| Project/Area Number |
09640615
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Physical chemistry
|
|---|
| Research Institution | Ritsumeikan University |
|---|
Principal Investigator |
TANIGUCHI Yoshihiro Ritsumeikan Univ. Fac. Science and Engineering , Professor, 理工学部, 教授 (70066702)
|
|---|
| Project Period (FY) |
1997 – 1999
|
| Project Status |
Completed (Fiscal Year 1999)
|
| Budget Amount *help |
¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1999: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1998: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1997: ¥1,500,000 (Direct Cost: ¥1,500,000)
|
|---|
| Keywords | NMR / Alkali bromide / Water molecules / Spin-lattice Relaxation Rates / Pressure / スピン-格子緩和速度 / スピン-格子統和速度 / アルカリ金属塩 / 水和 / 動的構造 |
|---|
| Research Abstract |
The spin-lattice relaxation rates(RィイD21ィエD2) of D andィイD117ィエD1O nuclei of a heavy water (DィイD22ィエD2O) molecule in alkali bromide (LiBr, NaBr, KBr and CsBr) aqueous solutions were measured in the range of 0-1.0 molkgィイD1-1ィエD1, 10-50℃ and 0.1-300 MPa by NMR spectroscopy. In these solution, the RィイD21ィエD2 value varies linearly with concentration under constant temperature and constant pressure. Even under high pressure, R1 can be expressed as a weighed sum of the limiting relaxation rates in infinite dilution based on two-state model. The activation volume is estimated from pressure dependence of the rotational correlation times (τ) for the DィイD22ィエD2O molecule coordinated to alkali metal ions. It decreases with increasing radius of alkali metal ion and with increasing pressure at each temperature. The activation energy is estimated from temperature dependence of τ. It decreases with increasing radius of alkali metal ion and with increasing temperature even under high pressure.
|
