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Study on preparation and some properties of new phtalocyanine complexes

Research Project

Project/Area Number 09640668
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionShimane University

Principal Investigator

KASUGA Kuninobu  Material Science, Shimane University Professor, 総合理工学部, 教授 (00032615)

Co-Investigator(Kenkyū-buntansha) SUGIMORI Tamotsu  Material Science, Shimane University Research Associate, 総合理工学部, 助手 (60263505)
HANDA Makoto  Material Science, Shimane University Associate Professor, 総合理工学部, 助教授 (70208700)
Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1999: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1998: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1997: ¥1,500,000 (Direct Cost: ¥1,500,000)
Keywordsphthalocyanine / dendrimer / photocatalyst / active oxygen / oxygenation / TCP / 光増感剤 / デンドリマ- / 二量化 / 光増刊剤
Research Abstract

Some new phthalocyanine (pc) complexes were prepared and the following properties were investigated.
(1)Structural isomer
Four structural isomers exist in Mpc substituted by four substituents. However, the introduction of bulky groups on the α-position of the pc ring only gives one structural isomer, and thus the single crystal of its nickel(II) complex could be obtained. The molecular structure of the complex was determined by an X-ray crystal analysis, showing a screw-type structure.
(2)Dendrimer-phthalocyanine
Znpc with dendrons on the α-position shows unique absorption spectra in non-polar solvents such as dichloromethane and benzene. This may result from the distortion of the pc ring by the coordination of the oxygen atom of dendron on the zinc(II) ion.
(3)Oxygenation catalyst
Oxygenation of cyclohexene catalyzed by pc complexes of manganese(II), iron(III), cobalt(II), nickel(II), and copper(II) was investigated. The reaction was promoted by peracid generated from aldehyde added in the solution and/or by an oxometal intermediate of the pc complex.
(4)Photocatalyst
An active oxygen was generated using Znpcs as a photosenstizer. They also decomposed trichlorophenol in irradiation with visible light.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (37 results)

All Other

All Publications (37 results)

  • [Publications] K. Kasuga: "Oxygen-oxygenation of cyclohexene catalyzed by manganese (III)"Inorg. Chem. Commun.. 2. 507-509 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Kasuga: "Preparation and some properties of a phosphorus (V)"Inorg. Chem.. 38. 4174-4176 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Handa: "Adduct polymers and dimers of rhodium (II)"Bull. Chem. Soc. Jpn. 72. 2681-2686 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Handa: "A new dimer of dimers complex derived from"Chem. Lett.. 1033-1034 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Sayama: "Mixed-valent ruthenium pivalate and its nitroxide"Coord. Chem. at the Turn of the Century. 4. 447-452 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Sayama: "Chain compound of mixed-valent ruthenium dimers"Chem. Lett.. 453-454 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Kasuga: "Handbook on the Physics and Chemistry"Elsevier Science Publishers (in press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Kasuga: "Sandwich-type phthalocyanines"Academic Press (in press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Kasuga: "Oxygen-oxygenation of cyclohexene catalyzed by manganese(III), iron(III) and cobalt(II) complexes of tetra-tert-butlyphthalocyanine in the presence of iso-butyraldehyde, Inorg"Chem. Commun.. 2. 507-509 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Kasuga: "Preparation and some properties of a phosphorus(V) complex of tetra-tert-butylphthalocyanine, Inorg"Chem.. 38. 4174-4176 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Handa: "Adduct polymers and dimers of rhodium(II) pivarete with pyrazine, 4, 4'-bipyridine, 1, 4-ddiazabicyclo[2.2.2]octane, triethylamine, and pyridine"Bull. Chem. Soc. Jpn.. 72. 2681-2686 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Handa: "A new dimer of dimers complex derived from axial coordination of 7, 7, 8, 8-etracyanoquinodimethane to Ru(II, III) cation dimer"Chem. Lett.. 1033-1034 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Sayama: "Mixed-valent ruthenium pivalate and its nitoroxide adduct, Coord"Chem. at the Turm of the Century (Siovak Technical Univ.). 4. 447-452 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y.Sayama: "Chain compound of mixed-valent ruthenium dimers linked by hydrogen-bonding between the axially coordinated nitronyl nitroxide and water molecules"Chem. Lett.. 453-454 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Kasuga: "Handbook on the physics and chemistry"Elsevier Science Publishers (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Kasuga: "Sandwich-type phthalocyaninato and porphyrinato metal complexes in 'Handbook of Advanced Electronic and Photonic Materials'"Academic Press (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Kasuga: "Chain Compound of Mixed-Valent Ruthenuim"Chemistry Letters. 453-454 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga: "Mixed-Valent Ruthenium Pivalate"Coordination Chemistry at the Turn of Century. 4. 447-452 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga: "Preparation and Some Properthes of Phophorous"Inorganic Chemistry. 38. 4174-4176 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga: "A New "Dimer of Dimers"Complex Derived"Chemiotry Letlers. 1033-1034 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga: "Oxygen-Oxgenation of Cgclohexene"Inorganic Chemistry Communications. 2. 507-509 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga: "Adduct Polymers and Dimers of Rhodium"Bulletim of Chemical Society of Japan. 72. 2681-2686 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga(分担): "Handbook on the Physics and Chemistry of Rare Earths"Elsevier Science Publiohers (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kasuga(分担): "Hand book of Adranced Electronic and Photonic Materiale"Academic Press (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Handa: "Structure and Magnetic Properties of a Chain Conplex" Bull.Chem.Soc.Jpn. 71. 119-125 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Handa: "Chain Complexes of Rbodium (III) Pivalate" Inorg.Chem.37. 149-152 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Handa: "Chain Compounds of Molybdenum (II)" Bull.Chem.Soc.Jpn. 71. 1811-1816 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Handa: "Feromagnetic Chain Complex of Ruthenium (II,III)" Chem.Lett.777-778 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Sugimori: "Preparation and Sone Properties of Phthalocganine" Inorg.Chem.Acta. 278. 253-255 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Kasuga: "Fixation of Carbon Dioxide with 1,2-Epoxypropane" Inorg.Chem.Acta. 278. 223-225 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Kasuga: "Fization of carbondioradecetxl.epoxpropaxe" Inorganica Chimica Acta. 257. 277-278 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Kasuga: "Preparation and some properties of one stru cteral isomen" Bulletin of the Chemical Society of Japan. 70. 1859-1865 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Kasuga: "Photoreduction of hydrogen corbonate or ethy lene" Bulletin of the Chemical Society of Japan. 70. 2107-2110 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Handa: "Stsuctsare and Maynetic proplrties of Chacin complex" Bulletin of the Chemical Society of Japan. 71. 119-125 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Handa: "Chacn complezes of rhodium(ii)pivarate dimers" Inorganic Chemiftry. 37. 149-152 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Kasuga: "Cctalytic oxyglnation of olefcne with cleoxygen" Inorganica Chimica Acta. (in press).

    • Related Report
      1997 Annual Research Report
  • [Publications] 春日邦宣(分筆): "フタロシアニン-化学と機能" アイピ-ツ-株式会社, 337 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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