2." Abstract of 1998 Annual Meeting of the Geochemical Society of Japan. 65 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 吉川博康、山本修一、松本公平、石渡良志: "カリフォルニア沖推積物コア中の有機物組成の変動:TMAH メチル化法による解析" 有機地球化学第16回シンポジウム要旨集. 8 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉川博康、山本修一、松本公平、関 宰、石渡良志: "カリフォルニア堆積物(ODP Leg167.Site1017)中の隆起時有機物:熱分解メチル化法による解析.-2" 日本地球化学会年会 講演要旨集1998. 65 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山本修一: "森北1号古墳の有機地球化学的手法による解析" 会津坂下町森北1号古墳(報告書). (印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉川博康、石渡良志、山本修一: "TMAH法による琵琶湖堆積物中の有機物の解析" 第15回有機地球化学シンポジウム講演要旨集. 11- (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 山本修一、吉川博康、石渡良志: "熱分解メチル化法による海洋堆積物(ODPLeg167,Site1017)中有機物の解析" 1997年度日本地球化学会年会講演要旨集. 172- (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 吉川博康、山本修一、松本公平、石渡良志: "カリフォルニア沖堆積物(ODPLeg167,Site1017)中の陸起源有機物:熱分解メチル化法による解析" 1997年度日本地球化学会年会講演要旨集. 54- (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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